Process to prepare adsorbents from organic fertilizer and their applications for removal of acidic gases from wet air streams

Abstract

The invention is directed to an adsorbent comprising: a) 20-30% porous carbon with incorporated organic nitrogen species; and b) 70-80% inorganic matter. The invention is directed to a method of making an adsorbent which comprises: a) thermally drying dewatered sewage sludge to form granulated organic fertilizer; and b) pyrolyzing said the organic fertilizer at temperatures between 600 and 1000° C. The invention is additionally directed to the process of removing acidic gases from wet air streams comprising putting an adsorbent in contact with the wet air stream and allowing the adsorbent to adsorb the acidic gases.

1 - 28 . (canceled) 
     
     
         29 . A method of making an adsorbent, said method consisting essentially of:
 (a) thermally drying dewatered sewage sludge;   (b) granulating said dried sludge; and   (c) pyrolizing said granulated dried sludge under pyrolysis conditions suitable to provide an absorbent having a basic pH,   said pyrolysis conditions being in an inert atmosphere at a temperature between 600 and 1000° C., wherein said temperature is reached at a heating rate between 5 and 10° C./minute and hold time for the pyrolysis is between 60 and 90 minutes; and   wherein said adsorbent maintains a basic pH after hydrogen sulfide adsorption.   
     
     
         30 . A method as defined in  claim 29 , wherein said pyrolysis is conducted at a temperature between 800 and 1000° C. 
     
     
         31 . A method as defined in  claim 30 , wherein said pyrolysis is conducted at a temperature between 900 and 1000° C. 
     
     
         32 . A method as defined in  claim 29 , wherein said pyrolysis is conducted at a temperature between 600 and 900° C. 
     
     
         33 . A method as defined in  claim 32 , wherein said pyrolysis is conducted at a temperature between 800 and 900° C. 
     
     
         34 . An adsorbent prepared by a method consisting essentially of:
 (a) thermally drying dewatered sewage sludge; and   (b) granulating said dried sludge; and   (c) pyrolizing said granulated dried sludge under pyrolysis conditions suitable to provide an absorbent having a basic pH,   said pyrolysis conditions being in an inert atmosphere at a temperature between 600 and 1000° C., wherein said temperature is reached at a heating rate between 5 and 10° C./minute and hold time for the pyrolysis is between 60 and 90 minutes; and   wherein said adsorbent maintains a basic pH after hydrogen sulfide adsorption.   
     
     
         35 . An adsorbent as defined in  claim 34 , wherein said adsorbent has a basic pH. 
     
     
         36 . An absorbent as defined in  claim 35 , wherein said pH is greater than 10. 
     
     
         37 . An adsorbent as defined in  claim 34 , wherein said adsorbent has a surface area of 100-500 m 2 /g. 
     
     
         38 . An adsorbent as defined in  claim 37 , wherein said adsorbent has a surface area of 100-200 m 2 /g. 
     
     
         39 . A method of making an adsorbent, said method comprising:
 (a) thermally drying dewatered sewage sludge;   (b) granulating said dried sludge; and   (c) pyrolizing said granulated dried sludge under pyrolysis conditions suitable to provide an absorbent having a basic pH,   said pyrolysis conditions being in an inert atmosphere at a temperature between 600 and 1000° C., wherein said temperature is reached at a heating rate between 5 and 10° C./minute and hold time for the pyrolysis is between 60 and 90 minutes;   wherein said adsorbent maintains a basic pH after hydrogen sulfide adsorption; and   wherein steps (a)-(c) are conducted without chemical activation.   
     
     
         40 . A method as defined in  claim 39 , wherein said pyrolysis is conducted at a temperature between 800 and 1000° C. 
     
     
         41 . A method as defined in  claim 40 , wherein said pyrolysis is conducted at a temperature between 900 and 1000° C. 
     
     
         46 . A method as defined in claim  43 , wherein said pyrolysis is conducted at a temperature between 600 and 900° C. 
     
     
         47 . A method as defined in  claim 46 , wherein said pyrolysis is conducted at a temperature between 800 and 900° C.