US2010018613A1PendingUtilityA1

High Strength, High Toughness Steel Alloy

Individually held — no corporate assignee on recordPriority: Jul 24, 2008Filed: Jun 19, 2009Published: Jan 28, 2010
Est. expiryJul 24, 2028(~2 yrs left)· nominal 20-yr term from priority
Inventors:Paul M. Novotny
C22C 38/42C21D 6/004C22C 38/34C21D 1/32C22C 38/02C22C 38/46C22C 38/04C22C 38/44C21D 6/00
68
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Claims

Abstract

A high strength, high toughness steel alloy is disclosed. The alloy has the following broad weight percent composition. Element Broad C 0.35-0.55 Mn 0.6-1.2 Si 0.9-2.5 P 0.01 max. S 0.001 max.  Cr 0.75-2.0  Ni 3.5-7.0 Mo + ½ W 0.4-1.3 Cu 0.5-0.6 Co 0.01 max. V + ( 5/9) × Nb 0.2-1.0 Fe Balance Included in the balance are the usual impurities found in commercial grades of steel alloys produced for similar use and properties. Also disclosed is a hardened and tempered article that has very high strength and fracture toughness. The article is formed from the alloy having the broad weight percent composition set forth above. The alloy article according to this aspect of the invention is further characterized by being tempered at a temperature of about 500° F. to 600° F.

Claims

exact text as granted — not AI-modified
1 . A high strength, high toughness steel alloy having good temper resistance, said alloy comprising, in weight percent, about: 
     
       
         
               
               
               
             
                   
                   
               
                   
                 Carbon 
                 0.35-0.5  
               
                   
                 Manganese 
                 0.6-1.2 
               
                   
                 Silicon 
                 0.9-2.5 
               
                   
                 Phosphorus 
                 0.01 max. 
               
                   
                 Sulfur 
                 0.001 max.  
               
                   
                 Chromium 
                 1.0-1.5 
               
                   
                 Nickel 
                 3.5-4.5 
               
                   
                 Molybdenum 
                 0.4-1.3 
               
                   
                 Copper 
                 0.5-0.6 
               
                   
                 Cobalt 
                 0.01 max. 
               
                   
                 Vanadium 
                 0.25-0.35 
               
                   
                   
               
           
              
             
             
              
              
              
              
              
              
              
              
              
              
              
              
             
          
         
       
     
     the balance being iron and usual impurities, and wherein
   2≦(% Si+% Cu)/% V≦14. 
 
   
   
       2 . The alloy as claimed in  claim 1  which contains at least about 0.37% carbon. 
   
   
       3 . The alloy as claimed in  claim 2  which contains not more than about 0.45% carbon. 
   
   
       4 . The alloy as claimed in  claim 1  which contains at least about 1.3% silicon. 
   
   
       5 . The alloy as claimed in  claim 4  which contains not more than about 2.1% silicon. 
   
   
       6 . The alloy as claimed in  claim 1  which contains at least about 3.7% nickel. 
   
   
       7 . The alloy as claimed in  claim 6  which contains not more than about 4.2% nickel. 
   
   
       8 . The alloy as claimed in  claim 1  which contains at least about 0.5% molybdenum. 
   
   
       9 . The alloy as claimed in  claim 8  which contains not more than about 1.1% molybdenum. 
   
   
       10 . The alloy as claimed in  claim 1  which contains at least about 1.2% chromium. 
   
   
       11 . The alloy as claimed in  claim 10  which contains not more than about 1.35% chromium. 
   
   
       12 . The alloy as claimed in  claim 1  wherein 6≦(% Si+% Cu)/% V≦12. 
   
   
       13 . A high strength, high toughness steel alloy having good temper resistance, said alloy comprising, in weight percent, about: 
     
       
         
               
               
               
             
                   
                   
               
                   
                 Carbon 
                 0.37-0.45 
               
                   
                 Manganese 
                 0.7-0.9 
               
                   
                 Silicon 
                 1.3-2.1 
               
                   
                 Phosphorus 
                  0.005 max. 
               
                   
                 Sulfur 
                 0.0005 max. 
               
                   
                 Chromium 
                  1.2-1.35 
               
                   
                 Nickel 
                 3.7-4.2 
               
                   
                 Molybdenum 
                 0.5-1.1 
               
                   
                 Copper 
                 0.5-0.6 
               
                   
                 Cobalt 
                  0.01 max. 
               
                   
                 Vanadium 
                 0.25-0.35 
               
                   
                   
               
           
              
             
             
              
              
              
              
              
              
              
              
              
              
              
              
             
          
         
       
     
     the balance being iron and usual impurities, and wherein
   6≦(% Si+% Cu)/% V≦12. 
 
   
   
       14 . A hardened and tempered alloy article that has very high strength and fracture toughness, said article comprising an alloy consisting essentially of, in weight percent, about 
     
       
         
               
               
               
             
                   
                   
               
                   
                 Carbon 
                 0.35-0.5  
               
                   
                 Manganese 
                 0.6-1.2 
               
                   
                 Silicon 
                 1.3-2.5 
               
                   
                 Phosphorus 
                 0.01 max. 
               
                   
                 Sulfur 
                 0.001 max.  
               
                   
                 Chromium 
                 1.0-1.5 
               
                   
                 Nickel 
                 3.5-4.5 
               
                   
                 Molybdenum 
                 0.4-1.3 
               
                   
                 Copper 
                 0.5-0.6 
               
                   
                 Cobalt 
                 0.01 max. 
               
                   
                 Vanadium 
                 0.25-0.35 
               
                   
                   
               
           
              
             
             
              
              
              
              
              
              
              
              
              
              
              
              
             
          
         
       
     
     the balance being iron and usual impurities;
 wherein 2≦(% Si+% Cu)/% V≦14; 
 said article having been tempered at a temperature of about 500° F. to 600° F. 
 
   
   
       15 . The alloy article as claimed in  claim 14  which contains at least about 0.37% carbon. 
   
   
       16 . The alloy article as claimed in  claim 15  which contains not more than about 0.45% carbon. 
   
   
       17 . The alloy article as claimed in  claim 14  which contains at least about 1.3% silicon. 
   
   
       18 . The alloy article as claimed in  claim 17  which contains not more than about 2.1% silicon. 
   
   
       19 . The alloy article as claimed in  claim 14  which contains at least about 3.7% nickel. 
   
   
       20 . The alloy article as claimed in  claim 19  which contains not more than about 4.2% nickel. 
   
   
       21 . The alloy article as claimed in  claim 14  which contains at least about 0.5% molybdenum. 
   
   
       22 . The alloy article as claimed in  claim 21  which contains not more than about 1.1% molybdenum. 
   
   
       23 . The alloy article as claimed in  claim 14  which contains at least about 1.2% chromium. 
   
   
       24 . The alloy article as claimed in  claim 23  which contains not more than about 1.35% chromium. 
   
   
       25 . The alloy article as claimed in  claim 14  wherein 6≦(% Si+% Cu)/% V≦12. 
   
   
       26 . A hardened and tempered alloy article that has very high strength and fracture toughness, said article comprising an alloy consisting essentially of, in weight percent, about 
     
       
         
               
               
               
             
                   
                   
               
                   
                 Carbon 
                 0.37-0.45 
               
                   
                 Manganese 
                 0.7-0.9 
               
                   
                 Silicon 
                 1.3-2.1 
               
                   
                 Phosphorus 
                  0.005 max. 
               
                   
                 Sulfur 
                 0.0005 max. 
               
                   
                 Chromium 
                  1.2-1.35 
               
                   
                 Nickel 
                 3.7-4.2 
               
                   
                 Molybdenum 
                 0.5-1.1 
               
                   
                 Copper 
                 0.5-0.6 
               
                   
                 Cobalt 
                  0.01 max. 
               
                   
                 Vanadium 
                 0.25-0.35 
               
                   
                   
               
           
              
             
             
              
              
              
              
              
              
              
              
              
              
              
              
             
          
         
       
     
     the balance being iron and usual impurities;
 wherein 6≦(% Si+% Cu)/% V≦12; 
 said article having been tempered at a temperature of about 500° F. to 600° F. 
 
   
   
       27 . A high strength, high toughness steel alloy having good temper resistance, said alloy comprising, in weight percent, about: 
     
       
         
               
               
               
             
                   
                   
               
                   
                 C 
                 0.35-0.55 
               
                   
                 Mn 
                 0.6-1.2 
               
                   
                 Si 
                 0.9-2.5 
               
                   
                 P 
                 0.01 max. 
               
                   
                 S 
                 0.001 max.  
               
                   
                 Cr 
                 0.75-2.0  
               
                   
                 Ni 
                 3.5-7.0 
               
                   
                 Mo + ½ W 
                 0.4-1.3 
               
                   
                 Cu 
                 0.5-0.6 
               
                   
                 Co 
                 0.01 max. 
               
                   
                 V + ( 5/9) × Nb 
                 0.2-1.0 
               
                   
                   
               
           
              
             
             
              
              
              
              
              
              
              
              
              
              
              
              
             
          
         
       
     
     the balance being iron and usual impurities, and wherein
   2≦(% Si+% Cu)/(% V+(5/9)×% Nb)≦14. 
 
   
   
       28 . The alloy as claimed in  claim 27  which contains at least about 0.37% carbon. 
   
   
       29 . The alloy as claimed in  claim 28  which contains not more than about 0.45% carbon. 
   
   
       30 . The alloy as claimed in  claim 27  which contains at least about 1.3% silicon. 
   
   
       31 . The alloy as claimed in  claim 30  which contains not more than about 2.1% silicon. 
   
   
       32 . The alloy as claimed in  claim 27  which contains at least about 3.7% nickel. 
   
   
       33 . The alloy as claimed in  claim 32  which contains not more than about 4.2% nickel. 
   
   
       34 . The alloy as claimed in  claim 27  which contains at least about 0.5% molybdenum. 
   
   
       35 . The alloy as claimed in  claim 34  which contains not more than about 1.1% molybdenum. 
   
   
       36 . The alloy as claimed in  claim 27  which contains at least about 1.2% chromium. 
   
   
       37 . The alloy as claimed in  claim 36  which contains not more than about 1.35% chromium. 
   
   
       38 . The alloy as claimed in  claim 1  wherein 6≦(% Si+% Cu)/(% V+(5/9)×% Nb)≦12. 
   
   
       39 . A high strength, high toughness steel alloy having good temper resistance, said alloy comprising, in weight percent, about: 
     
       
         
               
               
               
             
                   
                   
               
                   
                 C 
                 0.37-0.50 
               
                   
                 Mn 
                 0.7-0.9 
               
                   
                 Si 
                 1.3-2.1 
               
                   
                 P 
                  0.005 max. 
               
                   
                 S 
                 0.0005 max. 
               
                   
                 Cr 
                 1.0-1.5 
               
                   
                 Ni 
                 3.7-4.5 
               
                   
                 Mo + ½ W 
                 0.5-1.1 
               
                   
                 Cu 
                 0.5-0.6 
               
                   
                 Co 
                  0.01 max. 
               
                   
                 V + ( 5/9) × Nb 
                 0.2-1.0 
               
                   
                   
               
           
              
             
             
              
              
              
              
              
              
              
              
              
              
              
              
             
          
         
       
     
     the balance being iron and usual impurities, and wherein
   6≦(% Si+% Cu)/(% V+(5/9)×% Nb)≦12. 
 
   
   
       40 . A hardened and tempered alloy article that has very high strength and fracture toughness, said article comprising an alloy consisting essentially of, in weight percent, about 
     
       
         
               
               
               
             
                   
                   
               
                   
                 C 
                 0.35-0.55 
               
                   
                 Mn 
                 0.6-1.2 
               
                   
                 Si 
                 1.3-2.5 
               
                   
                 P 
                 0.01 max. 
               
                   
                 S 
                 0.001 max.  
               
                   
                 Cr 
                 0.75-2.0  
               
                   
                 Ni 
                 3.5-7.0 
               
                   
                 Mo + ½ W 
                 0.4-1.3 
               
                   
                 Cu 
                 0.5-0.6 
               
                   
                 Co 
                 0.01 max. 
               
                   
                 V + ( 5/9) × Nb 
                 0.2-1.0 
               
                   
                   
               
           
              
             
             
              
              
              
              
              
              
              
              
              
              
              
              
             
          
         
       
     
     the balance being iron and usual impurities;
 wherein 2≦(% Si+% Cu)/(% V+(5/9)×% Nb)≦14; 
 said article having been tempered at a temperature of about 500° F. to 600° F. 
 
   
   
       41 . The alloy article as claimed in  claim 40  which contains at least about 0.37% carbon. 
   
   
       42 . The alloy article as claimed in  claim 41  which contains not more than about 0.45% carbon. 
   
   
       43 . The alloy article as claimed in  claim 40  which contains at least about 1.3% silicon. 
   
   
       44 . The alloy article as claimed in  claim 43  which contains not more than about 2.1% silicon. 
   
   
       45 . The alloy article as claimed in  claim 40  which contains at least about 3.7% nickel. 
   
   
       46 . The alloy article as claimed in  claim 45  which contains not more than about 4.2% nickel. 
   
   
       47 . The alloy article as claimed in  claim 40  which contains at least about 0.5% molybdenum. 
   
   
       48 . The alloy article as claimed in  claim 47  which contains not more than about 1.1% molybdenum. 
   
   
       49 . The alloy article as claimed in  claim 40  which contains at least about 1.2% chromium. 
   
   
       50 . The alloy article as claimed in  claim 49  which contains not more than about 1.35% chromium. 
   
   
       51 . The alloy article as claimed in  claim 40  wherein 6≦(% Si+% Cu)/(% V+(5/9)×% Nb)≦12. 
   
   
       52 . A hardened and tempered alloy article that has very high strength and fracture toughness, said article comprising an alloy consisting essentially of, in weight percent, about 
     
       
         
               
               
               
             
                   
                   
               
                   
                 C 
                 0.37-0.50 
               
                   
                 Mn 
                 0.7-0.9 
               
                   
                 Si 
                 1.3-2.1 
               
                   
                 P 
                  0.005 max. 
               
                   
                 S 
                 0.0005 max. 
               
                   
                 Cr 
                 1.0-1.5 
               
                   
                 Ni 
                 3.7-4.5 
               
                   
                 Mo + ½ W 
                 0.5-1.1 
               
                   
                 Cu 
                 0.5-0.6 
               
                   
                 Co 
                  0.01 max. 
               
                   
                 V + ( 5/9) × Nb 
                 0.2-1.0 
               
                   
                   
               
           
              
             
             
              
              
              
              
              
              
              
              
              
              
              
              
             
          
         
       
     
     the balance being iron and usual impurities;
 wherein 6≦(% Si+% Cu)/(% V+(5/9)×% Nb)≦12; 
 said article having been tempered at a temperature of about 500° F. to 600° F. 
 
   
   
       53 . A high strength, high toughness steel alloy having good temper resistance, said alloy consisting essentially of, in weight percent, about: 
     
       
         
               
               
               
             
                   
                   
               
                   
                 C 
                 0.35-0.50 
               
                   
                 Mn 
                 0.6-1.2 
               
                   
                 Si 
                 0.9-2.5 
               
                   
                 P 
                 0.01 max. 
               
                   
                 S 
                 0.001 max.  
               
                   
                 Cr 
                 0.75-2.0  
               
                   
                 Ni 
                 3.5-7.0 
               
                   
                 Mo 
                 0.01 max. 
               
                   
                 W 
                 0.8-2.6 
               
                   
                 Cu 
                 0.5-0.6 
               
                   
                 Co 
                 0.01 max. 
               
                   
                 Nb 
                 0.2-1.0 
               
                   
                 V 
                 0.01 max. 
               
                   
                   
               
           
              
             
             
              
              
              
              
              
              
              
              
              
              
              
              
              
              
             
          
         
       
     
     the balance being iron and usual impurities, and wherein
   2≦(% Si+% Cu)/% Nb≦14. 
 
   
   
       54 . The alloy as claimed in  claim 53  which contains at least about 0.37% carbon. 
   
   
       55 . The alloy as claimed in  claim 54  which contains not more than about 0.45% carbon. 
   
   
       56 . The alloy as claimed in  claim 53  which contains at least about 1.3% silicon. 
   
   
       57 . The alloy as claimed in  claim 56  which contains not more than about 2.1% silicon. 
   
   
       58 . The alloy as claimed in  claim 53  which contains at least about 3.7% nickel. 
   
   
       59 . The alloy as claimed in  claim 58  which contains not more than about 4.2% nickel. 
   
   
       60 . The alloy as claimed in  claim 59  which contains at least about 0.5% molybdenum. 
   
   
       61 . The alloy as claimed in  claim 60  which contains not more than about 1.1% molybdenum. 
   
   
       62 . The alloy as claimed in  claim 53  which contains at least about 1.0% tungsten. 
   
   
       63 . The alloy as claimed in  claim 62  which contains not more than about 2.2% tungsten. 
   
   
       64 . The alloy as claimed in  claim 53  which contains at least about 1.0% chromium. 
   
   
       65 . The alloy as claimed in  claim 64  which contains not more than about 1.5% chromium. 
   
   
       66 . The alloy as claimed in  claim 53  which contains at least about 0.2% niobium. 
   
   
       67 . The alloy as claimed in  claim 66  which contains not more than about 1.0% niobium. 
   
   
       68 . The alloy as claimed in  claim 53  wherein 6≦(% Si+% Cu)/% Nb≦12. 
   
   
       69 . A high strength, high toughness steel alloy having good temper resistance, said alloy consisting essentially of, in weight percent, about: 
     
       
         
               
               
               
             
                   
                   
               
                   
                 C 
                 0.37-0.50 
               
                   
                 Mn 
                 0.7-0.9 
               
                   
                 Si 
                 1.3-2.1 
               
                   
                 P 
                 0.005 max.  
               
                   
                 S 
                 0.0005 max.  
               
                   
                 Cr 
                 1.0-1.5 
               
                   
                 Ni 
                 3.7-4.5 
               
                   
                 Mo 
                 0.01 max. 
               
                   
                 W 
                 1.0-2.2 
               
                   
                 Cu 
                 0.5-0.6 
               
                   
                 Co 
                 0.01 max. 
               
                   
                 Nb 
                 0.2-1.0 
               
                   
                 V 
                 0.01 max. 
               
                   
                   
               
           
              
             
             
              
              
              
              
              
              
              
              
              
              
              
              
              
              
             
          
         
       
     
     the balance being iron and usual impurities, and wherein
   6≦(% Si+% Cu)/% Nb≦12. 
 
   
   
       70 . A hardened and tempered alloy article that has very high strength and fracture toughness, said article comprising an alloy consisting essentially of, in weight percent, about 
     
       
         
               
               
               
             
                   
                   
               
                   
                 C 
                 0.35-0.55 
               
                   
                 Mn 
                 0.6-1.2 
               
                   
                 Si 
                 1.3-2.5 
               
                   
                 P 
                 0.01 max. 
               
                   
                 S 
                 0.001 max.  
               
                   
                 Cr 
                 0.75-2.0  
               
                   
                 Ni 
                 3.5-7.0 
               
                   
                 Mo 
                 0.01 max. 
               
                   
                 W 
                 0.8-2.6 
               
                   
                 Cu 
                 0.5-0.6 
               
                   
                 Co 
                 0.01 max. 
               
                   
                 Nb 
                 0.2-1.0 
               
                   
                 V 
                 0.01 max. 
               
                   
                   
               
           
              
             
             
              
              
              
              
              
              
              
              
              
              
              
              
              
              
             
          
         
       
     
     the balance being iron and usual impurities;
 wherein 2≦(% Si+% Cu)/% Nb≦14; 
 said article having been tempered at a temperature of about 500° F. to 600° F. 
 
   
   
       71 . The alloy article as claimed in  claim 70  which contains at least about 0.37% carbon. 
   
   
       72 . The alloy article as claimed in  claim 71  which contains not more than about 0.45% carbon. 
   
   
       73 . The alloy article as claimed in  claim 70  which contains at least about 1.3% silicon. 
   
   
       74 . The alloy article as claimed in  claim 73  which contains not more than about 2.1% silicon. 
   
   
       75 . The alloy article as claimed in  claim 70  which contains at least about 3.7% nickel. 
   
   
       76 . The alloy article as claimed in  claim 75  which contains not more than about 4.2% nickel. 
   
   
       77 . The alloy article as claimed in  claim 70  which contains at least about 0.5% molybdenum. 
   
   
       78 . The alloy article as claimed in  claim 77  which contains not more than about 1.1% molybdenum. 
   
   
       79 . The alloy article as claimed in  claim 70  which contains at least about 1.0% tungsten. 
   
   
       80 . The alloy article as claimed in  claim 79  which contains not more than about 2.2% tungsten. 
   
   
       81 . The alloy article as claimed in  claim 70  which contains at least about 1.0% chromium. 
   
   
       82 . The alloy article as claimed in  claim 81  which contains not more than about 1.5% chromium. 
   
   
       83 . The alloy article as claimed in  claim 70  which contains at least about 0.2% niobium. 
   
   
       84 . The alloy article as claimed in  claim 83  which contains not more than about 1.0% niobium. 
   
   
       85 . The alloy article as claimed in  claim 70  wherein 6≦(% Si+% Cu)/% Nb≦12. 
   
   
       86 . A hardened and tempered alloy article that has very high strength and fracture toughness, said article comprising an alloy consisting essentially of, in weight percent, about 
     
       
         
               
               
               
             
                   
                   
               
                   
                 C 
                 0.37-0.50 
               
                   
                 Mn 
                 0.7-0.9 
               
                   
                 Si 
                 1.3-2.1 
               
                   
                 P 
                 0.005 max.  
               
                   
                 S 
                 0.0005 max.  
               
                   
                 Cr 
                 1.0-1.5 
               
                   
                 Ni 
                 3.7-4.5 
               
                   
                 Mo 
                 0.01 max. 
               
                   
                 W 
                 1.0-2.2 
               
                   
                 Cu 
                 0.5-0.6 
               
                   
                 Co 
                 0.01 max. 
               
                   
                 Nb 
                 0.2-1.0 
               
                   
                 V 
                 0.01 max. 
               
                   
                   
               
           
              
             
             
              
              
              
              
              
              
              
              
              
              
              
              
              
              
             
          
         
       
     
     the balance being iron and usual impurities;
 wherein 6≦(% Si+% Cu)/% Nb≦12; 
 said article having been tempered at a temperature of about 500° F. to 600° F.

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