Adhesive for polarizing plate, and polarizing plate comprising same

Abstract

Provided are an adhesive for a polarizing plate and a polarizing plate comprising the same, and more particularly, an adhesive composition for a polarizing plate comprising one or more acrylic monomers having a hydrophilic group, a radical polymerization initiator, an epoxy resin, and a cationic photopolymerization initiator, as well as a polarizing plate comprising a polarizer, a polymer film adhered to one side or both sides of the polarizer, and an adhesive layer for bonding the polarizer and the polymer film, in which the adhesive layer is formed of an adhesive composition comprising one or more acrylic monomers having a hydrophilic group, a radical polymerization initiator, an epoxy resin, and a cationic photopolymerization initiator.

1 . An adhesive composition for a polarizing plate comprising:
 one or more acrylic monomers having a hydrophilic group;   a radical polymerization initiator;   an epoxy resin; and   a cationic photopolymerization initiator.   
     
     
         2 . The adhesive composition for a polarizing plate of  claim 1 , wherein the adhesive composition for a polarizing plate comprises 20 to 80 parts by weight of the one or more acrylic monomers having a hydrophilic group, 0.5 to 10 parts by weight of the radical polymerization initiator, 30 to 80 parts by weight of the epoxy resin and 1 to 10 parts by weight of the cationic photopolymerization initiator. 
     
     
         3 . The adhesive composition for a polarizing plate of  claim 1 , wherein the adhesive composition for a polarizing plate comprises 20 to 50 parts by weight of the one or more acrylic monomers having a hydrophilic group, 0.5 to 5 parts by weight of the radical polymerization initiator, 20 to 60 parts by weight of the epoxy resin and 1 to 7 parts by weight of the cationic photopolymerization initiator. 
     
     
         4 . The adhesive composition for a polarizing plate of  claim 1 , wherein the adhesive composition for a polarizing plate comprises 30 parts by weight of the one or more acrylic monomers having a hydrophilic group, 3 parts by weight of the radical polymerization initiator, 40 parts by weight of the epoxy resin and 3 parts by weight of the cationic photopolymerization initiator. 
     
     
         5 . The adhesive composition for a polarizing plate of  claim 1 , wherein the hydrophilic group is a hydroxy group (—OH). 
     
     
         6 . The adhesive composition for a polarizing plate of  claim 1 , wherein the epoxy resin is comprised of a combination of a first epoxy resin compound including one or more epoxidized aliphatic cyclic groups and a second epoxy compound including one or more glycidyl ether groups. 
     
     
         7 . The adhesive composition for a polarizing plate of  claim 6 , wherein the first epoxy compound is selected from the group consisting of 3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexane carboxylate, bis(3,4-epoxycyclohexylmethyl)adipate dicyclopentadiene dioxide, limonene dioxide, and 4-vinylcyclohexene dioxide. 
     
     
         8 . The adhesive composition for a polarizing plate of  claim 6 , wherein the second epoxy compound is selected from the group consisting of 1,4-cyclohexanedimethanol diglycidyl ether, a novolac-based epoxy, a bisphenol A-based epoxy, a bisphenol F-based epoxy, a brominated bisphenol-based epoxy, 1,6-hexanediol diglycidyl ether, trimethylolpropane triglycidyl ether, n-butyl glycidyl ether, aliphatic glycidyl ether(C12-C14), 2-ethylhexyl glycidyl ether, phenyl glycidyl ether, o-cresyl glycidyl ether, and nonyl phenyl glycidyl ether. 
     
     
         9 . The adhesive composition for a polarizing plate of  claim 6 , wherein the adhesive composition for a polarizing plate comprises 15 to 40 parts by weight of the first epoxy compound and 15 to 40 parts by weight of the second epoxy compound based on 100 parts by weight of the adhesive composition for a polarizing plate. 
     
     
         10 . The adhesive composition for a polarizing plate of  claim 6 , wherein the first and second epoxy compounds are comprised in a weight ratio range of 1:3 to 3:1. 
     
     
         11 . The adhesive composition for a polarizing plate of  claim 1 , wherein the acrylic monomer having a hydrophilic group is selected from the group consisting of hydroxyethyl acrylate (HEA), hydroxyethyl methacrylate, hydroxypropyl acrylate, hydroxypropyl methacrylate, hydroxybutyl acrylate, or a mixture thereof. 
     
     
         12 . The adhesive composition for a polarizing plate of  claim 1 , wherein the adhesive composition for a polarizing plate further comprises greater than 0 and equal to or less than 50 parts by weight of a monofunctional hydrophobic monomer based on 100 parts by weight of a total adhesive composition. 
     
     
         13 . The adhesive composition for a polarizing plate of  claim 12 , wherein the monofunctional hydrophobic monomer comprises at least one monomer selected from the group consisting of isobornyl acrylate (IBOA), benzyl(meth)acrylate, nonyl(meth)acrylate, isobutyl(meth)acrylate, isodecyl acrylate, lauryl acrylate, stearyl acrylate, 2-ethyl hexyl acrylate, polyethylene glycol methacrylate, octyl/decyl acrylate, phenoxyethyl acrylate (PEA), nonylphenol ethoxylate acrylate, dicyclopentenyl acrylate, dicyclopentenyl oxyethyl acrylate, propylene glycol mono(meth)acrylate, and ethoxyethoxy ethyl acrylate. 
     
     
         14 . The adhesive composition for a polarizing plate of  claim 12 , wherein the monofunctional hydrophobic monomer is phenoxyethyl acrylate and isobornyl acrylate. 
     
     
         15 . The adhesive composition for a polarizing plate of  claim 14 , wherein the adhesive composition for a polarizing plate comprises 20 to 80 parts by weight of hydroxyethyl acrylate, greater than 0 and equal to or less than 30 parts by weight of phenoxyethyl acrylate, greater than 0 and equal to or less than 20 parts by weight of isobornyl acrylate, 30 to 80 parts by weight of an epoxy resin, 1 to 7 parts by weight of a cationic photopolymerization initiator, and 0.5 to 5 parts by weight of a radical polymerization initiator. 
     
     
         16 . The adhesive composition for a polarizing plate of  claim 1 , wherein the adhesive composition for a polarizing plate has a viscosity range of 10 cP to 30 cP at 25° C. 
     
     
         17 . The adhesive composition for a polarizing plate of  claim 1 , wherein the adhesive composition for a polarizing plate further comprises greater than 0 and equal to or less than 4 parts by weight of urethane acrylate. 
     
     
         18 . A polarizing plate comprising:
 a polarizer;   a polymer film adhered to one side or both sides of the polarizer; and   an adhesive layer for bonding the polarizer and the polymer film,   wherein the adhesive layer is formed of an adhesive composition comprising one or more acrylic monomers having a hydrophilic group, a radical polymerization initiator, an epoxy resin, and a cationic photopolymerization initiator.   
     
     
         19 . The polarizing plate of  claim 18 , wherein the polarizing plate comprises 20 to 80 parts by weight of the one or more acrylic monomers having a hydrophilic group, 0.5 to 10 parts by weight of the radical polymerization initiator, 30 to 80 parts by weight of the epoxy resin and 1 to 10 parts by weight of the cationic photopolymerization initiator. 
     
     
         20 . The polarizing plate of  claim 19 , wherein the hydrophilic group is a hydroxy group (—OH). 
     
     
         21 . The polarizing plate of  claim 18 , wherein the epoxy resin is comprised of a combination of a first epoxy resin compound including one or more epoxidized aliphatic cyclic groups and a second epoxy compound including one or more glycidyl ether groups. 
     
     
         22 . The polarizing plate of  claim 18 , wherein the first epoxy compound is selected from the group consisting of 3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexane carboxylate, bis(3,4-epoxycyclohexylmethyl)adipate dicyclopentadiene dioxide, limonene dioxide, and 4-vinylcyclohexene dioxide. 
     
     
         23 . The polarizing plate of  claim 18 , wherein the second epoxy compound is selected from the group consisting of 1,4-cyclohexanedimethanol diglycidyl ether, a novolac-based epoxy, a bisphenol A-based epoxy, a bisphenol F-based epoxy, a brominated bisphenol-based epoxy, 1,6-hexanediol diglycidyl ether, trimethylolpropane triglycidyl ether, n-butyl glycidyl ether, aliphatic glycidyl ether(C12-C14), 2-ethylhexyl glycidyl ether, phenyl glycidyl ether, o-cresyl glycidyl ether, and nonyl phenyl glycidyl ether. 
     
     
         24 . The polarizing plate of  claim 21 , wherein the polarizing plate comprises 15 to 40 parts by weight of the first epoxy compound and 15 to 40 parts by weight of the second epoxy compound based on 100 parts by weight of an adhesive composition for a polarizing plate. 
     
     
         25 . The polarizing plate of  claim 21 , wherein the first and second epoxy compounds are comprised in a weight ratio range of 1:3 to 3:1. 
     
     
         26 . The polarizing plate of  claim 18 , wherein the acrylic monomer having a hydrophilic group is selected from the group consisting of hydroxyethyl acrylate (HEA), hydroxyethyl methacrylate, hydroxypropyl acrylate, hydroxypropyl methacrylate, hydroxybutyl acrylate, or a mixture thereof. 
     
     
         27 . The polarizing plate of  claim 18 , wherein the adhesive composition for a polarizing plate further comprises greater than 0 and equal to or less than 50 parts by weight of a monofunctional hydrophobic monomer based on 100 parts by weight of a total adhesive composition. 
     
     
         28 . The polarizing plate of  claim 27 , wherein the monofunctional hydrophobic monomer comprises at least one monomer selected from the group consisting of isobornyl acrylate (IBOA), benzyl(meth)acrylate, nonyl(meth)acrylate, isobutyl(meth)acrylate, isodecyl acrylate, lauryl acrylate, stearyl acrylate, 2-ethyl hexyl acrylate, polyethylene glycol methacrylate, octyl/decyl acrylate, phenoxyethyl acrylate (PEA), nonylphenol ethoxylate acrylate, dicyclopentenyl acrylate, dicyclopentenyl oxyethyl acrylate, propylene glycol mono(meth)acrylate, and ethoxyethoxy ethyl acrylate. 
     
     
         29 . The polarizing plate of  claim 27 , wherein the monofunctional hydrophobic monomer is phenoxyethyl acrylate and isobornyl acrylate. 
     
     
         30 . The polarizing plate of  claim 29 , wherein the adhesive composition for a polarizing plate comprises 20 to 80 parts by weight of hydroxyethyl acrylate, greater than 0 and equal to or less than 30 parts by weight of phenoxyethyl acrylate, greater than 0 and equal to or less than 20 parts by weight of isobornyl acrylate, 30 to 80 parts by weight of an epoxy resin, 1 to 7 parts by weight of a cationic photopolymerization initiator, and 0.5 to 5 parts by weight of a radical polymerization initiator. 
     
     
         31 . The polarizing plate of  claim 18 , wherein the adhesive composition for a polarizing plate has a viscosity range of 10 cP to 30 cP at 25° C. 
     
     
         32 . The polarizing plate of  claim 18 , wherein the adhesive composition for a polarizing plate further comprises greater than 0 and equal to or less than 4 parts by weight of urethane acrylate. 
     
     
         33 . The polarizing plate of  claim 18 , wherein the polymer film is at least one selected from the group consisting of an acrylic film, a polyethylene terephthalate (PET) film, a PET film treated with an acrylic primer, a triacetyl cellulose (TAC) film, a cycloolefin polymer (COP) film, a polycarbonate film, and a polynorbornene (PNB)-based film. 
     
     
         34 . An optical device comprising the polarizing plates of  claim 18 .