US2009266451A1PendingUtilityA1

Ultra-High Strength Martensitic Alloy

Individually held — no corporate assignee on recordPriority: Nov 18, 2005Filed: Feb 5, 2009Published: Oct 29, 2009
Est. expiryNov 18, 2025(expired)· nominal 20-yr term from priority
Inventors:Paul M. Novotny
C22C 38/44C22C 38/52C22C 38/005
63
PatentIndex Score
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Cited by
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Claims

Abstract

An age hardenable martensitic steel alloy is disclosed. The alloy has the following composition in weight percent. C 0.30-0.36 Mn 0.05 max. Si 0.05 max. P 0.01 max. S 0.0010 max. Cr 1.30-3.2  Ni 10.0-13.0 Mo  1.0-2.70 Co 13.8-17.4 Ti 0.02 max. Al 0.005 max. Ce 0.030 max. La 0.010 max. The balance is iron and the usual impurities. The composition of this alloy is balanced to provide a unique combination of very high strength, together with good toughness, ductility, and resistance to fatigue.

Claims

exact text as granted — not AI-modified
1 . An age hardenable martensitic steel alloy, consisting essentially of, in weight percent, about 
     
       
         
               
               
               
             
                   
                   
               
                   
                 C 
                 0.32-0.36 
               
               
               
               
               
             
                   
                 Mn 
                 0.05 
                 max. 
               
                   
                 Si 
                 0.05 
                 max. 
               
                   
                 P 
                 0.005 
                 max. 
               
                   
                 S 
                 0.0010 
                 max. 
               
               
               
               
             
                   
                 Cr 
                 1.30-2.30 
               
                   
                 Ni 
                 11.5-13.0 
               
                   
                 Mo 
                  1.8-2.70 
               
                   
                 Co 
                 15.4-17.4 
               
               
               
               
               
             
                   
                 Ti 
                 0.02 
                 max. 
               
                   
                 Al 
                 0.005 
                 max. 
               
                   
                 Ce 
                 0.030 
                 max. 
               
                   
                 La 
                 0.010 
                 max. 
               
                   
                   
               
           
              
             
             
              
             
          
           
              
              
              
              
             
          
           
              
              
              
              
             
          
           
              
              
              
              
              
             
          
         
       
     
     the balance being iron and usual impurities. 
   
   
       2 . (canceled) 
   
   
       3 . An age hardenable martensitic steel alloy as set forth in  claim 1  that contains at least about 2.0 weight percent chromium. 
   
   
       4 . (canceled) 
   
   
       5 . An age hardenable martensitic steel alloy as set forth in  claim 1  that contains not more than about 16.0 weight percent cobalt. 
   
   
       6 . (canceled) 
   
   
       7 . (canceled) 
   
   
       8 . An age hardenable martensitic steel alloy as set forth in  claim 1  that contains not more than about 2.2 weight percent molybdenum. 
   
   
       9 . (canceled) 
   
   
       10 . An age hardenable martensitic steel alloy, consisting essentially of, in weight percent, about 
     
       
         
               
               
               
             
                   
                   
               
                   
                 C 
                 0.32-0.35 
               
               
               
               
               
             
                   
                 Mn 
                 0.05 
                 max. 
               
                   
                 Si 
                 0.05 
                 max. 
               
                   
                 P 
                 0.005 
                 max. 
               
                   
                 S 
                 0.0010 
                 max. 
               
               
               
               
             
                   
                 Cr 
                 2.0-2.3 
               
                   
                 Ni 
                 11.5-13.0 
               
                   
                 Mo 
                 1.8-2.2 
               
                   
                 Co 
                 15.0-16.0 
               
               
               
               
               
             
                   
                 Ti 
                 0.015 
                 max. 
               
                   
                 Al 
                 0.003 
                 max. 
               
                   
                 Ce 
                 0.020 
                 max. 
               
                   
                 La 
                 0.010 
                 max. 
               
                   
                   
               
           
              
             
             
              
             
          
           
              
              
              
              
             
          
           
              
              
              
              
             
          
           
              
              
              
              
              
             
          
         
       
     
     the balance being iron and usual impurities. 
   
   
       11 . (canceled) 
   
   
       12 . An age hardenable martensitic steel alloy as set forth in  claim 10  that contains at least about 2.20 weight percent chromium. 
   
   
       13 . (canceled) 
   
   
       14 . (canceled) 
   
   
       15 . (canceled) 
   
   
       16 . (canceled) 
   
   
       17 . An age hardenable martensitic steel alloy as set forth in  claim 10  that contains not more than about 2.0 weight percent molybdenum. 
   
   
       18 . An age hardenable martensitic steel alloy as set forth in  claim 10  that contains not more than about 0.34 weight percent carbon. 
   
   
       19 . An age hardenable martensitic steel alloy, consisting essentially of, in weight percent, about 
     
       
         
               
               
               
             
                   
                   
               
                   
                 C 
                 0.32-0.34 
               
               
               
               
               
             
                   
                 Mn 
                 0.04 
                 max. 
               
                   
                 Si 
                 0.03 
                 max. 
               
                   
                 P 
                 0.003 
                 max. 
               
                   
                 S 
                 0.0005 
                 max. 
               
               
               
               
             
                   
                 Cr 
                 2.20-2.30 
               
                   
                 Ni 
                 11.5-12.5 
               
                   
                 Mo 
                 1.80-1.90 
               
                   
                 Co 
                 15.4-16.0 
               
               
               
               
               
             
                   
                 Ti 
                 0.01 
                 max. 
               
                   
                 Al 
                 0.001 
                 max. 
               
                   
                 Ce 
                 0.010 
                 max. 
               
                   
                 La 
                 0.005 
                 max. 
               
                   
                   
               
           
              
             
             
              
             
          
           
              
              
              
              
             
          
           
              
              
              
              
             
          
           
              
              
              
              
              
             
          
         
       
     
     the balance being iron and usual impurities. 
   
   
       20 . An age hardenable martensitic steel alloy as set forth in  claim 1 ,  10 , or  19  comprising an element selected from the group consisting of calcium, magnesium, yttrium, and combinations thereof, in place of at least a portion of the cerium and lanthanum. 
   
   
       21 . An article of manufacture formed from a martensitic steel alloy having a weight percent composition consisting essentially of about 
     
       
         
               
               
               
             
                   
                   
               
                   
                 C 
                 0.32-0.36 
               
               
               
               
               
             
                   
                 Mn 
                 0.05 
                 max. 
               
                   
                 Si 
                 0.05 
                 max. 
               
                   
                 P 
                 0.005 
                 max. 
               
                   
                 S 
                 0.0010 
                 max. 
               
               
               
               
             
                   
                 Cr 
                 1.30-2.30 
               
                   
                 Ni 
                 11.5-13.0 
               
                   
                 Mo 
                  1.8-2.70 
               
                   
                 Co 
                 15.4-17.4 
               
               
               
               
               
             
                   
                 Ti 
                 0.02 
                 max. 
               
                   
                 Al 
                 0.005 
                 max. 
               
                   
                 Ce 
                 0.030 
                 max. 
               
                   
                 La 
                 0.010 
                 max. 
               
                   
                   
               
           
              
             
             
              
             
          
           
              
              
              
              
             
          
           
              
              
              
              
             
          
           
              
              
              
              
              
             
          
         
       
     
     and the balance of said alloy is iron and usual impurities, wherein said article provides a tensile strength of at least about 345 ksi (2344 MPa). 
   
   
       22 . An article of manufacture as claimed in  claim 21  wherein said article is in the age hardened condition. 
   
   
       23 . An article of manufacture as claimed in  claim 21  which contains more than 1.8% molybdenum. 
   
   
       24 . An article of manufacture as claimed in  claim 21  wherein the ratio Ce/S is greater than 4. 
   
   
       25 . An article of manufacture as claimed in  claim 24  wherein the ratio Ce/S is not greater about 20.

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