Organic electroluminescence device

Abstract

An organic electroluminescence device comprising a pair of electrodes and a layer of an organic light emitting medium disposed between the pair of electrodes, wherein the layer of an organic light emitting medium comprises a mixed layer comprising (A) at least one hole transporting compound and (B) at least one electron transporting compound, an energy gap of the hole transporting compound represented by Eg1 and an energy gap of the electron transporting compound represented by Eg2 satisfy a relation: Eg1<Eg2. Electrons and holes are recombined in the layer of an organic light emitting medium and light is emitted. The organic electroluminescence device has a long life and emits light at a high efficiency.

1 . An organic electroluminescence device comprising a pair of electrodes and a layer of an organic light emitting medium disposed between the pair of electrodes, wherein the layer of an organic light emitting medium comprises a mixed layer consisting essentially of (A) at least one compound selected from hole transporting compounds and (B) at least one compound selected from electron transporting compounds in amounts such that a ratio of an amount of component (A) to an amount of component (B) is in a range of 8:92 to 92:8; an energy gap of the hole transporting compound represented by Eg1 and an energy gap of the electron transporting compound represented by Eg2 satisfy a relation:
   Eg1<Eg2; and   the electron transporting compound is represented by the following general formula (5) or the following general formula (6):
   A 1 -L-A 2   (5) 
   
       wherein A 1  and A 2  may be the same or different from each other and each independently represents a substituted or unsubstituted monophenylanthryl group or a substituted or unsubstituted diphenylanthryl group, and L represents a single bond or a divalent bonding group;
   A 3 -An-A 4   (6) 
 
       wherein An represents a substituted or unsubstituted anthracene residue group, and A 3  and A 4  may be the same or different from each other and each independently represents a substituted or unsubstituted monovalent condensed aromatic cyclic group having 10 to 40 carbon atoms or a substituted or unsubstituted aryl group having no condensed cyclic structures and having 12 to 40 carbon atoms. 
     
     
         2 . The organic electroluminescence device according to  claim 1 , wherein an ionization energy of the hole transporting compound represented by IP1 and an ionization energy of the electron transporting compound represented by IP2 satisfy a relation:
   IP1<IP2.   
     
     
         3 . The organic electroluminescence device according to  claim 2 , wherein an electron affinity of the hole transporting compound represented by Af1 and an electron affinity of the electron transporting compound represented by Af2 satisfy a relation:
   Af1≦Af2   
       and ΔEv given by ΔEv=IP2−IP1 and ΔEc given by ΔEc=Af2−AF1 satisfy a relation:
   ΔEv≧Ec. 
 
     
     
         4 . The organic electroluminescence device according to  claim 2 , wherein an electron affinity of the hole transporting compound represented by Af1 and an electron affinity of the electron transporting compound represented by Af2 satisfy a relation:
   Af1>Af2   
       and ΔEv given by ΔEv=IP2−IP1 and ΔEc given by ΔEc′=Af1−AF2 satisfy a relation:
   ΔEv≧Ec′. 
 
     
     
         5 . The organic electroluminescence device according to  claim 1 , wherein the hole transporting compound is an aromatic amine having condensed cyclic structures. 
     
     
         6 . The organic electroluminescence device according to  claim 5 , wherein the aromatic amine is represented by following general formula (1): 
       
         
           
           
               
               
           
         
       
       wherein Ar 1  to Ar 4  each independently represents a substituted or unsubstituted aromatic hydrocarbon group having 6 to 40 carbon atoms or a substituted or unsubstituted aromatic heterocyclic group having 3 to 40 carbon atoms, Y represents a substituted or unsubstituted aromatic residue group having 2 to 60 carbon atoms, at least one of the groups represented by Ar 1  to Ar 4  and Y has a condensed cyclic group having 3 or more rings, and a substituent in the groups represented by Ar 1  to Ar 4  and Y may form a ring with two groups selected from the groups represented by Ar 1  to Ar 4  and Y. 
     
     
         7 . The organic electroluminescence device according to  claim 5 , wherein the aromatic amine is represented by following general formula (2): 
       
         
           
           
               
               
           
         
       
       wherein Ar 1  to Ar 6  each independently represents a substituted or unsubstituted aromatic hydrocarbon group having 6 to 40 carbon atoms or a substituted or unsubstituted aromatic heterocyclic group having 3 to 40 carbon atoms, Z represents a substituted or unsubstituted aromatic residue group having 3 to 60 carbon atoms, at least one of the groups represented by Ar 1  to Ar 6  and Z has a condensed cyclic group having 3 or more rings, and a substituent in the groups represented by Ar 1  to Ar 6  and Z may form a ring with two groups selected from the groups represented by Ar 1  to Ar 6  and Z. 
     
     
         8 .- 12 . (canceled) 
     
     
         13 . The organic electroluminescence device according to  claim 1 , wherein the mixed layer in the layer of an organic light emitting medium further comprises (C) a fluorescent compound. 
     
     
         14 . The organic electroluminescence device according to  claim 13 , wherein the layer of an organic light emitting medium comprises component (A), component (B) and component (C) in amounts such that a ratio of a total amount by weight of component (A) and component (B) to an amount by weight of component (C) is in a range of 100:1 to 10:1. 
     
     
         15 . The organic electroluminescence device according to  claim 1 , wherein a layer of a chalcogenide, a metal halide or a metal oxide is disposed on a surface of at least one of the pair of electrodes. 
     
     
         16 . The organic electroluminescence device according to  claim 1 , wherein a mixed region of a reducing dopant and the electron transporting compound or a mixed region of an oxidizing dopant and the hole transporting compound is disposed on a surface of at least one of the pair of electrodes. 
     
     
         17 . The organic electroluminescence device according to  claim 1 , wherein a work function WF of an anode which injects holes into the layer of an organic light emitting medium and an ionization energy of the hole transporting compound IP1 satisfy a relation:
     IP 1−WF≦0.2eV.   
     
     
         18 . An organic electroluminescence device comprising a pair of electrodes and a layer of an organic light emitting medium disposed between the pair of electrodes, wherein the layer of an organic light emitting medium comprises a mixed layer comprising (A) at least one compound selected from hole transporting compounds and (B) at least one compound selected from electron transporting compounds; an energy gap of the hole transporting compound represented by Eg1 and an energy gap of the electron transporting compound represented by Eg2 satisfy a relation:
   Eg1<Eg2   
       and holes are transported in the layer of an organic light emitting medium with the hole transporting compound; and
 the electron transporting compound is represented by the following general formula (5) or the following general formula (6):
   A 1 -L-A 2   (5) 
 
 
       wherein A 1  and A 2  may be the same or different from each other and each independently represents a substituted or unsubstituted monophenylanthryl group or a substituted or unsubstituted diphenylanthryl group, and L represents a single bond or a divalent bonding group;
   A 3 -An-A 4   (6) 
 
       wherein An represents a substituted or unsubstituted anthracene residue group, and A 3  and A 4  may be the same or different from each other and each independently represents a substituted or unsubstituted monovalent condensed aromatic cyclic group having 10 to 40 carbon atoms or a substituted or unsubstituted aryl group having no condensed cyclic structures and having 12 to 40 carbon atoms.