Solid lithium secondary cell, and production method therefor

Abstract

A solid electrolyte layer and electrode layers are formed within an electrically insulating frame part, and current collecting plates are held by the electrically insulating frame part. Since the current collecting plates are held by the frame part, the shifting or coming-apart of the current collecting plates can be restrained. In order to cause the current collecting plates to be held by the frame part, a powder of material of the electrode layer is filled in between the frame part and the current collecting plates.

1 . A solid lithium secondary cell comprising:
 an electrically insulating tubular insulating frame;   a solid electrolyte layer formed within the insulating frame;   an electrode layer that is layered on at least one of surfaces of the solid electrolyte layer, and that is formed within the insulating frame; and   a current-collecting member that is layered on the electrode layer, and that is held by the insulating frame.   
   
   
       2 . The solid lithium secondary cell according to  claim 1 , wherein
 the electrode layer includes:   a positive electrode layer that is layered on one of sides of the solid electrolyte layer within the insulating frame, and that is formed by compressing a powder, and   a negative electrode layer that is layered on another side of the solid electrolyte layer within the insulating frame, and that is formed by compressing a powder, and wherein   the current-collecting member includes:   a positive electrode current-collecting member that is layered on the positive electrode layer, and that is held by the insulating frame; and   a negative electrode current-collecting member that is layered on the negative electrode layer, and that is held by the insulating frame.   
   
   
       3 . The solid lithium secondary cell according to  claim 1 , wherein:
 the current-collecting member is disposed so that at least a portion of the current-collecting member is within the insulating frame; and   a powder of a material of the electrode layer that contacts the current-collecting member fills a space between the insulating frame and the outer peripheral side surface of the current-collecting member.   
   
   
       4 . The solid lithium secondary cell according to  claim 3 , wherein an outside diameter of the current-collecting member is smaller than an inside diameter of the insulating frame by a length ranging from 200 micrometers to 1200 micrometers. 
   
   
       5 . A production method for a solid lithium secondary cell that includes:
 an electrically insulating tubular insulating frame;   a solid electrolyte layer formed within the insulating frame;   an electrode layer that is layered on at least one of surfaces of the solid electrolyte layer, and that is formed within the insulating frame by pressing a powder of a material of the electrode layer; and   a current-collecting member that is layered on the electrode layer, at least a portion of the current-collecting member being disposed within the insulating frame,   the production method being comprising   pressing the material of the electrode layer by applying force to the current-collecting member, wherein   when the material is pressed, pressing is performed so that the current-collecting member moves relative to the insulating frame.   
   
   
       6 . The production method according to  claim 5 , wherein
 a distance that the current-collecting member moves relative to the insulating frame is greater than or equal to one-fifth of a thickness of the current-collecting member, and is less than or equal to the thickness of the current-collecting member.   
   
   
       7 . A production method according to  claim 5 , wherein
 the electrode layer includes:   a positive electrode layer that is formed on one of sides of the solid electrolyte layer within the insulating frame; and   a negative electrode layer that is formed on another side of the solid electrolyte layer within the insulating frame, and wherein   the current-collecting member includes:   a positive electrode current-collecting member that is layered on the positive electrode layer, and that is held by the insulating frame; and   a negative electrode current-collecting member that is layered on the negative electrode layer, and that is held by the insulating frame.   
   
   
       8 . The production method according to  claim 5 , wherein an outside diameter of the current-collecting member is smaller than an inside diameter of the insulating frame by a length ranging from 200 micrometers to 1200 micrometers. 
   
   
       9 . A production method for a solid lithium secondary cell, comprising:
 making an electrolyte-electrode layered assembly that has a layered structure that includes an electrode layer and a solid electrolyte layer, by placing a powder of a material of the electrode layer, and a powder of a material of the solid electrolyte layer, in an electrically insulating tubular insulating frame, and tentatively pressing the powder of the material of the electrode layer, and the powder of the material of the solid electrolyte layer,   layering the current-collecting member on the electrolyte-electrode layered assembly so that at least a portion of the current-collecting member is disposed within the insulating frame; and   definitively pressing the electrolyte-electrode layered assembly on which the current-collecting member has been layered, in such a manner that the current-collecting member moves relative to the insulating frame.   
   
   
       10 . The production method according to  claim 9 , wherein
 a distance that the current-collecting member moves relative to the insulating frame is greater than or equal to one-fifth of a thickness of the current-collecting member, and is less than or equal to the thickness of the current-collecting member.   
   
   
       11 . A production method according to  claim 9 , wherein
 the electrode layer includes:   a positive electrode layer that is formed on one of sides of the solid electrolyte layer within the insulating frame; and   a negative electrode layer that is formed on another side of the solid electrolyte layer within the insulating frame, and wherein   the current-collecting member includes:   a positive electrode current-collecting member that is layered on the positive electrode layer, and that is held by the insulating frame; and   a negative electrode current-collecting member that is layered on the negative electrode layer, and that is held by the insulating frame.   
   
   
       12 . The production method according to  claim 9 , wherein an outside diameter of the current-collecting member is smaller than an inside diameter of the insulating frame by a length ranging from 200 micrometers to 1200 micrometers. 
   
   
       13 . A production method for a solid lithium secondary cell that includes:
 an electrically insulating tubular insulating frame;   a solid electrolyte layer formed within the insulating frame;   an electrode layer that is layered on at least one of surfaces of the solid electrolyte layer, and that is formed within the insulating frame by pressing a powder of a material of the electrode layer; and   a current-collecting member that is layered on the electrode layer, at least a portion of the current-collecting member being disposed within the insulating frame, the production method being comprising   pressing the material of the electrode layer by applying force to the current-collecting member, wherein   when the material is pressed, pressing is performed so that the material of the electrode layer gets in between the insulating frame and an outer periphery of the current-collecting member as a layer of the powder of the material of the electrode layer plastically deforms.   
   
   
       14 . A production method according to  claim 13 , wherein
 the electrode layer includes:   a positive electrode layer that is formed on one of sides of the solid electrolyte layer within the insulating frame; and   a negative electrode layer that is formed on another side of the solid electrolyte layer within the insulating frame, and wherein   the current-collecting member includes:   a positive electrode current-collecting member that is layered on the positive electrode layer, and that is held by the insulating frame; and   a negative electrode current-collecting member that is layered on the negative electrode layer, and that is held by the insulating frame.   
   
   
       15 . The production method according to  claim 13 , wherein an outside diameter of the current-collecting member is smaller than an inside diameter of the insulating frame by a length ranging from 200 micrometers to 1200 micrometers. 
   
   
       16 . A production method for a solid lithium secondary cell, comprising:
 making an electrolyte-electrode layered assembly that has a layered structure that includes an electrode layer, and a solid electrolyte layer, by placing a powder of a material of the electrode layer, and a powder of a material of the solid electrolyte layer, in an electrically insulating tubular insulating frame, and tentatively pressing the powder of the material of the electrode layer, and the powder of the material of the solid electrolyte layer;   layering the current-collecting member on the electrolyte-electrode layered assembly so that at least a portion of the current-collecting member is disposed within the insulating frame; and   definitively pressing the electrolyte-electrode layered assembly on which the current-collecting member has been layered, in such a manner that the material of the electrode layer gets in between the insulating frame and an outer periphery of the current-collecting member as the electrode layer plastically deforms.   
   
   
       17 . A production method according to  claim 16 , wherein
 the electrode layer includes:   a positive electrode layer that is formed on one of sides of the solid electrolyte layer within the insulating frame; and   a negative electrode layer that is formed on another side of the solid electrolyte layer within the insulating frame, and wherein   the current-collecting member includes:   a positive electrode current-collecting member that is layered on the positive electrode layer, and that is held by the insulating frame; and   a negative electrode current-collecting member that is layered on the negative electrode layer, and that is held by the insulating frame.   
   
   
       18 . The production method according to  claim 16 , wherein an outside diameter of the current-collecting member is smaller than an inside diameter of the insulating frame by a length ranging from 200 micrometers to 1200 micrometers.