Manufacture method of wet-tissue with antimicrobial and anti-fungus function

Abstract

This invention is on manufacturing method of antimicrobial and anti-fungus wet tissues with antimicrobial and anti-fungus whole cloth for wet tissue(i.e. non-woven fabrics, cottons and papers) manufactured with nano metal particles soak in tissue manufacturing water with nano sized metal particles which have antimicrobial and anti-fungus function to have multiple effects. According to this invention, woven fabrics, cottons and papers soak in the tissue manufacturing water that one or more than one of selected nano metal particles from gold, platinum, silver, germanium, selenium, zinc, copper and tungsten are mixed in the tissue manufacturing water and then they have antimicrobial and anti-fungus function. The antimicrobial and anti-fungus whole cloth for wet tissue is formed into antimicrobial and anti-fungus non-woven fabric whole cloth by mixing and blending selected one or mixtures more than one of the fabric materials of viscose rayon, polyester, polyethylene, polypropylene, cotton and pulp with selected one or mixtures more than one of nano metal particles of platinum, gold, silver, germanium, selenium, zinc, copper and tungsten.

1 . A manufacture method of antimicrobial and anti-fungus wet tissue characterized in that said tissue is wove with one or mixture of more than one of selected tissue fabric from viscose rayon, polyester, polyethylene fiber, polypropylene fiber, cotton and pulp, and by dipping into tissue manufacturing water which contained one or more than one of selected nano metal particles from platinum, gold, silver, germanium, selenium and zinc. 
   
   
       2 . The manufacture method according to  claim 1 , wherein in case of the size of said nano platinum particles, it is 1˜50 nm and final concentration to use is 0.00001˜0.0005 wt % (0.1-5 ppm) to the weight of said tissue manufacturing water, and it includes said nano platinum particles extracted through dissociation of said selected materials and reduction of Ion from platinum compound and platinum oxidize; [Ammonium hexachloroplatinum(IV); (NH4)2[PtCl6], Diamine Dinitritoplatinum(II); Pt(NO2)2(NH3)2, Hexachloroplatinum(IV) acid hydrate; H2(PtCl6).6H2O, Hexahydoxoplatinum(IV) acid; H2Pt(OH6), Platinum acetylacetonate; Pt(C5H7O2)2, Platinum chloride; PtCl, PtCl2, PtCl4, Platinum iodide; PtI2, Platinum oxide; PtO, PtO2, Pt2O3, Platinum sulfide; PtS2], and the one formed with made small platinum particles by the method of physical impact and crush;
 in case of the size of said nano gold particles, it is 1˜30 nm and the final concentration to use is 0.00001˜0.001 wt % (0.1˜10 ppm) to the weight of said tissue manufacturing water, and it includes the extracted gold through dissociation of said selected materials with pure water, ethanol and Isopropyl alcohol, and reduction of Ion from gold compound and gold oxidize: [Gold sulfide; Au2S, Gold hydroxide ; AuOH, Au(OH)3, Gold iodide; AuI, Gold oxide; Au2O, Au2O3, Gold oxide hydrate; Au2O3.xH2O, Gold chloride; AuCl, AuCl3, Gold chloride trihydrate ; HAuCl4.3H2O], and the one formed with made small gold particles by the method of physical impact, crush and electrical explosion;   in case of the size of the nano silver particles, it is 1˜20 nm and the final concentration to use is 0.00001˜0.002 wt % (0.1˜20 ppm) to the weight of the tissue manufacturing water, and it includes the one manufactured with the selected raw materials of its metal chloride and compound; [Silver nitrate; AgNO3, Silver chloride; AgCl, Silver chlorate ; AgClO3, AgClO4), Silver sulfate; Ag2SO4, Silver sulfite; Ag2SO3, Silver sulfide; Ag2S, Silver acetate; CH3COOAg, Silver selenide Ag2Se, Silver citrate hydra; AgO2CCH2C(OH)(CO2Ag)CH2CO2AgxH2], and the one formed with made small silver particles by the method of physical impact, crush and electrical explosion;   in case of the size of the nano zinc particles, it is 1˜50 nm and the final concentration used is 0.003˜0.03 wt % (30˜300 ppm) to the weight of the tissue manufacturing water, and it includes the extracted zinc through dissociation of the selected materials and reduction of Ion from zinc compound; [Zinc acetate; (CH3CO2)2Zn, Zinc acetate dihydrate; Zn(CH3COO)2.2H2O, Zinc acrylate;(H2C═CHCO2)2Zn, Zinc chloride; ZnCl2, Zinc iodide; ZnI2, Zinc phthalocyanine; C32H16N8Zn, Zinc selenide; ZnSe, Zinc sulfate; ZnSO4, Zinc sulfide; ZnS, Zinc 29H31H-tetrabenzol [b,g,l,q] porphyrin; C36H20N4Zn], and the one formed with made small zinc particles by the method of physical impact, crush and electrical explosion;   in case of the size of the nano germanium particles, it is 1˜50 nm and the final concentration to use is 0.0001˜0.01 wt % (1˜100 ppm) to the weight of the wet tissue manufacturing water, and it includes the extracted metal germanium through dissociation of said selected materials and reduction of Ion from germanium compound; [Germanium chloride; GeCl4, Germanium chloride dioxane complex; C4H8Cl2GeO2, Germanium fluoride; GeF4, Germanium iodide; GeI2, GeI4, Germanium isopropoxide; Ge(OCH(CH3)2)3, Germanium methoxide; Ge(OCH3)4, Germanium nitride; Ge3N4, Germanium oxide; GeO2, Germanium selenide; GeSe, GeSe2, Germanium sulfide; GeS], and organic compound germanium bis(2-carboxyethyl germanium sesquioxide); O[Ge(═O)CH2CH2CO2H]2, and the germanium particles crushed through physical impact;   in case of the size of the nano selenium particles, it is 1˜50 nm in and the final concentration to use is 0.0001˜0.01 wt % (1˜100 ppm) to the weight of the tissue manufacturing water, and it includes the extracted metal selenium through dissociation of the selected materials and reduction of Ion from selenium compound; [Selenium oxychloride; SeOCl2, Selenium sulfide; SeS2, Selenium tetrachloride; SeCl4, Seleno-L-cystine; C6H12N2O4Se2, Seleno-L-methionine; CH3SeCH2CH2CH(NH2)CO2H, Selenophene; C4H4Se, Selenous acid; H2SeO3, Germanium selenide; GeSe, GeSe2], and the one formed with crushed selenium particles by physical impact;   in said tissue manufacturing water mixed with one or more than one of platinum, gold, silver, germanium, selenium and zinc, hydrogen peroxide (H2O2) of 0.001˜0.045 wt % (10˜450 ppm) to the weight of the tissue manufacturing water as final concentration to avoid color changes of fabrics are contained;   said manufacturing method of antimicrobial and anti-fungus wet tissues that contain nano particles which is manufactured with nano particles of platinum, gold, silver, germanium, selenium and zinc made of each materials which is dissociated and resolved from its compound of platinum, gold, silver, germanium, selenium and zinc, and the one obtained by extracting each of platinum, gold, silver, germanium, selenium and zinc which is purged of nitrogen and irradiated with gamma ray after melt into water or non-water(volatile solvent) with high molecule stabilizer,   and said silver nano particles produced from the silver nitrate which is denitrated through an ion exchanger resin or distillation under vacuum and reducing pressure method to remove ‘NO3−’ which is generated in process of silver produce from silver nitrate as a counter ion of Ag+.   
   
   
       3 . The manufacture method according to  claim 2 , wherein the reducing agent which is used in manufacturing process of nano metal particles of gold, platinum, silver, germanium, selenium and zinc include formaldehyde, hydrazine, tocopherol, organic acids; [formic acid, citric acid, acetic acid, maleic acid, organic acid have carbon under 4, methyl ethanolamine HOCH2CH2N(CH3)2],
 the stability agent of selected one or more than one out of polyethylene, polyacrylonitrile, polymethylmeta-acrylate, polyurethane, polyacrylamide, polyethylene glycol and polyoxyethylene stearate are used in the manufacturing process of said nano metal particles of above gold, platinum, silver, germanium, selenium and zinc,   said manufacture method of antimicrobial and anti-fungus wet tissue with stability agent for silver of selected one or more than one from poly vinyl pyrrolidone-co-acrylic acid, polyoxyethylene stearate, polyvinyl Butyral, polyvinyl alcohol.   
   
   
       4 . A manufacture method of antimicrobial and anti-fungus wet tissue charaterized in that;
 forming antimicrobial and anti-fungus fiber by mixing nano material of selected one or more than one from gold, platinum, silver, germanium, selenium, zinc, copper and tungsten to the fiber material of selected one or more than one from viscose rayon, polyester, polyethylene, polypropylene, cotton and pulp,   and dipping said antimicrobial and anti-fungus fibers into tissue manufacturing water which is purified water or distilled water without preservative.   
   
   
       5 . The manufacture method according to  claim 4 , wherein nano metal particles of selected one or more than one from said germanium, selenium, zinc, copper and tungsten are added and spin in the material adding process before spinning of rayon fiber in the viscose rayon manufacturing process,
 in the case of fabric material such as polyester, polyethylene and polypropylene, nano metal particles of selected one or more than one from above platinum, gold, silver, germanium, selenium zinc, copper and tungsten are mixed with thermostatic plastic resin to produce either master-batch chips or compounding chips, and after extruding, mix these made master-batch chips of 3-10 wt % to the plastic raw materials with the plastic raw materials or use 100% of above made compounding chips to spin for antimicrobial and antifungal fiber,   in case of cotton, dip the cotton into water which contains nano metal particles of said platinum, gold, silver, zinc, germanium and selenium or spin with these nano metal particles,   in case of pulp, manufacturing method of antimicrobial and anti-fungus wet tissue is that mix selectively said nano metal particles of platinum, gold, silver, zinc, germanium and selenium with processing water which is used in the dispersion process of pulp materials or mix it with adhesive agents which are used in the process of having the pulp in certain thickness and shape or spray the mixture of above nano metal particles of platinum, gold, silver, germanium, selenium and zinc upon the surface of pulp after the pulp gets the shape of fabrics.   
   
   
       6 . The manufacture method according to  claim 4 , wherein said manufacturing method of antimicrobial and anti-fungus wet tissue contain that said fabrics are manufactured with viscose rayon, polyester, polyethylene, polypropylene, cotton and pulp as a fabric material by attach compression, melt and spraying to form the web, and mix nano metal particles of selected one or more than one from said platinum, gold, silver, germanium, selenium, zinc and copper with the adhesive agents for attach, melting fabric materials and spraying water. 
   
   
       7 . The manufacture method according to  claim 4 , wherein said manufacturing method of antimicrobial and anti-fungus wet tissues is especially as follows;
 in case of the size of said nano platinum particles, it is 1˜50 nm and final concentration to use is 0.00005˜0.003 wt % (0.5˜30 ppm) to the weight of said tissue manufacturing fabrics, and it includes nano platinum particles extracted through dissociation of the selected materials and reduction of Ion from platinum compound and platinum oxidize; [Ammonium hexachloroplatinum(IV); (NH4)2[PtCl6], Diamine Dinitritoplatinum(II); Pt(NO2)2(NH3)2, Hexachloroplatinum(IV) acid hydrate; H2(PtCl6).6H2O, Hexahydoxoplatinum(IV) acid; H2Pt(OH6), Platinum acetylacetonate; Pt(C5H7O2)2, Platinum chloride; PtCl, PtCl2, PtCl4, Platinum iodide; PtI2, Platinum oxide; PtO, PtO2, Pt2O3, Platinum sulfide; PtS2], and the one formed with made small platinum particles by the method of physical impact and crush;   in case of the size of said nano gold particles, it is 1˜30 nm and the final concentration to use is 0.00005˜0.005 wt % (0.5˜50 ppm) to the weight of the tissue manufacturing fabrics, and it includes the extracted gold through dissociation of the selected materials with pure water, ethanol and Isopropyl alcohol, and reduction of Ion from gold compound and gold oxidize: [Gold sulfide; Au2S, Gold hydroxide; AuOH, Au(OH)3, Gold iodide; AuI, Gold oxide; Au2O, Au2O3, Gold oxide hydrate; Au2O3. xH2O, Gold chloride; AuCl, AuCl3, Gold chloride trihydrate ; HAuCl4.3H2O], and the one formed with made small gold particles by the method of physical impact, crush and electrical explosion;   in case of the size of said nano silver particles, it is 1˜20 nm and the final concentration to use is 0.0005˜0.02 wt % (5˜200 ppm) to the weight of the tissue manufacturing fabrics, and it includes the one manufactured with the selected raw materials of its metal chloride and compound; [Silver nitrate; AgNO3, Silver chloride; AgCl, Silver chlorate; AgClO3, AgClO4), Silver sulfate; Ag2SO4, Silver sulfite; Ag2SO3, Silver sulfide; Ag2S, Silver acetate; CH3COOAg, Silver selenide Ag2Se, Silver citrate hydra; AgO2CCH2C(OH)(CO2Ag)CH2CO2AgxH2], and the one formed with made small silver particles by the method of physical impact, crush and electrical explosion;   in case of the size of said nano zinc particles, it is 1˜50 nm and the final concentration used is 0.003˜0.1 wt % (30˜1,000 ppm) to the weight of the tissue manufacturing fabrics, and it includes the extracted zinc through dissociation of the selected materials and reduction of Ion from zinc compound; [Zinc acetate; (CH3CO2)2Zn, Zinc acetate dihydrate; Zn(CH3COO)2.2H2O, Zinc acrylate;(H2C═CHCO2)2Zn, Zinc chloride; ZnCl2, Zinc iodide; ZnI2, Zinc phthalocyanine; C32H16N8Zn, Zinc selenide; ZnSe, Zinc sulfate; ZnSO4, Zinc sulfide; ZnS, Zinc 29H31H-tetrabenzol [b,g,l,q] porphyrin; C36H20N4Zn], and the one formed with made small zinc particles by the method of physical impact, crush and electrical explosion;   in case of the size of said nano germanium particles, it is 1˜50 nm and the final concentration to use is 0.0001˜0.03 wt % (1˜300 ppm) to the weight of the wet tissue manufacturing fabrics, and it includes the extracted metal germanium through dissociation of the selected materials and reduction of Ion from germanium compound; [Germanium chloride; GeCl4, Germanium chloride dioxane complex; C4H8Cl2GeO2, Germanium fluoride; GeF4, Germanium iodide; GeI2, Ge14, Germanium isopropoxide; Ge(OCH(CH3)2)3, Germanium methoxide; Ge(OCH3)4, Germanium nitride; Ge3N4, Germanium oxide; GeO2, Germanium selenide; GeSe, GeSe2, Germanium sulfide; GeS], and organic compound germanium bis(2-carboxyethyl germanium sesquioxide); O[Ge(═O)CH2CH2CO2H]2, and the germanium particles crushed through physical impact;   in case of the size of said nano selenium particles, it is 1˜50 nm in its particle size and the final concentration to use is 0.0001˜0.01 wt % (1˜100 ppm) to the weight of said tissue manufacturing fabrics, and it includes the extracted metal selenium through dissociation of the selected materials and reduction of Ion from selenium compound; [Selenium oxychloride; SeOCl2, Selenium sulfide; SeS2, Selenium tetrachloride; SeCl4, Selono-L-cystine; C6H12N2O4Se2, Seleno-L-methionine; CH3SeCH2CH2CH(NH2)CO2H, Selenophene; C4H4Se, Selenous acid; H2SeO3, Germanium selenide; GeSe, GeSe2], and the one formed with crushed selenium particles by physical impact;   in case of the size of said nano copper particles, it is 1˜50 nm and its final concentration to use is 0.001˜0.02 wt % (10˜200 ppm) to the weight of the tissue manufacturing fabrics, it includes nano copper particles extracted through dissociation of the selected materials and reduction of Ion from the material group of copper compound(Copper acetate ; CH3CO2Cu, copper(II)acetate; (CH3CO2)2Cu, copper(II)acetate monohydrate; (CH3COO)2Cu.H2O, CuBr2, copper chloride; CuCl, CuCl2, Copper(II) D-gluconate; Cl2H22CuO14, Copper(II) phthalocyamine; C32H16CuN8, Copper(II) sulfate; CuSO4, Copper(II) sulfide; Cu2S, Copper(II)selenide; Cu2Se) and the one formed with made small zinc particles by the method of physical impact, crush and electrical explosion;   in case of the size of said nano tungsten particles, it is 1-50 nm and its final concentration to use is 0.001˜0.03 wt % (10˜300 ppm) to the weight of the tissue manufacturing fabrics, it includes nano tungsten particles extracted through dissociation of the selected materials and reduction of Ion from the material group of tungsten compound (Tungsten(IV) carbide; WC, Tungsten(IV) chloride; WCl4, Tungsten(VI) chloride; WCl6, Tungsten(VI) dichloride dioxide; WCl2O2, Tungsten hexacarbonyl; W(CO)6, Tungsten(IV) Oxide; WO2, Tungsten(VI) Oxide; WO3, Tungsten(VI) oxychloride; WOCl4,Tungsten(o) pentacarbonyl-N-pentylisonitrile; (CO)3WCN(CH2)4CH3, Tungsten silicide; WSi2, Tungsten(IV) sulfide; WS2) and the one formed with made small tungsten particles by the method of physical impact, crush and electrical explosion;   said manufacturing method of antimicrobial and anti-fungus wet tissues that contain nano particles which is manufactured with nano particles of platinum, gold, silver, germanium, selenium, zinc, copper and tungsten made of each materials which is dissociated and resolved from its compound of platinum, gold, silver, germanium, selenium zinc, copper and tungsten and the one obtained by extracting each of platinum, gold, silver, germanium, selenium zinc, copper and tungsten which is purged of nitrogen and irradiated with gamma ray after melt into water or non-water(volatile solvent) with high molecule stabilizer, and the silver nano particles produced from the silver nitrate which is denitrated through an ion exchanger resin or distillation under vacuum and reducing pressure method to remove ‘NO3−’ which is generated in process of silver produce from silver nitrate as a counter ion of Ag+.   
   
   
       8 . The manufacture method according to  claim 7 , the reducing agent which is used in manufacturing process of nano metal particles of said gold, platinum, silver, germanium, selenium and zinc include formaldehyde, hydrazine, tocopherol, organic acids; [formic acid, citric acid, acetic acid, maleic acid, organic acid have carbon under 4, methyl ethanolamine HOCH2CH2N(CH3)2],
 the stability agent of selected one or more than one out of polyethylene, polyacrylonitrile, polymethylmeta-acrylate, polyurethane, polyacrylamide, polyethylene glycol and polyoxyethylene stearate are used in the manufacturing process of nano metal particles of above gold, platinum, silver, germanium, selenium and zinc,   said manufacturing method of antimicrobial and anti-fungus wet tissue with stability agent for silver of selected one or more than one from poly vinyl pyrrolidone-co-acrylic acid, polyoxyethylene stearate, polyvinyl Butyral, polyvinyl alcohol.   
   
   
       9 . A manufacture method of antimicrobial and anti-fungus wet tissues to have multiple antimicrobial and anti-fungus functions by both of non-woven fabrics and tissue manufacturing water is that form antimicrobial and anti-fungus non-woven fabrics by mixing and spinning nano material of selected one or more than one from gold, platinum, silver, germanium, selenium, zinc, copper and tungsten to the fiber material of selected one or more than one from viscose rayon, polyester, polyethylene, polypropylene, cotton and pulp, and mixing tissue manufacturing water which contains nano metal particles of selected one or more than one from gold, platinum, silver, germanium, selenium and zinc with above antimicrobial and anti-fungus non-woven fabrics. 
   
   
       10 . The manufacture method according to  claim 9 , wherein said manufacturing method of antimicrobial and anti-fungus wet tissues is especially as follows;
 in case of viscose rayon, said nano metal particles of selected one or more than one from germanium, selenium, zinc, copper and tungsten are added in the adding process of raw materials before spinning process of rayon fiber in manufacturing process of viscose rayon as fabric materials, and spin with above selected nano metal particles,   in case of polyester, polyethylene and polypropylene, either mater-batch chip or compounding chip are made by mixing said nano metal particles of selected one or more than one from above gold, platinum, silver, germanium, selenium, zinc, copper and tungsten with thermostatic plastic resin, and the above made master-batch chips are mixed with its plastic raw material with the ratio of 3˜10 wt % and spin yarn out of mixture of these, and in case of the above compounding chip, spin yarn out of 100 wt % of itself,   in case of cotton, it is dipped into the mixture water of said nano metal particles of platinum, gold, silver, zinc, germanium and selenium or spin yarn out of the mixture of cotton and above nano metal particles,   in case of pulp, it is made by mixing said nano metal particles of selected one or more than one from platinum, gold, silver, zinc, germanium and selenium with processing water which is used for dispersion process of pulp materials, and by mix it into adding process of adhesive agent to produce pulp in certain thickness and shape, and by mix the mixture of said nano metal particles into surface of pulp by spray after the pulp is formed as pulp fabric.   
   
   
       11 . The manufacture method according to  claim 9 , wherein said manufacturing method of antimicrobial and anti-fungus wet tissue is especially as follows;
 in case of viscose rayon, polyester, polyethylene, polypropylene, cotton and pulp as a fabric material by attach compression, melt and spraying to form the web, and mix nano metal particles of selected one or more than one from said platinum, gold, silver, germanium, selenium, zinc and copper with the adhesive agents for attach, melting fabric materials and spraying water.   
   
   
       12 . The manufacture method according to  claim 9 , wherein among the particles used for above fabric materials and its tissue manufacturing water is especially as follows;
 in case of the size of said nano platinum particles, it is 1˜50 nm and the final concentration to use is 0.00005˜0.001 wt % (0.5˜10 ppm) to the weight of the fabric materials, and 0.00001˜0.0003 wt % (0.1˜3 ppm) to the weight of the tissue manufacturing water and it includes nano platinum particles extracted through dissociation of the selected materials and reduction of Ion from platinum compound and platinum oxidize; [Ammonium hexachloroplatinum(IV);(NH4)2[PtCl6], Diamine Dinitritoplatinum(II); Pt(NO2)2(NH3)2, Hexachloroplatinum(IV) acid hydrate; H2(PtCl6).6H2O, Hexahydoxoplatinum(IV) acid; H2Pt(OH6), Platinum acetylacetonate; Pt(C5H7O2)2, Platinum chloride; PtCl, PtCl2, PtCl4, Platinum iodide; Pt12, Platinum oxide; PtO, PtO2, Pt2O3, Platinum sulfide; PtS2], and the one formed with made small platinum particles by the method of physical impact and crush;   in case of the size of said nano gold particles, it is 1˜30 nm and the final concentration to use is 0.00005˜0.001 wt % (0.5˜10 ppm) to the weight of said fabrics and 0.00001˜0.0005 wt % (0.1˜5 ppm) to the weight of the tissue manufacturing water, and it includes the extracted gold through dissociation of the selected materials with pure water, ethanol and Isopropyl alcohol, and reduction of Ion from gold compound and gold oxidize: [Gold sulfide; Au2S, Gold hydroxide; AuOH, Au(OH)3, Gold iodide; AuI, Gold oxide; Au2O, Au2O3, Gold oxide hydrate; Au2O3.xH2O, Gold chloride; AuCl, AuCl3, Gold chloride trihydrate; HAuCl4.3H2O], and the one formed with made small gold particles by the method of physical impact, crush and electrical explosion;   in case of the size of said nano silver particles, it is 1˜20 nm and the final concentration to use is 0.0005˜0.01 wt % (5˜100 ppm) to the weight of said fabrics and 0.00001˜0.0001 wt % (0.1˜10 ppm) to the weight of the tissue manufacturing water, and it includes the one manufactured with the selected raw materials of its metal chloride and compound; [Silver nitrate; AgNO3, Silver chloride; AgCl, Silver chlorate; AgClO3, AgClO4), Silver sulfate; Ag2SO4, Silver sulfite; Ag2SO3, Silver sulfide; Ag2S, Silver acetate; CH3COOAg, Silver selenide Ag2Se, Silver citrate hydra; AgO2CCH2C(OH)(CO2Ag)CH2CO2AgxH2], and the one formed with made small silver particles by the method of physical impact, crush and electrical explosion; in case of the size of said nano zinc particles, it is 1˜50 nm and the final concentration to use is 0.003˜0.03 wt % (30˜300 ppm) to the weight of said fabrics and 0.0001˜0.005 wt % (1˜50 ppm) to the weight of said tissue manufacturing water, and it includes the extracted zinc through dissociation of the selected materials and reduction of Ion from zinc compound; [Zinc acetate; (CH3CO2)2Zn, Zinc acetate dihydrate; Zn(CH3COO)22H2O, Zinc acrylate;(H2C═CHCO2)2Zn, Zinc chloride; ZnCl2, Zinc iodide; ZnI2, Zinc phthalocyanine; C32H16N8Zn, Zinc selenide; ZnSe, Zinc sulfate; ZnSO4, Zinc sulfide; ZnS, Zinc 29H31H-tetrabenzol [b,g,l,q] porphyrin; C36H20N4Zn], and the one formed with made small zinc particles by the method of physical impact, crush and electrical explosion;   in case of the size of said nano germanium particles, it is 1˜50 nm and the final concentration to use is 0.0001˜0.005 wt % (1˜50 ppm) to the weight of said fabrics and 0.0001˜0.005 wt % (0.5˜30 ppm) to the weight of the tissue manufacturing water, and it includes the extracted metal germanium through dissociation of the selected materials and reduction of Ion from germanium compound; [Germanium chloride; GeCl4, Germanium chloride dioxane complex; C4H8Cl2GeO2, Germanium fluoride; GeF4, Germanium iodide; GeI2, GeI4, Germanium isopropoxide; Ge(OCH(CH3)2)3, Germanium methoxide; Ge(OCH3)4, Germanium nitride; Ge3N4, Germanium oxide; GeO2, Germanium selenide; GeSe, GeSe2, Germanium sulfide; GeS], and organic compound germanium bis(2-carboxyethyl germanium sesquioxide); O[Ge(═O)CH2CH2CO2H]2, and the germanium particles crushed through physical impact;   in case of the size of said nano selenium particles, it is 1-50 nm and the final concentration to use is 0.0001˜0.005 wt % (1˜50 ppm) to the weight of above fabrics and 0.0001˜0.005 wt % (1˜50 ppm) to the weight of the tissue manufacturing water, and it includes the extracted metal selenium through dissociation of the selected materials and reduction of Ion from selenium compound; [Selenium oxychloride; SeOCl2, Selenium sulfide; SeS2, Selenium tetrachloride; SeCl4, Seleno-L-cystine; C6H12N2O4Se2, Seleno-L-methionine; CH3SeCH2CH2CH(NH2)CO2H, Selenophene; C4H4Se, Selenous acid; H2SeO3, Germanium selenide; GeSe, GeSe2], and the one formed with crushed selenium particles by physical impact;   in case of the size of said nano copper particles, it is 1˜50 nm and the final concentration to use is 0.001˜0.01 wt % (10˜100 ppm) to the weight of said fabrics, it includes nano copper particles extracted through dissociation of the selected materials and reduction of Ion from the material group of copper compound(Copper acetate ; CH3CO2Cu, copper(II)acetate; (CH3CO2)2Cu, copper(II)acetate monohydrate; (CH3COO)2Cu.H2O, CuBr2, copper chloride; CuCl, CuCl2, Copper(II) D-gluconate; Cl2H22CuO14, Copper(II) phthalocyamine; C32H16CuN8, Copper(II) sulfate; CuSO4, Copper(II) sulfide; Cu2S, Copper(II) selenide; Cu2Se) and the one formed with made small zinc particles by the method of physical impact, crush and electrical explosion;   in case of the size of said nano tungsten particles, it is 1˜50 nm and the final concentration to use is 0.001˜0.01 wt % (10˜100 ppm) to the weight of said fabrics, and it includes nano tungsten particles extracted through dissociation of the selected materials and reduction of Ion from the material group of tungsten compound (Tungsten(IV) carbide; WC, Tungsten(IV) chloride; WCl4, Tungsten(VI) chloride; WCl6, Tungsten(VI) dichloride dioxide; WCl2O2, Tungsten hexacarbonyl; W(CO)6, Tungsten(IV) Oxide; WO2, Tungsten(VI) Oxide; WO3, Tungsten(VI) oxychloride; WOCl4,Tungsten(o) pentacarbonyl-N-pentylisonitrile; (CO)3WCN(CH2)4CH3, Tungsten silicide; WSi2, Tungsten(IV) sulfide; WS2) and the one formed with made small tungsten particles by the method of physical impact, crush and electrical explosion;   said manufacturing method of antimicrobial and anti-fungus wet tissues that contain nano particles which is manufactured with nano particles of platinum, gold, silver, germanium, selenium, zinc, copper and tungsten made of each materials which is dissociated and resolved from its compound of platinum, gold, silver, germanium, selenium zinc, copper and tungsten and the one obtained by extracting each of platinum, gold, silver, germanium, selenium zinc, copper and tungsten which is purged of nitrogen and irradiated with gamma ray after melt into water or non-water(volatile solvent) with high molecule stabilizer, and the silver nano particles produced from the silver nitrate which is denitrated through an ion exchanger resin or distillation under vacuum and reducing pressure method to remove ‘NO3−’ which is generated in process of silver produce from silver nitrate as a counter ion of ‘Ag+’;   said manufacturing method of antimicrobial and anti-fungus wet tissue manufacturing water which contains one or more than one of above nano metal particles (platinum, gold, silver, germanium, selenium and zinc) with hydrogen peroxide (H2O2) of 0.001˜0.045 wt % (10˜450 ppm) to the weight of tissue manufacturing water as its final concentration to use for preventing color contamination of above fabrics.   
   
   
       13 . The manufacture method according to  claim 12 , wherein the reducing agent which is used in manufacturing process of nano metal particles of said gold, platinum, silver, germanium, selenium and zinc includes formaldehyde, hydrazine, tocopherol, organic acids; [formic acid, citric acid, acetic acid, maleic acid, organic acid have carbon under 4, methyl ethanolamine HOCH2CH2N(CH3)2],
 the stability agent of selected one or more than one out of polyethylene, polyacrylonitrile, polymethylmeta-acrylate, polyurethane, polyacrylamide, polyethylene glycol and polyoxyethylene stearate are used in the manufacturing process of nano metal particles of above gold, platinum, silver, germanium, selenium and zinc,   said manufacturing method of antimicrobial and anti-fungus wet tissue with stability agent for silver of selected one or more than one from poly vinyl pyrrolidone-co-acrylic acid, polyoxyethylene stearate, polyvinyl Butyral, polyvinyl alcohol.   
   
   
       14 . The manufacture method according to  claim 6 , wherein said manufacturing method of antimicrobial and anti-fungus wet tissues is especially as follows;
 in case of the size of said nano platinum particles, it is 1˜50 nm and final concentration to use is 0.00005˜0.003 wt % (0.5˜30 ppm) to the weight of said tissue manufacturing fabrics, and it includes nano platinum particles extracted through dissociation of the selected materials and reduction of Ion from platinum compound and platinum oxidize; [Ammonium hexachloroplatinum(IV);(NH4)2[PtCl6], Diamine Dinitritoplatinum(II); Pt(NO2)2(NH3)2, Hexachloroplatinum(IV) acid hydrate; H2(PtCl6).6H2O, Hexahydoxoplatinum(IV) acid; H2Pt(OH6), Platinum acetylacetonate; Pt(C5H7O2)2, Platinum chloride; PtCl, PtCl2, PtCl4, Platinum iodide; PtI2, Platinum oxide; PtO, PtO2, Pt2O3, Platinum sulfide; PtS2], and the one formed with made small platinum particles by the method of physical impact and crush;   in case of the size of said nano gold particles, it is 1˜30 nm and the final concentration to use is 0.00005˜0.005 wt % (0.5˜50 ppm) to the weight of the tissue manufacturing fabrics, and it includes the extracted gold through dissociation of the selected materials with pure water, ethanol and Isopropyl alcohol, and reduction of Ion from gold compound and gold oxidize: [Gold sulfide; Au2S, Gold hydroxide; AuOH, Au(OH)3, Gold iodide; AuI, Gold oxide; Au2O, Au2O3, Gold oxide hydrate; Au2O3.xH2O, Gold chloride; AuCl, AuCl3, Gold chloride trihydrate; HAuCl4.3H2O], and the one formed with made small gold particles by the method of physical impact, crush and electrical explosion;   in case of the size of said nano silver particles, it is 1˜20 nm and the final concentration to use is 0.0005˜0.02 wt % (5˜200 ppm) to the weight of the tissue manufacturing fabrics, and it includes the one manufactured with the selected raw materials of its metal chloride and compound; [Silver nitrate; AgNO3, Silver chloride; AgCl, Silver chlorate; AgClO3, AgClO4), Silver sulfate; Ag2SO4, Silver sulfite; Ag2SO3, Silver sulfide; Ag2S, Silver acetate; CH3COOAg, Silver selenide Ag2Se, Silver citrate hydra; AgO2CCH2C(OH)(CO2Ag)CH2CO2AgxH2], and the one formed with made small silver particles by the method of physical impact, crush and electrical explosion;   in case of the size of said nano zinc particles, it is 1˜50 nm and the final concentration used is 0.003˜0.1 wt % (30˜1,000 ppm) to the weight of the tissue manufacturing fabrics, and it includes the extracted zinc through dissociation of the selected materials and reduction of Ion from zinc compound; [Zinc acetate; (CH3CO2)2Zn, Zinc acetate dihydrate; Zn(CH3COO)2.2H2O, Zinc acrylate;(H2C═CHCO2)2Zn, Zinc chloride; ZnCl2, Zinc iodide; ZnI2, Zinc phthalocyanine; C32H16N8Zn, Zinc selenide; ZnSe, Zinc sulfate; ZnSO4, Zinc sulfide; ZnS, Zinc 29H31H-tetrabenzol [b,g,l,q] porphyrin; C36H20N4Zn], and the one formed with made small zinc particles by the method of physical impact, crush and electrical explosion;   in case of the size of said nano germanium particles, it is 1˜50 nm and the final concentration to use is 0.0001˜0.03 wt % (1˜300 ppm) to the weight of the wet tissue manufacturing fabrics, and it includes the extracted metal germanium through dissociation of the selected materials and reduction of Ion from germanium compound; [Germanium chloride; GeCl4, Germanium chloride dioxane complex; C4H8Cl2GeO2, Germanium fluoride; GeF4, Germanium iodide; GeI2, GeI4, Germanium isopropoxide; Ge(OCH(CH3)2)3, Germanium methoxide; Ge(OCH3)4, Germanium nitride; Ge3N4, Germanium oxide; GeO2, Germanium selenide; GeSe, GeSe2, Germanium sulfide; GeS], and organic compound germanium bis(2-carboxyethyl germanium sesquioxide); O[Ge(═O)CH2CH2CO2H]2, and the germanium particles crushed through physical impact;   in case of the size of said nano selenium particles, it is 1˜50 nm in its particle size and the final concentration to use is 0.0001˜0.01 wt % (1˜100 ppm) to the weight of said tissue manufacturing fabrics, and it includes the extracted metal selenium through dissociation of the selected materials and reduction of Ion from selenium compound; [Selenium oxychloride; SeOCl2, Selenium sulfide; SeS2, Selenium tetrachloride; SeCl4, Selono-L-cystine; C6H12N2O4Se2, Seleno-L-methionine; CH3SeCH2CH2CH(NH2)CO2H, Selenophene; C4H4Se, Selenous acid; H2SeO3, Germanium selenide; GeSe, GeSe2], and the one formed with crushed selenium particles by physical impact;   in case of the size of said nano copper particles, it is 1˜50 nm and its final concentration to use is 0.001˜0.02 wt % (10˜200 ppm) to the weight of the tissue manufacturing fabrics, it includes nano copper particles extracted through dissociation of the selected materials and reduction of Ion from the material group of copper compound(Copper acetate ; CH3CO2Cu, copper(II)acetate; (CH3CO2)2Cu, copper(II)acetate monohydrate; (CH3COO)2Cu .H2O, CuBr2, copper chloride; CuCl, CuCl2, Copper(II) D-gluconate; Cl2H22CuO14, Copper(II) phthalocyamine; C32H16CuN8, Copper(II) sulfate; CuSO4, Copper(II) sulfide; Cu2S, Copper(II) selenide; Cu2Se) and the one formed with made small zinc particles by the method of physical impact, crush and electrical explosion;   in case of the size of said nano tungsten particles, it is 1˜50 nm and its final concentration to use is 0.001˜0.03 wt % (10˜300 ppm) to the weight of the tissue manufacturing fabrics, it includes nano tungsten particles extracted through dissociation of the selected materials and reduction of Ion from the material group of tungsten compound (Tungsten(IV) carbide; WC, Tungsten(IV) chloride; WCl4, Tungsten(VI) chloride; WCl6, Tungsten(VI) dichloride dioxide; WCl2O2, Tungsten hexacarbonyl; W(CO)6, Tungsten(IV) Oxide; WO2, Tungsten(VI) Oxide; WO3, Tungsten(VI) oxychloride; WOCl4,Tungsten(o) pentacarbonyl-N-pentylisonitrile; (CO)3WCN(CH2)4CH3, Tungsten silicide; WSi2, Tungsten(IV) sulfide; WS2) and the one formed with made small tungsten particles by the method of physical impact, crush and electrical explosion;   said manufacturing method of antimicrobial and anti-fungus wet tissues that contain nano particles which is manufactured with nano particles of platinum, gold, silver, germanium, selenium, zinc, copper and tungsten made of each materials which is dissociated and resolved from its compound of platinum, gold, silver, germanium, selenium zinc, copper and tungsten and the one obtained by extracting each of platinum, gold, silver, germanium, selenium zinc, copper and tungsten which is purged of nitrogen and irradiated with gamma ray after melt into water or non-water(volatile solvent) with high molecule stabilizer, and the silver nano particles produced from the silver nitrate which is denitrated through an ion exchanger resin or distillation under vacuum and reducing pressure method to remove ‘NO3−’ which is generated in process of silver produce from silver nitrate as a counter ion of Ag+.   
   
   
       15 . The manufacture method according to  claim 14 , the reducing agent which is used in manufacturing process of nano metal particles of said gold, platinum, silver, germanium, selenium and zinc include formaldehyde, hydrazine, tocopherol, organic acids; [formic acid, citric acid, acetic acid, maleic acid, organic acid have carbon under 4, methyl ethanolamine HOCH2CH2N(CH3)2],
 the stability agent of selected one or more than one out of polyethylene, polyacrylonitrile, polymethylmeta-acrylate, polyurethane, polyacrylamide, polyethylene glycol and polyoxyethylene stearate are used in the manufacturing process of nano metal particles of above gold, platinum, silver, germanium, selenium and zinc, said manufacturing method of antimicrobial and anti-fungus wet tissue with stability agent for silver of selected one or more than one from poly vinyl pyrrolidone-co-acrylic acid, polyoxyethylene stearate, polyvinyl Butyral, polyvinyl alcohol.