Radiological image conversion panel, method of manufacturing the same, and radiological image detection apparatus

Abstract

A radiological image conversion panel 2 provided with a support 11 and a phosphor 18 which is formed on the support and contains a fluorescent material that emits fluorescence by radiation exposure. The phosphor includes a columnar section 34 formed by a group of columnar crystals which are obtained through columnar growth of crystals of the fluorescent material, and a non-columnar section 36 . The columnar section and the non-columnar section are integrally formed to overlap in a crystal growth direction of the columnar crystals, and a porosity at the columnar section side of the non-columnar section is higher than a porosity at the support side of the non-columnar section.

1 . A radiological image conversion panel provided with a support and a phosphor which is formed on the support and contains a fluorescent material that emits fluorescence by radiation exposure,
 wherein the phosphor comprises a columnar section formed by a group of columnar crystals which are obtained through columnar growth of crystals of the fluorescent material and a non-columnar section,   the columnar section and the non-columnar section are integrally formed to overlap in a crystal growth direction of the columnar crystals, and   a porosity at the columnar section side of the non-columnar section is higher than a porosity at the support side of the non-columnar section.   
     
     
         2 . The radiological image conversion panel of  claim 1 , wherein the non-columnar section comprises a plurality of layers with different porosities, and
 a porosity of an upper layer in contact with the columnar section is higher than a porosity of a lower layer in contact with the support.   
     
     
         3 . The radiological image conversion panel of  claim 2 , wherein the porosity of the lower layer is 15% or less. 
     
     
         4 . The radiological image conversion panel of  claim 2 , wherein the porosity of the upper layer ranges from 5 to 20%. 
     
     
         5 . The radiological image conversion panel of  claim 2 , wherein a thickness of the lower layer ranges from 5 to 50 μm. 
     
     
         6 . The radiological image conversion panel of  claim 2 , wherein a thickness of the upper layer ranges from 5 to 125 μm. 
     
     
         7 . The radiological image conversion panel of  claim 1 , wherein the non-columnar section has a porosity which gradually increases from a side in contact with the support to a side in contact with the columnar section. 
     
     
         8 . The radiological image conversion panel of  claim 1 , wherein the non-columnar section is formed by comprising a group of spherical crystals obtained by growing crystals of the fluorescent material in a substantially spherical shape, and at least a part of the group of the spherical crystals are fused in an in-plane direction. 
     
     
         9 . A method of manufacturing the radiological image conversion panel of  claim 1 , wherein the non-columnar section and the columnar section are formed in this order on the support by depositing crystals of the fluorescent material on the support by a vapor deposition method,
 wherein when the non-columnar section is formed, a deposition rate of the crystals of the fluorescent material is varied.   
     
     
         10 . The method of  claim 9 , wherein when the non-columnar section is formed, an initial-stage deposition rate of the crystals of the fluorescent material is set to be higher than a final-stage deposition rate of the crystals of the fluorescent material. 
     
     
         11 . A radiological image detection apparatus provided with the radiological image conversion panel of  claim 1 , and a sensor panel which detects fluorescence generated from the radiological image conversion panel and converts the fluorescence into an electrical signal. 
     
     
         12 . The radiological image detection apparatus of  claim 11 , wherein the radiological image conversion panel and the sensor panel are bonded to each other so that a surface of the columnar section side of the phosphor faces the sensor panel. 
     
     
         13 . The radiological image detection apparatus of  claim 12 , which has a radiation entrance surface at the sensor panel side. 
     
     
         14 . The radiological image detection apparatus of  claim 12 , which has a radiation entrance surface at the radiological image conversion panel side. 
     
     
         15 . A radiological image detection apparatus provided with a phosphor which contains a fluorescent material that emits fluorescence by radiation exposure and a sensor panel which detects fluorescence generated from the phosphor and converts the fluorescence into an electrical signal,
 wherein the phosphor is formed on the sensor panel and comprises a columnar section formed by a group of columnar crystals which are obtained through columnar growth of crystals of the fluorescent material and a non-columnar section,   the non-columnar section is in contact with the sensor panel,   the columnar section and the non-columnar section are integrally formed to overlap in a crystal growth direction of the columnar section, and   the non-columnar section comprises a plurality of layers with different porosities, and a porosity of a lower layer in contact with the sensor panel is smaller than a porosity of an upper layer in contact with a porosity of an upper layer in contact with the columnar section, and   a radiation entrance surface is provided at the sensor panel side.   
     
     
         16 . The radiological image conversion panel of  claim 15 , wherein the porosity of the lower layer is 15% or less. 
     
     
         17 . The radiological image conversion panel of  claim 15 , wherein a thickness of the lower layer ranges from 5 to 50 μm. 
     
     
         18 . The radiological image conversion panel of  claim 15 , wherein a thickness of the upper layer ranges from 5 to 125 μm. 
     
     
         19 . A radiological image detection apparatus provided with a phosphor which contains a fluorescent material that emits fluorescence by radiation exposure and a sensor panel which detects fluorescence generated from the phosphor and converts the fluorescence into an electrical signal,
 wherein the phosphor is formed on the sensor panel and comprises a columnar section formed by a group of columnar crystals which are obtained through columnar growth of crystals of the fluorescent material and a non-columnar section,   the non-columnar section is in contact with the sensor panel,   the columnar section and the non-columnar section are integrally formed to overlap in a crystal growth direction of the columnar section,   the non-columnar section has a porosity which gradually increases from a side in contact with the sensor panel to a side in contact with the columnar section, and   a radiation entrance surface is provided at the sensor panel side.