US2014123629A1PendingUtilityA1

Ammonia slip detection

Assignee: INT ENGINE INTELLECTUAL PROPPriority: Nov 2, 2012Filed: Jul 16, 2013Published: May 8, 2014
Est. expiryNov 2, 2032(~6.3 yrs left)· nominal 20-yr term from priority
F01N 2560/14F01N 2900/1616Y02T10/12F01N 2900/1402F01N 11/00F01N 2900/1621B01D 53/9495Y02T10/40F01N 3/2066F01N 2900/08B01D 2251/2062F01N 2560/026B01D 53/9409F01N 2550/02F01N 3/208
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Claims

Abstract

A method of detecting ammonia in the exhaust system includes detecting a predetermined engine operating condition. Upon detecting the predetermined operating condition, the method determines a first NO x conversion efficiency of a catalyst at a first time T 1. The method then injects a reactant into the exhaust upstream of the catalyst and determines a second NO x conversion efficiency at a second time T 2. The method then processes the first and second NO x conversion efficiencies to determine whether an ammonia slip condition exists.

Claims

exact text as granted — not AI-modified
1 . A method of detecting ammonia slip across a catalyst in an exhaust system of an internal combustion engine comprising;
 detecting a preselected operating condition of the engine;   determining a first NO x  conversion efficiency of the catalyst at a first time;   injecting a reductant into the exhaust upstream of the catalyst;   thereafter detecting a second NO x  conversion efficiency of the catalyst at a second time; and   processing the first and second NO x  conversion efficiencies to determine whether an ammonia slip condition exists.   
     
     
         2 . The method of  claim 1 , wherein the reductant comprises ammonia. 
     
     
         3 . The method of  claim 1 , wherein the preselected engine operating condition comprises a steady state condition. 
     
     
         4 . The method of  claim 1 , wherein the step of determining a first NO x  conversion efficiency of the catalyst at a first time further comprises:
 detecting a first upstream NO x  level relative to the catalyst at the first time; and   detecting a first downstream NO x  level relative to the catalyst at the first time.   
     
     
         5 . The method of  claim 1 , wherein the step of determining a second NO x  conversion efficiency of the catalyst at a second time further comprises:
 detecting a second upstream NO x  level relative to the catalyst at the second time; and   detecting a second downstream NO x  level relative to the catalyst at the second time.   
     
     
         6 . The method of  claim 1 , wherein NO x  conversion efficiency is determined in accordance with the following formula: 
       
         
           
             
               Eff 
               = 
               
                 
                   
                     
                       NO 
                       
                         x 
                          
                         
                           - 
                         
                          
                         upstream 
                       
                     
                     - 
                     
                       NO 
                       
                         x 
                          
                         
                           - 
                         
                          
                         downstream 
                       
                     
                   
                   
                     NO 
                     
                       x 
                        
                       
                         - 
                       
                        
                       upstream 
                     
                   
                 
                 · 
                 100 
               
             
           
         
       
       where Eff is NO x  conversion efficiency, NO x-upstream  is the upstream NO x  level and NO x-downstream  is the downstream NO x  level. 
     
     
         7 . The method of  claim 1 , further comprising signaling an ammonia slip condition in response to the NO x  conversion efficiency increasing between the first and second times. 
     
     
         8 . A method of detecting ammonia slip across a catalyst in an exhaust system of an internal combustion engine comprising:
 detecting a preselected operating condition of the engine;   thereafter detecting a first upstream NO x  level relative to the catalyst at a first time;   detecting a first downstream NO x  level relative to the catalyst at a first time;   injecting a reductant into the exhaust upstream of the catalyst;   thereafter detecting a second upstream NO x  level relative to the catalyst at a second time;   detecting a second downstream NO x  level relative to the catalyst at a second time; and   determining a first NO x  conversion efficiency based on the first upstream and first downstream NO x  levels;   determining second NO x  conversion efficiency based on the second upstream and second downstream NO x  levels; and   processing the first and second NO x  conversion efficiencies to determine whether an ammonia slip condition exists.   
     
     
         9 . The method of  claim 8 , wherein NO x  conversion efficiency is determined in accordance with the following formula: 
       
         
           
             
               Eff 
               = 
               
                 
                   
                     
                       NO 
                       
                         x 
                          
                         
                           - 
                         
                          
                         upstream 
                       
                     
                     - 
                     
                       NO 
                       
                         x 
                          
                         
                           - 
                         
                          
                         downstream 
                       
                     
                   
                   
                     NO 
                     
                       x 
                        
                       
                         - 
                       
                        
                       upstream 
                     
                   
                 
                 · 
                 100 
               
             
           
         
         where Eff is NO x  conversion efficiency, NO x-upstream  is the upstream NO x  level and NO x-downstream  is the downstream NO x  level. 
       
     
     
         10 . The method of  claim 9 , wherein the reductant comprises ammonia. 
     
     
         11 . The method of  claim 10 , wherein the preselected engine operating condition comprises a steady state condition. 
     
     
         12 . A system for detecting ammonia in an exhaust system of an internal combustion engine, the exhaust system including a catalyst and an injector upstream of the catalyst for injecting a reductant into the exhaust system, the system comprising:
 an upstream NO x  sensor positioned to detect the level of NO x  in the exhaust stream at a location upstream of the catalyst and produce a responsive upstream NO x  signal;   a downstream NO x  sensor positioned to detect the level of NO x  in the exhaust stream at a location downstream of the catalyst and produce a responsive downstream NO x  signal;   a controller configured to receive the upstream and downstream NO x  signals; detect a preselected engine operating condition; determine a first NO x  conversion efficiency based on the upstream and downstream NO x  levels at a first time; signal the injector to inject reductant into the exhaust system; determine a second NO x  conversion efficiency based on the upstream and downstream NO x  levels at a second time following injection of the reluctant; and process the first and second NO x  conversion efficiencies to determine whether an ammonia slip condition exists.   
     
     
         13 . The system of  claim 12 , wherein the preselected engine operating condition comprises a steady state operating condition. 
     
     
         14 . The method of  claim 12 , wherein NO x  conversion efficiency is determined in accordance with the following formula: 
       
         
           
             
               Eff 
               = 
               
                 
                   
                     
                       NO 
                       
                         x 
                          
                         
                           - 
                         
                          
                         upstream 
                       
                     
                     - 
                     
                       NO 
                       
                         x 
                          
                         
                           - 
                         
                          
                         downstream 
                       
                     
                   
                   
                     NO 
                     
                       x 
                        
                       
                         - 
                       
                        
                       upstream 
                     
                   
                 
                 · 
                 100 
               
             
           
         
         where Eff is NO x  conversion efficiency, NO x-upstream  is the upstream NO x  level and NO x-downstream  is the downstream NO x  level. 
       
     
     
         15 . The method of  claim 12 , wherein the reductant comprises ammonia.

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