Oil filters containing strong base and methods of their use

Abstract

Novel filter elements for sequestering acids from oil or fuel, the strong base flocs that comprise the filter elements, and methods of their preparation and use are disclosed. The filter elements comprise a mechanically linked interlocking fiber matrix interspersed with strong base particle flocs wherein the strong base particles constitute at least 30% by weight of the filter element. Certain filter elements may be useful for sequestering acids or neutralized acids in certain oils or fuels, for example, the acids originating in the combustion and lubrication system of an internal combustion engine or those contained in oils in an oil circulation system. Other filter elements may be useful for reducing oxidation of an oil.

1 . A method for sequestering acids from oil containing acids or neutralized acids originating in the combustion and lubrication system of an internal combustion engine, the method comprising:
 contacting in a lubricating oil circulation system a filter element with a lubricating oil containing acids or neutralized acids, or a mixture thereof,   wherein the filter element comprises:   a matrix formed of mechanically-interlocking structural fibers and interstitial spaces;   strong base particles within the matrix for sequestering acids from the oil, the strong base particles having an average particle size less than the average cross-section of the interstitial spaces; and   a high molecular weight flocculating agent to retain the strong base particles in a strong base particle floc formed within the matrix;   wherein:   1) a smallest unit size dimension of the strong base particle floc is greater than the average cross-section of the interstitial spaces;   2) the strong base particles in the strong base particle floc are substantially unattached to the mechanically-interlocked fibers but are physically bound within the matrix;   3) there is substantially no latex chemically binding the strong base particles to the matrix; and   4) the strong base constitutes at least 30% by weight of the filter element;   wherein the filter element causes at least a portion of the acids to remain with the strong base particles within the filter element; and   wherein filter element has a total surface area, as measured by Hg intrusion porosimetry, of at least 10 m 2 /gram.   
     
     
         2 . The method of  claim 1 , wherein the strong base particles within the filter element comprise magnesium oxide. 
     
     
         3 . The method of  claim 1 , wherein the filter element further comprises a porous backing sheet material having a dry tensile strength of at least about 5 pounds per inch as measured ASTM method D828. 
     
     
         4 . A method for sequestering acid from oil containing acids or neutralized acids in an oil circulation system, comprising:
 contacting oil in the oil circulation system with a filter element;   wherein the filter element comprises:   a matrix formed of mechanically-interlocking structural fibers and interstitial spaces;   strong base particles within the matrix for sequestering acids from the oil, the strong base particles having an average particle size less than the average cross-section of the interstitial spaces; and   a high molecular weight flocculating agent to retain the strong base particles in a strong base particle floc formed within the matrix;   wherein:   1) a smallest unit size dimension of the strong base particle floc is greater than the average cross-section of the interstitial spaces;   2) the strong base particles in the strong base particle floc are substantially unattached to the mechanically-interlocked fibers but are physically bound within the matrix;   3) there is substantially no latex chemically binding the strong base particles to the matrix; and   4) the strong base constitutes at least 30% by weight of the filter element;   wherein the filter element causes at least a portion of the acids to remain with the strong base particles within the filter element; and   wherein the filter element has a total surface area, as measured by Hg intrusion porosimetry, of at least 10 m 2 /gram.   
     
     
         5 . The method of  claim 4 , wherein the strong base particles within the filter element comprise magnesium oxide. 
     
     
         6 . The method of  claim 4 , wherein the filter element further comprises a porous backing sheet material having a dry tensile strength of at least about 5 pounds per inch as measured ASTM method D828. 
     
     
         7 . A method of reducing oxidation of an oil, comprising:
 contacting the oil with a filter element to sequester acids at a rate such that oxidation of the oil is decreased by at least about 20% relative to the rate of oxidation in an oil in contact with a non-base containing filter element;   wherein the filter element comprises:   a matrix formed of mechanically-interlocking structural fibers and interstitial spaces;   strong base particles within the matrix for sequestering acids from the oil, the strong base particles having an average particle size less than the average cross-section of the interstitial spaces; and   a high molecular weight flocculating agent to retain the strong base particles in a strong base particle floc formed within the matrix;   wherein:   1) a smallest unit size dimension of the strong base particle floc formed is greater than the average cross-section of the interstitial spaces;   2) the strong base particles are substantially unattached to the mechanically-interlocked fibers but are physically bound within the matrix;   3) there is substantially no latex chemically binding the strong base particles to the matrix; and   4) the strong base constitutes at least 30% by weight of the filter element;   wherein the filter element causes at least a portion of the acids to remain with the strong base particles within the filter element; and   wherein the filter element has a total surface area, as measured by Hg intrusion porosimetry, of at least 10 m 2 /gram.   
     
     
         8 . The method of  claim 7 , wherein the strong base particles within the filter element comprise magnesium oxide. 
     
     
         9 . The method of  claim 7 , wherein the filter element further comprises a porous backing sheet material having a dry tensile strength of at least about 5 pounds per inch as measured ASTM method D828.