Modified blowing agent surface-treated with metallic siloxylated compound and polymer resin composition including the same

Abstract

Provided is a modified blowing agent, wherein the surface of a blowing agent powder is coated with a metallic siloxylated compound. When the modified blowing agent is included in a polymer resin, dispersibility of the modified blowing agent is excellent in the polymer resin and fluidity of the polymer resin is improved in an extrusion molding machine and an injection molding machine, and thus productivity and processability can be improved. In addition, the foam that is formed using the polymer resin composition including the modified blowing agent has excellent tear strength, durability, and masking sound properties due to fine and uniform size of foam cells and increased number of foam cells per unit surface area.

1 . A polymer resin composition comprising a modified blowing agent, wherein the surface of a blowing agent powder is coated with a metallic siloxylated compound, wherein the amount of the modified blowing agent is from 0.1 to 30 parts by weight based on 100 parts by weight of a polymer resin. 
     
     
         2 . The polymer resin composition of  claim 1 , wherein the polymer resin is at least one resin selected from the group consisting of polyvinyl chloride, polyethylene, polypropylene, ethylenevinylacetate resin, polyurethane, polystyrene, acrylonitrile butadiene styrene (ABS) resin, oleffin resin, rubber, phenol resin, melamine resin and epoxy resin. 
     
     
         3 . A polymer resin composition comprising a modified blowing agent according to  claim 1 , wherein the metallic siloxylated compound is represented by one compound selected from the group consisting of Formula 1 having a molecular weight of 5,000 to 40,000, Formula 2 having a molecular weight of 5,000 to 30,000, and Formula 3 having a molecular weight of 10,000 to 40,000: 
       
         
           
           
               
               
           
         
         wherein m and n are each independently an integer of from 4 to 100, 
         M is a metal selected from the group consisting of aluminum, arsenic, gold, boron, barium, beryllium, bismuth, calcium, niobium, cadmium, cerium, cobalt, chrome, cesium, copper, iron, gallium, germanium, mercury, indium, potassium, lanthanum, lithium, magnesium, manganese, molybdenum, iridium, sodium, nickel, osmium, lead, palladium, platinum, rubidium, rhodium, ruthenium, antimony, silicon, tin, strontium, tantalum, tellurium, thorium, titanium, thallium, uranium, vanadium, tungsten, zinc and zirconium, and 
         R 1 , R 2 , R 3  and R 4  are each independently selected the group consisting of: a hydrogen atom; a halogen atom; —Si(R′)(R″)(R′″); a C 1 ˜C 6  alkyl group substituted or unsubstituted with at least one of a halogen atom and —Si(R′)(R″)(R′″); a C 2 ˜C 6  alkenyl group substituted or unsubstituted with at least one of a halogen atom and —Si(R′)(R″)(R′″); and a phenyl group substituted or unsubstituted with at least one of a halogen atom and —Si(R′)(R″)(R′″), wherein R′, R″ and R′″ are each independently a C 1 ˜C 6  alkyl group; 
       
       
         
           
           
               
               
           
         
         wherein m and n are each independently an integer of from 4 to 100, 
         M is a metal selected from the group consisting of aluminum, arsenic, gold, boron, barium, beryllium, bismuth, calcium, niobium, cadmium, cerium, cobalt, chrome, cesium, copper, iron, gallium, germanium, mercury, indium, potassium, lanthanum, lithium, magnesium, manganese, molybdenum, iridium, sodium, nickel, osmium, lead, palladium, platinum, rubidium, rhodium, ruthenium, antimony, silicon, tin, strontium, tantalum, tellurium, thorium, titanium, thallium, uranium, vanadium, tungsten, zinc and zirconium, and 
         R 1 , R 2 , R 3  and R 4  are each independently selected the group consisting of: a hydrogen atom; a halogen atom; —Si(R′)(R″)(R′″); a C 1 ˜C 6  alkyl group substituted or unsubstituted with at least one of a halogen atom and —Si(R′)(R″)(R′″); a C 2 ˜C 6  alkenyl group substituted or unsubstituted with at least one of a halogen atom and —Si(R′)(R″)(R′″); and a phenyl group substituted or unsubstituted with at least one of a halogen atom and —Si(R′)(R″)(R′″), wherein R′, R″ and R′″ are each independently a C 1 ˜C 6  alkyl group; and 
       
       
         
           
           
               
               
           
         
         wherein 
         A is 
       
       
         
           
           
               
               
           
         
         B is 
         CH 2 —CH 2 —, 
         wherein X is CH 3 (SiO-2CH 2 -M) m -, wherein m is an integer of from 4 to 100, 
         M is a metal selected from the group consisting of aluminum, arsenic, gold, boron, barium, beryllium, bismuth, calcium, niobium, cadmium, cerium, cobalt, chrome, cesium, copper, iron, gallium, germanium, mercury, indium, potassium, lanthanum, lithium, magnesium, manganese, molybdenum, iridium, sodium, nickel, osmium, lead, palladium, platinum, rubidium, rhodium, ruthenium, antimony, silicon, tin, strontium, tantalum, tellurium, thorium, titanium, thallium, uranium, vanadium, tungsten, zinc and zirconium, 
         each of the repeating units of A and B are randomly connected, 
         a and b are each independently 10 to 90 mol %, and 1<n<1000. 
       
     
     
         4 . A polymer resin composition comprising a modified blowing agent according to  claim 1 , wherein the amount of the metallic siloxylated compound is from 0.1 to 10 parts by weight based on 100 parts by weight of the blowing agent. 
     
     
         5 . A polymer resin composition comprising a modified blowing agent according to  claim 1 , wherein the blowing agent is at least one compound selected from the group consisting of azo dicarbon amide, p,p′-oxybis(benzenesulfonyl hydrazide), p-toluenesulfonyl hydrazide, benzenesulfonyl hydrazide, N,N′-dinitroso pentamethylene tetramine, p-toluenesulfonyl semicarbazide, 5-phenyltetrazol, sodium bicarbonate, zinc dibenzenesulfinate and zinc ditoluenesulfinate. 
     
     
         6 . A polymer resin composition comprising a modified blowing agent according to  claim 1 , wherein the modified blowing agent further comprises fumed silica.