Austenitic heat resistant alloy, heat resistant pressure member comprising the alloy, and method for manufacturing the same member

Abstract

An austenitic heat resistant alloy, which comprises by mass percent, C: over 0.02 to 0.15%, Si≦2%, Mn≦3%, P≦0.03%, S≦0.01%, Cr: 28 to 38%, Ni: over 40 to 60%, Co≦20% (including 0%), W over 3 to 15%, Ti: 0.05 to 1.0%, Zr: 0.005 to 0.2%, Al: 0.01 to 0.3%, N≦0.02%, and Mo<0.5%, with the balance being Fe and impurities, in which the following formulas (1) to (3) are satisfied has high creep rupture strength and high toughness after a long period of use at a high temperature, and further it is excellent in hot workability. This austenitic heat resistant alloy may contain a specific amount of one or more elements selected from Nb, V, Hf, B, Mg, Ca, Y, La, Ce, Nd, Sc, Ta, Re, Ir, Pd, Pt and Ag. P≦3/{200(Ti+8.5×Zr)} . . . (1), 1.35×Cr≦Ni+Co≦1.85×Cr . . . (2), Al≧1.5×Zr . . . (3).

1 . An austenitic heat resistant alloy, which comprises by mass percent, C: more than 0.02% to not more than 0.15%, Si: 2% or less, Mn: 3% or less, P: 0.03% or less, S: 0.01% or less, Cr: 28 to 38%, Ni: more than 40% to not more than 60%, W: more than 3% to not more than 15%, Ti: 0.05 to 1.0%, Zr: 0.005 to 0.2%, Al: 0.01 to 0.3%, N: 0.02% or less, and Mo: less than 0.5%, with the balance being Fe and impurities, in which the following formulas (1) to (3) are satisfied:
   P≦3/{200(Ti+8.5×Zr)}  (1),
     1.35×Cr≦Ni≦1.85×Cr  (2),
     Al≧1.5×Zr (3);
   
       wherein each element symbol in the equations (1) to (3) represents the content by mass % of the element concerned. 
     
     
         2 . An austenitic heat resistant alloy, which comprises by mass percent, C: more than 0.02% to not more than 0.15%, Si: 2% or less, Mn: 3% or less, P: 0.03% or less, S: 0.01% or less, Cr: 28 to 38%, Ni: more than 40% to not more than 60%, Co: 20% or less, W: more than 3% to not more than 15%, Ti: 0.05 to 1.0%, Zr: 0.005 to 0.2%, Al: 0.01 to 0.3%, N: 0.02% or less, and Mo: less than 0.5%, with the balance being Fe and impurities, in which the following formulas (1), (3) and (4) are satisfied:
   P≦3/{200(Ti+8.5×Zr)}  (1),
     Al≧1.5×Zr  (3),
     1.35×Cr≦Ni+Co≦1.85×Cr  (4);
   
       wherein each element symbol in the equations (1), (3) and (4) represents the content by mass % of the element concerned. 
     
     
         3 . The austenitic heat resistant alloy according to  claim 1 , which further contains, by mass percent, one or more elements of one or more groups selected from the  1  to  3  groups listed below in lieu of a part of Fe:
   1  Nb: 1.0% or less, V: 1.5% or less, Hf: 1% or less and B: 0.05% or less; 
   2  Mg: 0.05% or less, Ca: 0.05% or less, Y: 0.5% or less, La: 0.5% or less, Ce: 0.5% or less, Nd: 0.5% or less and Sc: 0.5% or less; 
   3  Ta: 8% or less, Re: 8% or less, Ir: 5% or less, Pd: 5% or less, Pt: 5% or less and Ag: 5% or less. 
 
     
     
         4 . The austenitic heat resistant alloy according to  claim 2 , which further contains, by mass percent, one or more elements of one or more groups selected from the  1  to  3  groups listed below in lieu of a part of Fe:
   1  Nb: 1.0% or less, V: 1.5% or less, Hf: 1% or less and B: 0.05% or less; 
   2  Mg: 0.05% or less, Ca: 0.05% or less, Y: 0.5% or less, La: 0.5% or less, Ce: 0.5% or less, Nd: 0.5% or less and Sc: 0.5% or less; 
   3  Ta: 8% or less, Re: 8% or less, Ir: 5% or less, Pd: 5% or less, Pt: 5% or less and Ag: 5% or less. 
 
     
     
         5 . A heat resistant pressure member excellent in creep resistance properties and structural stability in a high temperature range, which is made from the austenitic heat resistant alloy according to  claim 1 . 
     
     
         6 . A heat resistant pressure member excellent in creep resistance properties and structural stability in a high temperature range, which is made from the austenitic heat resistant alloy according to  claim 2 . 
     
     
         7 . A heat resistant pressure member excellent in creep resistance properties and structural stability in a high temperature range, which is made from the austenitic heat resistant alloy according to  claim 3 . 
     
     
         8 . A heat resistant pressure member excellent in creep resistance properties and structural stability in a high temperature range, which is made from the austenitic heat resistant alloy according to  claim 4 . 
     
     
         9 . A method for manufacturing the heat resistant pressure member excellent in creep resistance and structural stability in a high temperature range, wherein the austenitic heat resistant alloy according to  claim 1  is treated in sequence by the following steps (i), (ii) and (iii):
 step (i): heating to 1050 to 1250° C. at least once before final hot or cold working; 
 step (ii): carrying out a final hot or cold plastic working such that the reduction of area is 10% or more; 
 step (iii): carrying out a final heat treatment in which cooling is performed after heating and holding at a temperature in the range of 1100 to 1250° C. 
 
     
     
         10 . A method for manufacturing the heat resistant pressure member excellent in creep resistance and structural stability in a high temperature range, wherein the austenitic heat resistant alloy according to  claim 2  is treated in sequence by the following steps (i), (ii) and (iii):
 step (i): heating to 1050 to 1250° C. at least once before final hot or cold working; 
 step (ii): carrying out a final hot or cold plastic working such that the reduction of area is 10% or more; 
 step (iii): carrying out a final heat treatment in which cooling is performed after heating and holding at a temperature in the range of 1100 to 1250° C. 
 
     
     
         11 . A method for manufacturing the heat resistant pressure member excellent in creep resistance and structural stability in a high temperature range, wherein the austenitic heat resistant alloy according to  claim 3  is treated in sequence by the following steps (i), (ii) and (iii):
 step (i): heating to 1050 to 1250° C. at least once before final hot or cold working; 
 step (ii): carrying out a final hot or cold plastic working such that the reduction of area is 10% or more; 
 step (iii): carrying out a final heat treatment in which cooling is performed after heating and holding at a temperature in the range of 1100 to 1250° C. 
 
     
     
         12 . A method for manufacturing the heat resistant pressure member excellent in creep resistance and structural stability in a high temperature range, wherein the austenitic heat resistant alloy according to  claim 4  is treated in sequence by the following steps (i), (ii) and (iii):
 step (i): heating to 1050 to 1250° C. at least once before final hot or cold working; 
 step (ii): carrying out a final hot or cold plastic working such that the reduction of area is 10% or more; 
 step (iii): carrying out a final heat treatment in which cooling is performed after heating and holding at a temperature in the range of 1100 to 1250° C.