Liquid crystal gas sensor cell and the use thereof

Abstract

A gas sensor cell using a liquid crystal composite material is provided. The gas sensor cell has recovery capability and can be reused. Upon gas adsorption, the liquid crystal composite material has visually detectable color changes and changes in electrical properties to facilitate the measurement of gas concentration from low to high.

1 . A liquid crystal composite material at least comprising a cholesteric liquid crystal material and at least one conductive substance, the liquid crystal composite material being characterized by having visually detectable color changes and changes in electrical properties upon gas adsorption, the cholesteric liquid crystal material comprising at least one chiral dopant and one or more biphenyl compound liquid crystal molecules represented by a general formula (I): 
       
         
           
           
               
               
           
         
         wherein Y denotes halide (including F or Cl) or cyano (—C≡N), and R represents alkyl, alkyloxy, phenylalkyl, alkenyl, or alkenyloxy. 
       
     
     
         2 . The liquid crystal composite material as recited in  claim 1 , wherein the at least one conductive substance is selected from carbon black, carbon nanotubes, metal micro-particles, metal oxide micro-particles, or micro-particles having a conductive layer thereon. 
     
     
         3 . The liquid crystal composite material as recited in  claim 1 , wherein the at least one chiral dopant is selected from dioctan-2-yl biphenyl-4,4′-dicarboxylate, benzoic acid, 4-(trans-4-pentylcyclohexyl)-,1,1′-[(1S)-1-phenyl-1,2-ethanediyl] ester, or isopentylcyanobiphenyl. 
     
     
         4 . The liquid crystal composite material as recited in  claim 1 , wherein a resistance of the liquid crystal composite material decreases upon gas adsorption, and the resistance of the liquid crystal composite material ranges from 100MΩ to 0.001 MΩ. 
     
     
         5 . The liquid crystal composite material as recited in  claim 1 , wherein a color spectrum of the liquid crystal composite material ranges from a wavelength of ultraviolet light to a wavelength of near-infrared light. 
     
     
         6 . The liquid crystal composite material as recited in  claim 5 , wherein the color spectrum of the liquid crystal composite material ranges from a wavelength of 350 nm to a wavelength of 720 nm. 
     
     
         7 . A gas sensor cell, at least comprising:
 a substrate;   an electrode layer located on the substrate;   a liquid crystal composite material layer covering the electrode layer and the substrate; and   a signal collecting and displaying unit electrically connected to the electrode layer, wherein the liquid crystal composite material layer includes at least a cholesteric liquid crystal material and at least one conductive substance, the liquid crystal composite material being characterized by having visually detectable color changes and changes in electrical properties upon gas adsorption, the cholesteric liquid crystal material comprising at least one chiral dopant and one or more biphenyl compound liquid crystal molecules represented by a general formula (I):   
       
         
           
           
               
               
           
         
         wherein Y denotes halide (including F or Cl) or cyano (—C≡N), and R represents alkyl, alkyloxy, phenylalkyl, alkenyl, or alkenyloxy. 
       
     
     
         8 . The gas sensor cell as recited in  claim 7 , wherein the electrode layer is made of a conductive silver paste. 
     
     
         9 . The gas sensor cell as recited in  claim 7 , wherein the substrate is a glass substrate or a transparent plastic substrate. 
     
     
         10 . The gas sensor cell as recited in  claim 7 , wherein the liquid crystal composite material comprises a halide or cyano biphenyl compound liquid crystal material, a chiral dopant, and carbon nanotubes. 
     
     
         11 . The gas sensor cell as recited in  claim 7 , wherein the signal collecting and displaying unit is an optical signal collecting and displaying device or an electrical signal collecting and displaying device, and the signal collecting and displaying unit further comprises an optical or electrical signal analyzing unit. 
     
     
         12 . The liquid crystal composite material as recited in  claim 7 , wherein the at least one conductive substance is selected from carbon black, carbon nanotubes, metal micro-particles, metal oxide micro-particles, or micro-particles having a conductive layer thereon. 
     
     
         13 . The liquid crystal composite material as recited in  claim 7 , wherein the at least one chiral dopant is selected from dioctan-2-yl biphenyl-4,4′-dicarboxylate, benzoic acid, 4-(trans-4-pentylcyclohexyl)-,1,1′-[(1S)-1-phenyl-1,2-ethanediyl] ester, or isopentylcyanobiphenyl.