Weakly oxidizing ammonium nitrate composite materials and methods for preparing such compositions

Abstract

A method forms a relatively stable ammonium nitrate composite material. The method includes (a) blending ammonium nitrate with an average particle diameter greater than about 1 mm and a substantially non-oxidizing compound in fine particle form; and (b) reducing the average size of said ammonium nitrate granules in the presence of the non-oxidizing compound in fine particle form to produce a substantially homogeneous blend of ammonium nitrate and the non-oxidizing compound having an average particle diameter of about 1 to about 1,000 μm to form a substantially non-explosive powder.

1 . A method of forming stable ammonium nitrate composite material comprising:
 (a) blending ammonium nitrate having an average particle diameter greater than about 1 mm and a substantially non-oxidizing compound having an average particle diameter of about 1,000 μm or less; and   (b) reducing the average size of said ammonium nitrate in the presence of said non-oxidizing compound to produce a substantially homogeneous blend of ammonium nitrate and said non-oxidizing compound having an average particle diameter of about 1 to about 1,000 μm to form a substantially non-explosive powder.   
     
     
         2 . The method of  claim 1 , wherein said non-oxidizing compound is at least one selected from the group consisting of non-oxidative or low-oxidative ammonium salts, non-oxidative or low-oxidative calcium salts, non-oxidative. or low-oxidative potassium salts, and other non-oxidative or low-oxidative salts. 
     
     
         3 . The method of  claim 1 , wherein said non-oxidizing compound is at least one selected from the group consisting of ammonium sulfate, ammonium phosphate, ammonium molybdenate, ammonium hexaflourosilicate, calcium nitrate, calcium carbonate, magnesium nitrate, potassium nitrate, and potassium phosphate. 
     
     
         4 . The method of  claim 1 , wherein the mole ratio of ammonium nitrate to the non-oxidizing compound is from about 0.8:1 to about 1:1.2. 
     
     
         5 . The method of  claim 1 , wherein the non-oxidizing compound is less than or equal to about 0.2 wt. % organic impurities. 
     
     
         6 . The method of  claim 1 , further comprising contacting the substantially non-explosive powder with a non-thermoreactive acid or a mixture of acid under ammoniating conditions such that ammonium sulfate at least partially covers or coats particles or groups of particles and causes agglomeration or growth of particles to further stabilize the substantially non-explosive powder. 
     
     
         7 . The method of  claim 1 , wherein the non-explosive powder is substantially free of ammonium nitrate sulfate double salts. 
     
     
         8 . A non-explosive composition comprising a substantially homogeneous blend of solid state ammonium nitrate having an average particle diameter of about 1 to about 1,000 μm and non-oxidizing particulate matter having an average particle diameter of about 1 to about 1,000 μm. 
     
     
         9 . The composition of  claim 8 , wherein said non-oxidizing compound is at least one selected from the group consisting of non-oxidative or low-oxidative ammonium salts, non-oxidative or low-oxidative calcium salts, non-oxidative or low-oxidative potassium salts, and other non-oxidative or low-oxidative salts. 
     
     
         10 . The composition of  claim 8 , wherein said non-oxidizing compound is at least one selected from the group consisting of ammonium sulfate, ammonium phosphate, ammonium molybdenate, ammonium hexaflouralsilicate, calcium nitrate, calcium carbonate, magnesium nitrate, potassium nitrate, and potassium phosphate. 
     
     
         11 . The composition of  claim 8 , wherein the mole ratio of ammonium nitrate to the non-oxidizing compound is from about 0.8:1 to about 1:1.2. 
     
     
         12 . The composition of  claim 8 , wherein the non-oxidizing compound is less than or equal to about 0:2 wt. % organic impurities. 
     
     
         13 . The composition of  claim 8 , which is substantially free of ammonium nitrate sulfate double salts. 
     
     
         14 . A method of forming stable ammonium nitrate composite material comprising:
 (a) reducing the average size of ammonium nitrate having an average particle diameter greater than about 1 mm; and   (b) blending said ammonium nitrate with a substantially non-oxidizing compound having an average particle diameter of about 1,000 μm or less to produce a substantially homogeneous blend of ammonium nitrate and said non-oxidizing compound having an average particle diameter of about 1 to about 1,000 μm to form a substantially non-explosive powder.   
     
     
         15 . The method of  claim 14 , wherein said non-oxidizing compound is at least one selected from the group consisting of non-oxidative or low-oxidative ammonium salts, non-oxidative or low-oxidative calcium salts, non-oxidative or tow-oxidative potassium salts, and other non-oxidative or low-oxidative salts. 
     
     
         16 . The method of  claim 14 , wherein said non-oxidizing compound is at least one selected from the group consisting of ammonium sulfate, ammonium phosphate, ammonium molybdenate, ammonium hexaflourosilicate, calcium nitrate, calcium carbonate, magnesium nitrate, potassium nitrate, and potassium phosphate. 
     
     
         17 . The method of  claim 14 , Wherein the mole ratio of ammonium nitrate to the non-oxidizing compound is from about 0.8:1 to about 1:1.2. 
     
     
         18 . The method of  claim 14 , wherein the non-oxidizing compound is less than or equal to about 0.2 wt. % organic impurities. 
     
     
         19 . The method of  claim 4 , further comprising contacting the substantially non-explosive powder with a non-thermoreactive acid or a mixture of acid under ammoniating conditions such that ammonium sulfate at least partially covers or coats particles or groups of particles and causes agglomeration or growth of particles to further stabilize the substantially non-explosive powder; 
     
     
         20 . The method of  claim 14 , wherein the non-explosive powder is substantially free of ammonium nitrate sulfate double salts.