Ba-sr-co-fe-o based perovskite mixed conducting materials as cathode materials for intermediate temperature solid oxide fuel cells both in dual chamber and single chamber configuration

Abstract

Improved cathode active materials for reduced temperature operation in single and dual chamber solid oxide fuel cells are provided. The cathode active materials comprise perovskites of the general form ABO 3 , where A is a cation with approximately a +2 charge, and B is a cation with approximately a +4 charge. These perovskite cathode materials exhibit substantially enhanced power generation at operation temperatures less than or equal to 600° C.

1 .- 63 . (canceled) 
     
     
         64 . A solid oxide fuel cell comprising:
 a cathode comprising a compound of the general form Ba 1-x Sr x Co 1-y Fe y O 3-δ  having a perovskite crystal structure, wherein y is less than 1 and greater than 0, x is greater than 0 and less than 1, and δ is less than or equal to 1;   an anode; and   an electrolyte.   
     
     
         65 . A solid oxide fuel cell according to  claim 64 , wherein the solid oxide fuel cell is a single chamber solid oxide fuel cell. 
     
     
         66 . A solid oxide fuel cell according to  claim 64 , wherein the solid oxide fuel cell is a dual chamber solid oxide fuel cell. 
     
     
         67 . A solid oxide fuel cell according to  claim 64 , wherein x is 0.5. 
     
     
         68 . A solid oxide fuel cell according to  claim 64 , wherein y is 0.2.