Composition for coating agent

Abstract

A composition for a coating agent, which contains a fluoropolymer (component A) containing units (A2) having a compound represented by formula (1) reacted with units based on a hydroxy group-containing monomer and units (A1) based on a fluoroolefin, and component B represented by formula (2), wherein the proportion of the component A is from 10 to 90 mass % to the total content of the component A and the component B; wherein formula (1) is OCN(CH 2 ) m SiX n R 3-n , such that R is a hydrogen atom or a monovalent hydrocarbon group, X is an alkoxy group, n is an integer of from 1 to 3, and m is an integer of from 1 to 5; formula (2) is (R 1 ) 4-a Si(OR 2 ) a , such that each of R 1 and R 2 which are independent of each other, is a monovalent hydrocarbon group, and “a” is an integer of from 1 to 4.

1 . A composition for a coating agent, which comprises component A, component B, and component C, wherein the proportion of the component A is from 10 to 90 mass % to the total content of the component A and the component B, and the proportion of the component C is from 0.01 to 5 mass % to the total solid content of the composition for a coating agent:
 component A: a fluoropolymer containing units (Al) based on a fluoroolefin and units (A2) having a compound of formula (1) reacted with units based on a hydroxy group-containing monomer,   component B: a compound of formula (2) and/or a partially hydrolyzed condensate of the compound of formula (2):
   OCN(CH 2 ) m SiX n R 3-n    (1)
 
   wherein R is a hydrogen atom or a C 1-10  monovalent hydrocarbon group, X is a C 1-5  alkoxy group, n is an integer of from 1 to 3, and m is an integer of from 1 to 5,
   (R 1 ) 4-a Si(OR 2 ) a    (2)
 
   wherein each of R 1  and R 2 , which are independent of each other, is a C 1-10  monovalent hydrocarbon group, and “a” is an integer of from 1 to 4,   component C: at least one curing catalyst selected from the group consisting of a C 1-8  monoalkyl phosphate and a C 1-8  dialkyl phosphate.   
     
     
         2 . The composition for a coating agent according to  claim 1 , wherein the units (A2) are
 polymerized units obtained by polymerizing a monomer which is a reaction product of reacting the hydroxy group-containing monomer with the compound of formula (1), or   units having the compound of formula (1) reacted with hydroxy groups in polymerized units of the hydroxy group-containing monomer.   
     
     
         3 . The composition for a coating agent according to  claim 1 , wherein the component A is a fluoropolymer containing the units (A1) and the units (A2) as essential units and optionally containing units (A3) which are units other than the units (A1) and which have no functional group, and units (A4) based on a hydroxy group-containing monomer. 
     
     
         4 . The composition for a coating agent according to  claim 3 , wherein in the component A, the proportion of the units (A1) is from 10 to 99 mol % and the proportion of the units (A2) is from 1 to 90 mol % to the total content of the units (A1) and the units (A2), the proportion of the units (A3) which are units other than the units (A1) and which have no functional group is from 0 to 89 mol % to the total content of all the units, and the proportion of the units (A4) based on a hydroxy group-containing monomer is from 0 to 30 mol % to the total content of all the units. 
     
     
         5 . The composition for a coating agent according to  claim 1 , wherein the compound of formula (1) is at least one compound selected from the group consisting of γ-isocyanatopropyltrimethoxysilane, γ-isocyanatopropyltriethoxysilane, γ-isocyanatopropylmethyldimethoxysilane, γ-isocyanatopropylmethyldiethoxysilane, γ-isocyanatopropyldimethylmethoxysilane, γ-isocyanatopropyldimethylethoxysilane, δ-isocyanatobutyltrimethoxysilane, δ-isocyanatobutyltriethoxysilane, β-isocyanatoethyltrimethoxysilane and β-isocyanatoethyltriethoxysilane. 
     
     
         6 . The composition for a coating agent according to  claim 1 , wherein the hydroxy group-containing monomer is at least one monomer selected from the group consisting of a hydroxyalkyl vinyl ether, an ethylene glycol monovinyl ether, a hydroxyalkyl allyl ether, a hydroxyalkyl vinyl ester, a hydroxyalkyl allyl ester and a hydroxyalkyl (meth)acrylate. 
     
     
         7 . The composition for a coating agent according to  claim 1 , wherein the component B is at least one compound selected from the group consisting of tetramethoxysilane, tetraethoxysilane, methyltrimethoxysialne, methyltriethoxysilane, phenyltrimethoxysilane, phenyltriethoxysilane, hexyltrimethoxysilane, hexyltriethoxysilane, decyltrimethoxysilane, trifluoropropyltrimethoxysilane, dimethyldimethoxysilane, dimethyldiethoxysilane, diphenyldimethoxysilane and diphenyldiethoxysialne, and/or a partially hydrolyzed condensate of the compound. 
     
     
         8 . The composition for a coating agent according to  claim 1 , wherein the fluoroolefin is tetrafluoroethylene and/or trifluoroethylene. 
     
     
         9 - 10 . (canceled) 
     
     
         11 . The composition for a coating agent according to  claim 1 , further comprising a weak solvent as component D, wherein component D is at least one weak solvent selected from the group consisting of gasoline, coal tar naphtha, solvent naphtha, petroleum ether, petroleum naphtha, petroleum benzin, terpin oil, mineral spirit, mineral thinner, petroleum spirit, white spirit, and mineral turpentine. 
     
     
         12 . The composition for a coating agent according to  claim 1 , further comprising titanium oxide.