Combinations of 4-bromo-2-(4-chlorophenyl)-5-trifluoromethyl)-1h-pyrrole-3-carbonitrile and metal compounds

Abstract

The present invention relates to combinations of 4-bromo-2-(4-chloro-phenyl)-5-(trifluoromethyl)-1H-pyrrole-3-carbonitrile, or a salt thereof, and copper or zinc compounds which provide an improved protecting effect against fouling organisms. More particularly, the present invention relates to compositions comprising a combination of 4-bromo-2-(4-chlorophenyl)-5-(trifluoromethyl)-1H-pyrrole-3-carbonitrile, or a salt thereof, together with one or more copper or zinc compounds selected from Cu 2 O, Cu(OH) 2 , CuSO 4 , copper pyrithione, CuSCN, CuCO 3 , ZnO, ZnCl 2 , ZnSO 4 , zineb, and zinc pyrithione; in respective proportions to provide a synergistic effect against fouling organisms and the use of these compositions for protecting materials against fouling organisms. This invention thus relates to the field of protection of materials, such as underwater objects, protection of wood, wood products, biodegradable materials and coatings.

1 . A composition comprising a combination of 4-bromo-2-(4-chlorophenyl)-5-(trifluoromethyl)-1H-pyrrole-3-carbonitrile, or a salt thereof, as component (I), and as a component (II) a zinc compound selected from ZnCl 2 , ZnSO 4 , and zinc pyrithione; whereby component (I) and one of the components (II) are in respective proportions to provide a synergistic effect against fouling organisms; provided that when the component (II) is zinc pyrithione the ratio by weight of component (I) to zinc pyrithione is 2:1 to 1:2. 
     
     
         2 - 8 . (canceled) 
     
     
         9 . A composition as claimed in  claim 1  wherein the component (II) is ZnCl 2 . 
     
     
         10 . A composition as claimed in  claim 1  wherein the component (II) is ZnSO 4 . 
     
     
         11 . (canceled) 
     
     
         12 . A combination as claimed in  claim 1  wherein the component (II) is zinc pyrithione. 
     
     
         13 . A composition according to  claim 1  wherein the ratio by weight of component (I) to one of the components (II) is 10:1 to 1:10. 
     
     
         14 . A composition according to  claim 1  wherein the ratio by weight of component (I) to one of the components (II) is 3:1 to 1:3. 
     
     
         15 . A composition as claimed in  claim 1  wherein the amount of component (I) ranges from 1 wt % to 40 wt % based on the total weight of the composition. 
     
     
         16 . (canceled) 
     
     
         17 . A method of protecting materials against fouling organisms, wherein the said method comprises administration or application of an antifouling effective amount of a composition according to  claim 1 . 
     
     
         18 . A method of disinfecting ballast water by adding an antifouling effective amount of a composition according to  claim 1 . 
     
     
         19 . A product containing
 (a) a composition comprising 4-bromo-2-(4-chloro-phenyl)-5-(trifluoromethyl)-1H-pyrrole-3-carbonitrile, or a salt thereof, as component (I), and   (b) a composition comprising a component (II), selected from ZnCl 2 , ZnSO 4 , and zinc pyrithione, as a combination for simultaneous or sequential use, wherein said (a) and (b) are in respective proportions to provide a synergistic effect against fouling organisms; provided that when the component (II) is zinc pyrithione the ratio by weight of component (I) to zinc pyrithione is 2:1 to 1:2.