Aqueous surface-treating agent

Abstract

An aqueous surface-treating agent, which comprises a silicone oil aqueous emulsion, a polyurethane resin aqueous emulsion, and a silane compound represented by the following general formula: (where R 1 and R 2 each are an alkyl group having 1 to 4 carbon atoms, and n and m are 1≦n≦3 and m=3−n, respectively), and/or a hydrolyzate thereof; wherein 100 parts by weight or more of the polyurethane resin in terms of the weight of solid matters is used on the basis of 100 parts by weight in terms of nonvolatile matters of silicone oil, can prevent sticking of rubber seal materials such as O rings, etc. themselves or sticking to a metal, a resin, etc., and can reduce the friction of rubber or resin seal members at the time of sliding motion.

1 - 9 . (canceled) 
     
     
         10 : An aqueous surface-treating anti-adhesive agent, which comprises a silicone oil aqueous emulsion, a polyurethane resin aqueous emulsion, and a silane compound represented by the following general formula: 
       
         
           
           
               
               
           
         
       
       (where R 1  and R 2  each are independently an alkyl group having 1-4 carbon atoms, n and m are 1≦n≦3 and m=3−n respectively), and/or a partial hydrolyzate thereof, wherein 100 parts by weight or more of the polyurethane resin in terms of the weight of solid matters is used on the basis of 100 parts by weight in terms of the weight of nonvolatile matters of the silicone oil,
 wherein the polyurethane resin aqueous emulsion is a mixture of (a) an aqueous emulsion containing a hydrazide and a carbonyl group-containing polyurethane resin, and (b) a silanol-modified polyurethane resin aqueous emulsion wherein the silanol-modified polyurethane resin has, in the polyurethane structure, silanol groups, which turn to siloxane bonds by condensation cross-linking reaction after surface treating, in a ratio by weight of solid matter sum total of (a):(b)=5-95:95-10, and 
 wherein when applied to rubber seal members the anti-adhesive agent prevents sticking of the rubber seal members to themselves and prevents sticking of the rubber seal members to other materials. 
 
     
     
         11 : An aqueous surface-treating anti-adhesive agent according to  claim 10 , wherein 10-60 parts by weight of the silane compound and/or a hydrolyzate thereof is used on the basis of 100 parts by weight in terms of nonvolatile matters of the silicone oil. 
     
     
         12 : An aqueous surface-treating anti-adhesive agent according to  claim 10 , for application to the surfaces of rubber materials or resin materials. 
     
     
         13 : An aqueous surface-treating anti-adhesive agent according to  claim 12 , wherein the rubber materials are seal materials. 
     
     
         14 : A seal material surface-treated by an aqueous surface-treating anti-adhesive agent according to  claim 13 . 
     
     
         15 : An aqueous surface-treating anti-adhesive agent according to  claim 12 , wherein the rubber materials are sliding members. 
     
     
         16 : A sliding member surface-treated by an aqueous surface-treating anti-adhesive agent according to  claim 15 . 
     
     
         17 : A method for surface-treating rubber materials to prevent sticking of the rubber materials to themselves and prevent sticking of the rubber materials to other materials which method comprises:
 a) providing an aqueous surface-treating anti-adhesive agent, which comprises a silicone oil aqueous emulsion, a polyurethane resin aqueous emulsion, and a silane compound represented by the following general formula:   
       
         
           
           
               
               
           
         
       
       (where R 1  and R 2  each are independently an alkyl group having 1-4 carbon atoms, n and m are 1≦n≦3 and m=3−n respectively), and/or a partial hydrolyzate thereof, wherein 100 parts by weight or more of the polyurethane resin in terms of the weight of solid matters is used on the basis of 100 parts by weight in terms of the weight of nonvolatile matters of the silicone oil,
 wherein the polyurethane resin aqueous emulsion is a mixture of (a) an aqueous emulsion containing a hydrazide and a carbonyl group-containing polyurethane resin, and (b) a silanol-modified polyurethane resin aqueous emulsion wherein the silanol-modified polyurethane resin has, in the polyurethane structure, silanol groups, which turn to siloxane bonds by condensation cross-linking reaction after surface treating, in a ratio by weight of solid matter sum total of (a):(b)=5-95:95-10, and 
 wherein when applied to rubber seal members the anti-adhesive agent prevents sticking of the rubber seal members to themselves and prevents sticking of the rubber seal members to other materials; and 
 (b) surface-treating rubber materials with the aqueous surface-treating anti-adhesive agent.