Cyclopropene amine compounds

Abstract

Methods of applying cyclopropene amine derivatives and compositions thereof to inhibit ethylene receptors in plants and plant material are disclosed. Methods include applying to the plant an effective ethylene response-inhibiting amount of at least one cyclopropene amine compound or composition thereof. Cyclopropene amine compounds, enantiomers, stereoisomers or salts thereof are also provided.

That which is claimed is: 
     
         1 . A compound having the following structure: 
       
         
           
           
               
               
           
         
       
       or
 an enantiomer, stereoisomer or a salt thereof. 
 
     
     
         2 . The compound of  claim 1 , wherein the compound is N-(cycloprop-1-en ylmethyl)-N-ethylethanamine. 
     
     
         3 . A composition comprising:
 (a) A compound having the following structure:   
       
         
           
           
               
               
           
         
       
       or
 an enantiomer, stereoisomer or a salt thereof; and 
 (b) an adjuvant. 
 
     
     
         4 . The composition of  claim 3 , wherein the adjuvant is an agriculturally acceptable carrier. 
     
     
         5 . The compound of  claim 1 , wherein the salt of the compound is selected from the group consisting of phosphate, acetate, formate, carbonate, hydrobromide, hydrochloride, sulfate, bisulfate, nitrate, trifluoroacetate, oxalate, valerate, oleate, palmitate, stearate, laurate, borate, benzoate, lactate, tosylate, citrate, maleate, fumarate, succinate, tartrate, naphthylate, mesylate, glucoheptonate, lactiobionate and laurylsulfonate salts. 
     
     
         6 . The compound of  claim 1 , wherein the salt of the compound is selected from the group consisting of phosphate, acetate, formate and carbonate salts. 
     
     
         7 . The compound of  claim 1 , wherein the salt of the compound is a carbonate salt. 
     
     
         8 . A method of inhibiting an ethylene response in a plant, comprising applying to the plant an effective ethylene response-inhibiting amount of a compound having the following structure: 
       
         
           
           
               
               
           
         
       
       or 
       an enantiomer, stereoisomer or a salt thereof. 
     
     
         9 . The method of  claim 8 , wherein said salt of the compound is selected from the group consisting of phosphate, acetate, formate, carbonate, hydrobromide, hydrochloride, sulfate, bisulfate, nitrate, trifluoroacetate, oxalate, valerate, oleate, palmitate, stearate, laurate, borate, benzoate, lactate, tosylate, citrate, maleate, fumarate, succinate, tartrate, naphthylate, mesylate, glucoheptonate, lactiobionate and laurylsulfonate salts. 
     
     
         10 . The method of  claim 8 , wherein said salt of the compound is selected from the group consisting of phosphate, acetate, formate and carbonate salts. 
     
     
         11 . The method of  claim 8 , wherein said salt of the compound is a carbonate salt. 
     
     
         12 . The method of  claim 8 , wherein application is carried out by contacting said plant to a gas of said compound. 
     
     
         13 . The method of  claim 8 , wherein application is carried out by contacting said plant to a solid comprising said compound. 
     
     
         14 . The method of  claim 8 , wherein application is carried out by contacting said plant to a gas, salt or mixture thereof. 
     
     
         15 . The method of  claim 8 , wherein application is carried out by applying a spray comprising said compound. 
     
     
         16 . The method of  claim 8 , wherein application is carried out by dipping said plant in a composition comprising said compound. 
     
     
         17 . The method of  claim 8 , wherein application is carried out by addition of said compound to a container containing said plant. 
     
     
         18 . The method of  claim 8 , wherein said plant is a cut flower. 
     
     
         19 . The method of  claim 8 , wherein said ethylene response is one or more of ripening or senescence of flowers, fruits, and vegetables; abscission of foliage, flowers, and fruit; the shortening of life of ornamental plants, cut flowers, shrubbery, seeds, or dormant seedlings; inhibition of growth; stimulation of growth; auxin activity; inhibition of terminal growth; control of apical dominance; increase in branching; increase in tillering; changing the morphology of plants; modifying the susceptibility to plant pathogens such as fungi; changing bio-chemical compositions; inducing pest resistance; abortion or inhibition of flowering or seed development; lodging effects; stimulation of seed germination; breaking of dormancy; hormone effects; and epinasty effects. 
     
     
         20 . The method of  claim 8 , wherein said compound can be applied in a closed system. 
     
     
         21 . The method of  claim 8 , wherein said compound can be applied in an open system. 
     
     
         22 . The method of  claim 8 , wherein said plant is a whole plant and or any portions thereof, a field crop, landscape plant, potted plant, cut flower, or harvested fruit or vegetable. 
     
     
         23 . A method of inhibiting an ethylene response in a plant grown in a field crop, comprising applying to the field crop an effective ethylene response-inhibiting amount of a spray formulation comprising the following compound: 
       
         
           
           
               
               
           
         
       
       or 
       an enantiomer, stereoisomer or a salt thereof. 
     
     
         24 . The method of  claim 23 , wherein said compound is a salt. 
     
     
         25 . A method of prolonging the life of a landscape plant comprising applying to the landscape plant an effective ethylene response-inhibiting amount of a formulation comprising the following compound: 
       
         
           
           
               
               
           
         
       
       or 
       an enantiomer, stereoisomer or a salt thereof.