Organopolysilmethylene-siloxane and a cured product thereof

Abstract

Organopolysilmethylene-siloxane of the formula (1): wherein each R 1 is, independently of one another, an unsubstituted or substituted monovalent hydrocarbon group having 1 to 10 carbon atoms other than an alkenyl group, an alkoxy group, a hydroxy group, and a halogen atom; each R 2 is, independently of one another, an unsubstituted or substituted monovalent hydrocarbon group having 1 to 10 carbon atoms other than an alkenyl group, an alkoxy group, a hydroxy group, a halogen atom, and (R 1 ) 3 SiCH 2 —, wherein each R 3 is, independently of one another, a hydrogen atom and an alkyl group having 1 to 4 carbon atoms; k is an integer of 1 to 100; and n is an integer of 1 to 1000; said organopolysilmethylene-siloxane having, in a molecule, at least two out of alkoxy groups, hydroxy groups, and halogen atoms bonded to one or more silicon atoms.

What is claimed is: 
     
         1 . An organopolysilmethylene-siloxane composition comprising:
 (A) 1 to 100 parts by weight of an organopolysilmethylene-siloxane represented by the following general formula (1):   
       
         
           
           
               
               
           
         
       
       wherein: R 1  is, independently of each other, a group selected from the group consisting of an unsubstituted or substituted monovalent hydrocarbon group having 1 to 10 carbon atoms other than an alkenyl group, an alkoxy group, a hydroxy group, and a halogen atom; R 2  is, independently of each other, a group selected from the group consisting of an unsubstituted or substituted monovalent hydrocarbon group having 1 to 10 carbon atoms other than an alkenyl group, an alkoxy group, a hydroxy group, a halogen atom, and (R 1 ) 3 SiCH 2 —; R 3  is, independently of each other, a group selected from the group consisting of a hydrogen atom and an alkyl group having 1 to 4 carbon atoms; k is an integer of 1 to 100; and n is an integer of 1 to 1000, said organopolysilmethylene-siloxane having, in a molecule, at least two out of alkoxy groups, hydroxy groups, and halogen atoms bonded to one or more silicon atoms;
 (B) 0 to 99 parts by weight, provided that a total of the amounts of (A) and (B) is 100 parts by weight, of an organopolysiloxane represented by the following general formula: 
 
       
         
           
           
               
               
           
         
       
       wherein R 1  is, independently of each other, a group selected from the group consisting of an unsubstituted or substituted monovalent hydrocarbon group having 1 to 10 carbon atoms other than an alkenyl group, an alkoxy group, a hydroxy group, and a halogen atom, and m is an integer of 0 to 300; and having, in a molecule, at least two out of alkoxy groups, hydroxy groups and halogen atoms bonded to one or more silicon atoms;
 (C) 1 to 30 parts by weight of a curing agent which is an organosilicon compound represented by the following general formula:
   R a SiX 4-a   (5)
 
 
 
       and/or a partial hydrolysis condensate thereof, wherein R is, independently of each other, a group selected from the group consisting of an unsubstituted or substituted monovalent hydrocarbon group having 1 to 10 carbon atoms; X is, independently of each other, a group selected from the group consisting of ketoxime, alkoxy, and 1-methylvinyloxy groups; and a is 0, 1, or 2; and
 (D) a catalytic amount of a curing catalyst. 
 
     
     
         2 . An organopolysilmethylene-siloxane composition comprising
 (A) 30 to 100 parts by weight of the organopolysilmethylene-siloxane according to  claims 1 ;   (B) 0 to 70 parts by weight of the organopolysiloxane according to  claim 1 , provided that a total of the amounts of (A) and (B) is 100 parts by weight;   (C) 1 to 30 parts by weight of the curing agent according to  claim 1 ; and   (D) a catalytic amount of a curing catalyst.   
     
     
         3 . The organopolysilmethylene-siloxane composition according to  claim 1 , wherein the organopolysiloxane (B) is represented by the following formula (6): 
       
         
           
           
               
               
           
         
       
       wherein R 1  is, independently of each other, a monovalent hydrocarbon group having 1 to 10 carbon atoms other than an alkenyl group and m is an integer of 0 to 300. 
     
     
         4 . A cured organopolysilmethylene-siloxane product from an organopolysilmethylene-siloxane composition comprising:
 (A) 1 to 100 parts by weight of an organopolysilmethylene-siloxane represented by the following general formula (1):   
       
         
           
           
               
               
           
         
       
       wherein: R 1  is, independently of each other, a group selected from the group consisting of an unsubstituted or substituted monovalent hydrocarbon group having 1 to 10 carbon atoms other than an alkenyl group, an alkoxy group, a hydroxy group, and a halogen atom; R 2  is, independently of each other, a group selected from the group consisting of an unsubstituted or substituted monovalent hydrocarbon group having 1 to 10 carbon atoms other than an alkenyl group, an alkoxy group, a hydroxy group, a halogen atom, and (R 1 ) 3 SiCH 2 —; R 3  is, independently of each other, a group selected from the group consisting of a hydrogen atom and an alkyl group having 1 to 4 carbon atoms; k is an integer of 1 to 100; and n is an integer of 1 to 1000, said organopolysilmethylene-siloxane having, in a molecule, at least two out of alkoxy groups, hydroxy groups, and halogen atoms bonded to one or more silicon atoms;
 (B) 0 to 99 parts by weight, provided that a total of the amounts of (A) and (B) is 100 parts by weight, of an organopolysiloxane represented by the following general formula: 
 
       
         
           
           
               
               
           
         
       
       wherein R 1  is, independently of each other, a group selected from the group consisting of an unsubstituted or substituted monovalent hydrocarbon group having 1 to 10 carbon atoms other than an alkenyl group, an alkoxy group, a hydroxy group, and a halogen atom, and m is an integer of 0 to 300; and having, in a molecule, at least two out of alkoxy groups, hydroxy groups and halogen atoms bonded to one or more silicon atoms;
 (C) 1 to 30 parts by weight of a curing agent which is an organosilicon compound represented by the following general formula:
   R a SiX 4-a   (5)
 
 
 
       and/or a partial hydrolysis condensate thereof, wherein R is, independently of each other, a group selected from the group consisting of an unsubstituted or substituted monovalent hydrocarbon group having 1 to 10 carbon atoms; X is, independently of each other, a group selected from the group consisting of ketoxime, alkoxy, and 1-methylvinyloxy groups; and a is 0, 1, or 2; and
 (D) a catalytic amount of a curing catalyst. 
 
     
     
         5 . The organopolysilmethylene-siloxane composition according to any one of  claims 1  to  3 , wherein the organopolysilmethylene-siloxane is represented by the following formula (2): 
       
         
           
           
               
               
           
         
       
       wherein R 2  is, independently of each other, a group selected from the group consisting of a methyl group and Y(CH 3 ) 2 SiCH 2 —, R 3  is a group selected from the group consisting of a hydrogen atom and an alkyl group having 1 to 4 carbon atoms, Y is a group selected from the group consisting of an alkoxy group having 1 to 4 carbon atoms and a hydroxy group, k is an integer of 1 to 100, and n is an integer of 1 to 1000. 
     
     
         6 . An insulating material, a sealing material, an electric part, an electronic part, or an automobile part comprising the cured organopolysilmethylene-siloxane product according to  claim 4 .