Composite compound including explosive and modifier for explosive and method of manufacture thereof

Abstract

Universal modifiers from the class of organic and inorganic acids and their salts of new power systems of driving force on the basis of complex complete or/and incomplete nitrates (nitroesters) monoatomic (alcohols, alkanes), diatomic (diols, glycols, alkanediols), triatomic (triols, glycerin), multinuclear (of absolute valence) alcohols, cellulose, as well as nitroamines (nitramines), azides (azoimides), nitro compounds and compositions with mixed groups and their mixtures purposefully modifying their thermodynamic parameters, mechanical, physical, chemical, biochemical properties.

1 - 30 . (canceled) 
     
     
         31 . A composite compound comprising:
 an explosive selected from the group of complex complete or incomplete nitrates of monoatomic, diatomic, triatomic or multinuclear alcohols, nitrocelluloses, nitroamines, azides, nitrobenzenes, nitroanilines, nitroalkanes and mixtures thereof; and   a modifier selected from:   an inorganic acid consisting of at least one from the following group: orthoboric acid, phosphorous acid, or orthophosphoric acid,   an organic acid consisting of at least one from the following group: 2-nitrobenzoic acid, 3-nitrobenzoic acid, 4-nitrobenzoic acid, or   a composition of formula (1)   
       
         
           
           
               
               
           
         
       
       where R═—H, —OH, —COOH, —COONa, 
       R 1 ═—H, —OH, —COOH, 'COONH 4 , —COONa, 
       R 2 ═—H, —OH, —COOH, —COONa, 
       
         
           
           
               
               
           
         
       
       and R 1  and R have the above-stated values, or 
       a composition of formula (2): 
       
         
           
           
               
               
           
         
       
       where R═—OH, —OK, —ONH 4 , —ONa, R 1 =a single bond or —C 2 H 4 , and R 2 =is absent or H 2 O or 2H 2 O. 
     
     
         32 . The composite compound according to  claim 31 , wherein the modifier has the composition of formula (1) and is at least one selected from the group consisting of: 5,5′-methylenedisalicylic acid, diammonium salt of 5,5′-methylenedisalicylic acid, orthophthalic acid, isophthalic acid, terephthalic acid, disodium salt of terephthalic acid, disodium salt of metaphthalic acid, salicylic acid, sodium salt of salicylic acid, benzoic acid, sodium salt of benzoic acid, para-oxybenzoic acid, and meta-oxybenzoic acid. 
     
     
         33 . The composite compound according to  claim 31 , wherein the modifier has the composition of formula (2) and is at least one selected from the group consisting of oxalic acid, oxalic acid dihydrate, lemon salt, sodium oxalate, ammonium oxalate, and succinic acid. 
     
     
         34 . The composite compound according to any of  claims 31  to  33 , wherein the explosive is at least one selected from the group consisting of: glycerol trinitrate, methyl nitrate, ethyl nitrate, ethylene glycol dinitrate, propylene glycol dinitrate, mannitol hexanitrate, monochlorhydrin dinitrate, pentaerythritol tetranitrate. 
     
     
         35 . The composite compound according to any of  claims 31  to  33 , wherein the explosive is at least one selected from the group consisting of: nitroisobutyl glycerinetrinitrate, diethanol-N-nitroamine dinitrate, diglycerin tetranitrate, and diethyleneglycol dinitrate. 
     
     
         36 . The composite compound according to any of  claims 31  to  33 , wherein the explosive is trinitrate of cellulose. 
     
     
         37 . The composite compound according to any of  claims 31  to  33 , wherein the explosive is at least one selected from the group consisting of: ethylene-N,N′-dinitramine, nitroguanidine, nitrourea, N,N′-bis(β,β,β-trinitroethyl)carbamide, N,N′-bis(β,β,β-trinitroethyl)urea, N-nitroaniline, 4-nitrophenyl-N-methylnitroamine, 2,4-dinitro-N-methylaniline, 2,4-dinitrophenyl-N-methylnitroamine, N-methyl-2,4,6-trinitroaniline, N-methyl-N, 2,4,6-tetranitroaniline, N-methyl-N, 2,4,6-tetranitroaniline, and 2,4,6-trinitroaniline. 
     
     
         38 . The composite compound according to any of  claims 31  to  33 , wherein the explosive is at least one selected from the group consisting of: 2,4,6-trinitrophenol, 2,4,6-trinitrochlorbenzene, 2,4,6-trinitroresorcin, 2,4,6-trinitroanisol, 1,3-diamino-2,4,6-trinitrobenzene, 1,3,5-triamino-2,4,6-trinitrobenzenes, 2,4,6-trinitrotoluene, trinitrocreosol, 1,3,5-trinitrobenzene, 1-methyl-3-tert-butyl-2,4,6-trinitrobenzene, 1,3-dimethyl-5-tert-butyl-2,4,6-trinitrobenzene, 2,4,6-trinitro-meta-xylene, and an isomer of tetranitrobenzene. 
     
     
         39 . The composite compound according to any of  claims 31  to  33 , wherein the explosive is at least one selected from the group consisting of: 1,3,5-trinitro-1,3,5-triazacyclohexane and 1,3,5,7-tetranitro-1,3,5,7-tetraazocyclooctane. 
     
     
         40 . The composite compound according to any of  claims 31  to  33 , wherein the explosive is at least one selected from the group consisting of: 2,2′,4,4′,6,6′-hexanitrodiphenyl, 2,2′,4,4′,6,6′-hexanitrodiphenylsulfide, 2,2′,4,4′,6,6′-hexanitrodiphenylsulfone, 2,2′,4,4′, 6,6′-hexanitrostilbene, 3,3′-diamino-2,2′,4,4′,6,6′-hexanitrodiphenyl, 2,4,6-hexanitrodiphenylamine, an isomer of trinitronaphthalene, and an isomer of tetranitronaphthalene. 
     
     
         41 . The composite compound according to any of  claims 31  to  33 , wherein the explosive is at least one selected from the group consisting of: tetranitromethane, 1,2-dinitroethane, 1,1-dinitroethane, 1,1,1-trinitroethane, hexanitroethane. 
     
     
         42 . The composite compound according to any of  claims 31  to  33 , wherein the explosive is at least one selected from the group consisting of: trinitrotriazidobenzene or cyanurtriazide. 
     
     
         43 . A method of manufacturing an explosive composition comprising the step of:
 combining an explosive selected from the group of complex complete or incomplete nitrates of monoatomic, diatomic, triatomic or multinuclear alcohols, nitrocelluloses, nitroamines, azides, nitrobenzenes, nitroanilines, nitroalkanes and mixtures thereof; and   a modifier selected from:   an inorganic acid consisting of at least one from the following group: orthoboric acid, phosphorous acid, and orthophosphoric acid,   an organic acid consisting of at least one from the following group: 2-nitrobenzoic acid, 3-nitrobenzoic acid, and 4-nitrobenzoic acid, or   a composition of formula (1)   
       
         
           
           
               
               
           
         
         where R═—H, —OH, —COOH, or —COONa 
         R 1 ═—H, —OH, —COOH, —COONH 4 , or —COONa, 
         R 2 ′—H, —OH, —COOH, —COONa, or 
       
       
         
           
           
               
               
           
         
         and R 1  and R have the above-stated values, or 
         a composition of formula (2): 
       
       
         
           
           
               
               
           
         
         where R═—OH, —OK, —ONH 4 , or —ONa,
 R 1 =a single bond or —C 2 H 4 , 
 R 2 =is absent or H 2 O or 2H 2 O. 
 
       
     
     
         44 . The method according to  claim 43 , wherein the modifier has the composition of formula (1) and is at least one selected from the group consisting of: 5,5′-methylenedisalicylic acid, diammonium salt of 5,5′-methylenedisalicylic acid, orthophthalic acid, isophthalic acid, terephthalic acid, disodium salt of terephthalic acid, disodium salt of metaphthalic acid, salicylic acid, sodium salt of salicylic acid, benzoic acid, sodium salt of benzoic acid, para-oxybenzoic acid, and meta-oxybenzoic acid. 
     
     
         45 . The method according to  claim 43 , wherein the modifier has the composition of formula (2) and is at least one selected from the group consisting of oxalic acid, oxalic acid dihydrate, lemon salt, sodium oxalate, ammonium oxalate, and succinic acid. 
     
     
         46 . The method according to any of  claims 43  to  45 , wherein the explosive is at least one selected from the group consisting of: glycerol trinitrate, methyl nitrate, ethyl nitrate, ethylene glycol dinitrate, propylene glycol dinitrate, mannitol hexanitrate, monochlorhydrin dinitrate, and pentaerythritol tetranitrate. 
     
     
         47 . The method according to any of  claims 43  to  45 , wherein the explosive is at least one selected from the group consisting of: nitroisobutyl glycerinetrinitrate, diethanol-N-nitroamine dinitrate, diglycerin tetranitrate, and diethyleneglycol dinitrate. 
     
     
         48 . The method according to any of  claims 43  to  45 , wherein the explosive is trinitrate of cellulose. 
     
     
         49 . The method according to any of  claims 43  to  45 , wherein the explosive is at least one selected from the group consisting of: ethylene-N,N′-dinitramine, nitroguanidine, nitrourea, N,N′-bis(β,β,β-trinitroethyl)carbamide, N,N′-bis(β,β,β-trinitroethyl)urea, N-nitroaniline, 4-nitrophenyl-N-methylnitroamine, 2,4-dinitro-N-methylaniline, 2,4-di-nitrophenyl-N-methylnitroamine, N-methyl-2,4,6-trinitroaniline, N-methyl-N, 2,4,6-tetranitroaniline, N-methyl-N, 2,4,6-tetranitroaniline, and 2,4,6-trinitroaniline. 
     
     
         50 . The method according to any of  claims 43  to  45 , wherein the explosive is at least one selected from the group consisting of: 2,4,6-trinitrophenol, 2,4,6-trinitrochlorbenzene, 2,4,6-trinitroresorcin, 2,4,6-trinitroanisol, 1,3-diamino-2,4,6-trinitrobenzene, 1,3,5-triamino-2,4,6-trinitrobenzenes, 2,4,6-trinitrotoluene, trinitrocreosol, 1,3,5-trinitrobenzene, 1-methyl-3-tert-butyl-2,4,6-trinitrobenzene, 1,3-dimethyl-5-tent-butyl-2,4,6-trinitrobenzene, 2,4,6-trinitro-meta-xylene, and an isomer of tetranitrobenzene. 
     
     
         51 . The method according to any of  claims 43  to  45 , wherein the explosive is at least one selected from the group consisting of: 1,3,5-trinitro-1,3,5-triazacyclohexane and 1,3,5,7-tetranitro-1,3,5,7-tetraazocyclooctane. 
     
     
         52 . The method according to any of  claims 43  to  45 , wherein the explosive is at least one selected from the group consisting of: 2,2′,4,4′,6,6′-hexanitrodiphenyl, 2,2′,4,4′,6,6′-hexanitrodiphenylsulfide, 2,2′,4,4′,6,6′-hexanitrodiphenylsulfone, 2,2′,4,4′,6,6′-hexanitrostilbene, 3,3′-diamino-2,2′,4,4′,6,6′-hexanitrodiphenyl, 2,4,6-hexanitrodiphenylamine, an isomer of trinitronaphthalene, and an isomer of tetranitronaphthalene. 
     
     
         53 . The method according to any of  claims 43  to  45 , wherein the explosive is at least one selected from the group consisting of: tetranitromethane, 1,2-dinitroethane, 1,1-dinitroethane, 1,1,1-trinitroethane, and hexanitroethane. 
     
     
         54 . The method according to any of  claims 43  to  45 , wherein the explosive is at least one selected from the group consisting of: trinitrotriazidobenzene and cyanurtriazide.