Gasoline Composition, Methods and Use

Abstract

A gasoline composition comprising, as an additive, one or more quaternary ammonium salt(s) (i) formed by the reaction of a compound of formula (A): and a compound formed by the reaction of a hydrocarbyl-substituted acylating agent and an amine of formula (B1) or (B2): wherein R is an optionally substituted alkyl, alkenyl, aryl or alkylaryl group; R 1 is an alkyl, aryl or alkylaryl group having up to 36 carbon atoms; R 2 and R 3 are the same or different alkyl groups having from 1 to 36 carbon atoms; X is an alkylene group having from 1 to 20 carbon atoms; n is from 0 to 20; m is from 1 to 5; and R 4 is hydrogen or a C 1 to C 36 alkyl group.

1 . A gasoline composition comprising, as an additive, one or more quaternary ammonium salt(s) (i) formed by the reaction of a compound of formula (A): 
       
         
           
           
               
               
           
         
       
       and a compound formed by the reaction of a hydrocarbyl-substituted acylating agent and an amine of formula (B1) or (B2): 
       
         
           
           
               
               
           
         
       
       wherein R is an optionally substituted alkyl, alkenyl, aryl or alkylaryl group; R 1  is an alkyl, aryl or alkylaryl group having up to 36 carbon atoms; R 2  and R 3  are the same or different alkyl groups having from 1 to 36 carbon atoms; X is an alkylene group having from 1 to 20 carbon atoms; n is from 0 to 20; m is from 1 to 5; and R 4  is hydrogen or a C 1  to C 36  alkyl group. 
     
     
         2 . The gasoline composition according to  claim 1  wherein the compound of formula (A) is an ester of a carboxylic acid having a pK a  of 3.5 or less. 
     
     
         3 . The gasoline composition according to  claim 1  wherein the compound of formula (A) is an ester of a carboxylic acid selected from the group consisting of a substituted aromatic carboxylic acid, an α-hydroxycarboxylic acid and a polycarboxylic acid. 
     
     
         4 . The gasoline composition according to  claim 3  wherein the compound of formula (A) is an ester of a substituted aromatic carboxylic acid. 
     
     
         5 . The gasoline composition according to  claim 4  wherein R is a substituted phenyl or naphthyl group substituted with one or more groups selected from the group consisting of optionally substituted alkyl, alkenyl, aryl or carboalkoxy groups, nitro, cyano, hydroxy, SR 5 , NR 5 R 6  or COOR 7 , wherein each of R 5 , R 6  and R 7  is a hydrogen atom or an optionally substituted alkyl, alkenyl, aryl or carboalkoxy groups. 
     
     
         6 . The gasoline composition according to  claim 1  wherein the quaternary ammonium salt(s) are formed by the reaction of a compound of formula (A) and a compound formed by the reaction of a hydrocarbyl-substituted acylating agent and an amine of formula (B1). 
     
     
         7 . The gasoline composition according to  claim 1  wherein the hydrocarbyl-substituted acylating agent is polyisobutenyl substituted succinic anhydride. 
     
     
         8 . The gasoline composition according to  claim 1  further comprising one or more additives selected from the group consisting of:
 a) carrier oils; 
 b) acylated nitrogen compounds which are the reaction product of a carboxylic acid-derived acylating agent and an amine; 
 c) hydrocarbyl-substituted amines wherein the hydrocarbyl substituent is substantially aliphatic and contains at least 8 carbon atoms; 
 d) Mannich base additives comprising nitrogen-containing condensates of a phenol, aldehyde and primary or secondary amine; and 
 e) aromatic esters of a polyalkylphenoxyalkanol. 
 
     
     
         9 . The gasoline composition according to  claim 8  wherein component (a) is selected from the group consisting of polyethers and polyetheramines. 
     
     
         10 . The gasoline composition according to  claim 8  wherein component (d) comprises the reaction product of formaldehyde, an ethylene or polyethylene polyamine, and para-substituted monoalkyl phenol. 
     
     
         11 . An additive package which upon addition to gasoline provides a composition as claimed in  claim 1 . 
     
     
         12 . A method of improving the performance of a gasoline engine comprising adding to gasoline one or more quaternary ammonium salt(s) formed by the reaction of a compound of formula (A): 
       
         
           
           
               
               
           
         
       
       and a compound formed by the reaction of a hydrocarbyl-substituted acylating agent and an amine of formula (B1) or (B2): 
       
         
           
           
               
               
           
         
       
       wherein R is an optionally substituted alkyl, alkenyl, aryl or alkylaryl group; R 1  is an alkyl, aryl ear alkylaryl group having up to 36 carbon atoms; R 2  and R 3  are the same or different alkyl groups having from 1 to 36 carbon atoms; X is an alkylene group having from 1 to 20 carbon atoms; n is from it to 20; m is from 1 to 5; and R 4  is hydrogen or a C 1  to C 36  alkyl group; and 
       combusting the additised gasoline. 
     
     
         13 . A method of controlling deposits in a gasoline engine comprising adding to gasoline one or more quaternary ammonium salt(s) formed by the reaction of a compound of formula (A): 
       
         
           
           
               
               
           
         
       
       and a compound formed by the reaction of a hydrocarbyl-substituted acylating agent and an amine of formula (B1) or (B2): 
       
         
           
           
               
               
           
         
       
       wherein R is an optionally substituted alkyl, alkenyl, aryl or alkylaryl group; R 1  is an alkyl, aryl or alkylaryl group having up to 36 carbon atoms; R 2  and R 3  are the same or different alkyl groups having from 1 to 36 carbon atoms; X is an alkylene group having from 1 to 20 carbon atoms; n is from 0 to 20; m is from 1 to 5; and R 4  is hydrogen or a C 1  to C 36  alkyl group; and 
       combusting the additised gasoline. 
     
     
         14 . The method according to  claim 13 , wherein said controlling deposits comprises reducing existing deposits or reducing deposit formation. 
     
     
         15 . The method according to  claim 12 , where the gasoline engine is a direct injection spark ignition gasoline engine. 
     
     
         16 . A method of controlling deposits and/or of improving the efficiency in a spark ignition gasoline engine, the method comprising adding into the gasoline to be combusted:
 (i) one or, more quaternary ammonium salt(s) as defined in  claim 1 , and   (ii) optionally, one or more additional components selected from a)-e) as defined in  claim 8 .