Hydrolysis resistant organomodified trisiloxane surfactants

Abstract

Three types of trisiloxane surfactants having the basic formula: MDM′ are described wherein the substituents on the differing M and M′ groups in conjunction with a pendant polyalkylene oxide substituents on the D group to render the surfactant resistant to hydrolysis under either basic or acidic conditions.

1 - 40 . (canceled) 
     
     
         41 . A silicone composition comprising a silicone having the formula:
   M 3  D 2  M 4      
       wherein
     M   3 =(R 10 )(R 11 )(R 12 )SiO 1/2 ; 
     M   4 =(R 13 )(R 14 )(R 15 )SiO 1/2 ; and 
     D   2 =(R 16 )(Z′)SiO 2/2 ,
 
 
       where R 10 , R 11 , R 12  R 13 , R 14 , R 15  and R 16  are each independently selected from the group consisting of 1 to 4 carbon monovalent hydrocarbon radicals, aryl, and an alkyl hydrocarbon group of 4 to 9 carbons containing an aryl substituents of 6 to 20 carbon atoms; Z′ is an alkylene oxide group of the formula:
 R 17 (C 2 H 4 O) d (C 3 H 6 O) e (C 4 H 8 O) f R 18 , where R 17  has the formula:
   —C 4 H 8 O—(C 2 H 4 O)—
 
 
 
       with R 18  selected from the group consisting of H, monovalent hydrocarbon radicals of from 1 to 6 carbon atoms and acetyl, the subscripts d, e and f are zero or positive and satisfy the following relationships:
   2≦d+e+f≦20 with d≧2.
 
 
     
     
         42 . The composition of  claim 41  where the subscript f is 0. 
     
     
         43 . The composition of  claim 41  where the subscript e ranges from 0 to 3. 
     
     
         44 . The composition of  claim 41  where the subscript d ranges from 8 to 11. 
     
     
         45 . The composition of  claim 41  where R 10 , R 11 , R 12 , R 13 , R 14 , R 15  and R 16  are methyl. 
     
     
         46 . The composition of  claim 41  where R 18  is methyl. 
     
     
         47 . The composition of  claim 42  where the subscript e is 0. 
     
     
         48 . The composition of  claim 47  where the subscript d is 8. 
     
     
         49 . The composition of  claim 48  where R 10 , R 11 , R 12 , R 13 , R 14 , R 15  and R 16  are methyl. 
     
     
         50 . The composition of  claim 49  where R 18  is methyl. 
     
     
         51 . A silicone composition comprising a silicone having the formula:
   M 3  D 2  M 4      
       wherein
     M   3 =(R 10 )(R 11 )(R 12 )SiO 1/2 ; 
     M   4 =(R 13 )(R 14 )(R 15 )SiO 1/2 ; and 
     D   2 =(R 16 )(Z′)SiO 2/2  
 
 
       where R 10 , R 11 , R 12  R 13 , R 14 , R 15  and R 16  are each independently selected from the group consisting of 1 to 4 carbon monovalent hydrocarbon radicals, aryl, and an alkyl hydrocarbon group of 4 to 9 carbons containing an aryl substituents of 6 to 20 carbon atoms; Z′ is an alkylene oxide group of the formula:
 R 17 (C 2 H 4 O) d (C 3 H 6 O) e (C 4 H 8 O) f R 18 , where R 17  has the formula;
   —C 4 H 8 O—(C 2 H 4 O)—
 
 
 
       with R 18  selected from the group consisting of H, monovalent hydrocarbon radicals of from 1 to 6 carbon atoms and acetyl, the subscripts d, e and f are zero or positive and satisfy the following relationships:
 2≦d+e+f≦20 with d≧2 wherein said silicone composition has an enhanced resistance to hydrolysis. 
 
     
     
         52 . The composition of  claim 51  where the subscript f is 0. 
     
     
         53 . The composition of  claim 51  where the subscript e ranges from 0 to 3. 
     
     
         54 . The composition of  claim 51  where the subscript d ranges from 8 to 11. 
     
     
         55 . The composition of  claim 51  where R 10 , R 11 , R 12 , R 13 , R 14 , R 15  and R 16  are methyl. 
     
     
         56 . The composition of  claim 51  where R 18  is methyl. 
     
     
         57 . The composition of  claim 52  where the subscript e is 0. 
     
     
         58 . The composition of  claim 57  where the subscript d is 8. 
     
     
         59 . The composition of  claim 58  where R 10 , R 11 , R 12 , R 13 , R 14 , R 15  and R 16  are methyl. 
     
     
         60 . The composition of  claim 59  where R 18  is methyl. 
     
     
         61 . An aqueous emulsion wherein the discontinuous phase comprises water and the continuous phase comprises the composition of  claim 41 . 
     
     
         62 . An aqueous emulsion wherein the discontinuous phase comprises water and the continuous phase comprises the composition of  claim 51 . 
     
     
         63 . An aqueous emulsion wherein the continuous phase comprises water and the discontinuous phase comprises the composition of  claim 41 . 
     
     
         63 . An aqueous emulsion wherein the continuous phase comprises water and the discontinuous phase comprises the composition of  claim 51 . 
     
     
         65 . A non-aqueous emulsion wherein the discontinuous phase comprises a non-aqueous hydroxylic solvent and the continuous phase comprises the composition of  claim 41 . 
     
     
         66 . A non-aqueous emulsion wherein the discontinuous phase comprises a non-aqueous hydroxylic solvent and the continuous phase comprises the composition of  claim 51 . 
     
     
         67 . A non-aqueous emulsion wherein the continuous phase comprises a non-aqueous hydroxylic solvent and the discontinuous phase comprises the composition of  claim 41 . 
     
     
         68 . A non-aqueous emulsion wherein the continuous phase comprises a non-aqueous hydroxylic solvent and the discontinuous phase comprises the composition of  claim 51 . 
     
     
         69 - 104 . (canceled)