US2009325778A1PendingUtilityA1

Silica-soda-lime glass compositions and their applications

Assignee: SAINT GOBAINPriority: Mar 13, 1997Filed: May 1, 2008Published: Dec 31, 2009
Est. expiryMar 13, 2017(expired)· nominal 20-yr term from priority
C03C 3/087C03B 27/00C03C 4/00C03C 3/083C03C 23/007
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Claims

Abstract

The subject of the invention is a glass composition of the silica-soda-lime type, intended for the manufacture of substrates or sheets, the said glass composition having a φ coefficient of between 0.50 and 0.85 N/(mm2·° C.) and a working point of less than 1200° C.

Claims

exact text as granted — not AI-modified
1 . A silica-soda-lime glass composition having a φ coefficient of between 0.50 and 0.85 N/(mm 2 ·° C.) and a working point of less than 1200° C. 
   
   
       2 . The glass composition according to  claim 1 , wherein it has a softening point of greater than 750° C. 
   
   
       3 . The glass composition according to  claim 1 , wherein the working point is less than 1190° C. 
   
   
       4 . The glass composition according to  claim 1 , wherein the thermal expansion coefficient α 20-300  is between 60 and 88×10 −7 ° C. −1 . 
   
   
       5 . The glass composition according to  claim 1 , wherein, wherein it satisfies the relationship:
   φ 2   ·c/a< 2 MPa 2 /° C. 2 .   
   
   
       6 . The glass composition according to  claim 1 , wherein it satisfies the relationship:
   0.70 MPa 2 /° C. 2 <φ 2   ·c/a.      
   
   
       7 . The glass composition according to  claim 1 , wherein it has a strain point of greater than 570° C. and preferably greater than 600° C. 
   
   
       8 . The glass composition according to  claim 1 , wherein it comprises the constituents below in the following proportions by weight based on total weight: 
     
       
         
               
               
               
             
                   
                   
               
                   
                 SiO 2 — 
                 55-75% 
               
                   
                 Al 2 O 3   
                 0-7% 
               
                   
                 ZrO 2   
                 0-8% 
               
                   
                 Na 2 O 
                  5-10% 
               
                   
                 K 2 O 
                 0-8% 
               
                   
                 CaO 
                   8-12%. 
               
                   
                   
               
           
              
             
             
              
              
              
              
              
              
              
             
          
         
       
     
   
   
       9 . The glass composition according to  claim 8 , wherein it comprises the constituents below in the following proportions by weight based on total weight: 
     
       
         
               
               
               
             
                   
                   
               
                   
                 SiO 
                 69.60% 
               
                   
                 Al 2 O 3   
                 0.90% 
               
                   
                 ZrO 2   
                 2.60% 
               
                   
                 Na 2 O 
                 7.10% 
               
                   
                 K 2 O 
                 2.90% 
               
                   
                 CaO 
                 10.50% 
               
                   
                 MgO 
                 2.00% 
               
                   
                 SrO 
                 3.90% 
               
                   
                 Fe 2 O 3   
                 <0.15% 
               
                   
                 Other oxides 
                 <0.50%. 
               
                   
                   
               
           
              
             
             
              
              
              
              
              
              
              
              
              
              
              
             
          
         
       
     
   
   
       10 . The glass composition according to  claim 8 , wherein it comprises the constituents below in the following proportions by weight based on total weight: 
     
       
         
               
               
               
             
                   
                   
               
                   
                 SiO 2   
                 74.40% 
               
                   
                 Al 2 O 3   
                 0.95% 
               
                   
                 Na 2 O 
                 9.05% 
               
                   
                 K 2 O 
                 0.45% 
               
                   
                 CaO 
                 9.10% 
               
                   
                 MgO 
                 5.65% 
               
                   
                 Fe 2 O 3   
                 0.10% 
               
                   
                 Other oxides 
                 0.30%. 
               
                   
                   
               
           
              
             
             
              
              
              
              
              
              
              
              
              
             
          
         
       
     
   
   
       11 . The glass composition according to  claim 1 , wherein it comprises the constituents below in the following proportions by weight based on total weight: 
     
       
         
               
               
               
             
                   
                   
               
                   
                 SiO 2   
                 55-75% 
               
                   
                 Al 2 O 3   
                 0-7% 
               
                   
                 ZrO 2   
                 0-8% 
               
                   
                 Na 2 O 
                 2-8% 
               
                   
                 K 2 O 
                 2-8% 
               
                   
                 CaO 
                  4-11% 
               
                   
                 MgO 
                  0-4%. 
               
                   
                   
               
           
              
             
             
              
              
              
              
              
              
              
              
             
          
         
       
     
   
   
       12 . The glass composition according to  claim 1 , wherein it has φ coefficient of less than 0.84, a strain point greater than 507° C. and an electrical resistivity such that its log ρ (250° C.)  is greater than 6.6. 
   
   
       13 . The glass composition according to  claim 12 , wherein the φ coefficient is less than 0.84 and greater than 0.75. 
   
   
       14 . The glass composition according to  claim 12 , wherein its strain point is between 530 and 590° C. 
   
   
       15 . The glass composition according to  claim 12 , wherein its electrical resistivity is such that log ρ (250° C.)  is greater than 8. 
   
   
       16 . The glass composition according to  claim 12 , wherein it comprises the constituents below in the following proportions by weight based on total weight: 
     
       
         
               
               
               
             
                   
                   
               
                   
                 SiO 2   
                 55-75% 
               
                   
                 Al 2 O 3   
                 0-5% 
               
                   
                 ZrO 2   
                 3-8% 
               
                   
                 Na 2 O 
                 4.5-8%   
               
                   
                 K 2 O 
                 3.5-7.5% 
               
                   
                 CaO 
                   7-11%. 
               
                   
                   
               
           
              
             
             
              
              
              
              
              
              
              
             
          
         
       
     
   
   
       17 . The glass composition according to  claim 1 , in the form of a monolithic glazing panel resistant to fire according to the G fire resistance classes. 
   
   
       18 . A plasma-screen, electroluminescent-screen or cold-cathode-screen comprising the glass composition according to  claim 1 . 
   
   
       19 . The glass composition according to  claim 12 , in the form of a monolithic glazing panel resistant to fire according to the G fire resistance classes. 
   
   
       20 . A plasma-screen, electroluminescent-screen or cold-cathode-screen comprising the glass composition according to  claim 12 .

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