Carbon nanotube freestanding membrane, process for production of the same, composites having carbon nanotube membranes and process for production thereof

Abstract

The invention provides a composite comprising a substrate and a membrane of vertically aligned carbon nanotubes formed on the substrate which membrane is independent of the material of the substrate and a process for the production of the same. A process for producing the first composite comprising the first substrate and vertically aligned carbon nanotubes formed on the first substrate which comprises the step (a) of preparing the second composite comprising the second substrate made of quartz or silicon and vertically aligned carbon nanotubes formed on the second substrate, the step (b) of subjecting the second composite to water immersion wherein the temperature (T w ) of the water is higher than the temperature (T c ) of the second composite with a temperature difference ΔT (=T w −T c ) of at least 25° C. to make the carbon nanotubes peel off the second substrate and arrange them either in water or on the surface thereof, and the step (c) of arranging the resulting vertically aligned carbon nanotubes on the first substrate.

1 . A freestanding membrane consisting of vertically aligned carbon nanotubes. 
     
     
         2 . The freestanding membrane according to  claim 1 , wherein the freestanding membrane has a thickness of 200 nm to 500 μm. 
     
     
         3 . The freestanding membrane according to  claim 1 , wherein a ratio r/d of a diameter r of a circle to a thickness d of the freestanding membrane is 10 or more, the circle being calculated for the freestanding membrane and having an area equivalent to that of the freestanding membrane. 
     
     
         4 . The freestanding membrane according to  claim 1 , wherein the freestanding membrane is free from silicon (Si). 
     
     
         5 . The freestanding membrane according to  claim 1 , wherein the freestanding membrane is free from halogen. 
     
     
         6 . The freestanding membrane according to  claim 5 , wherein the halogen is fluoride, and the freestanding membrane has fluoride of 100 ppm or less. 
     
     
         7 . The freestanding membrane according to  claim 5 , wherein the halogen is chlorine, and the freestanding membrane has chlorine of 100 ppm or less. 
     
     
         8 . The freestanding membrane according to  claim 1 , wherein when the vertically aligned carbon nanotubes are formed on a substrate and the carbon nanotubes are peeled off from the substrate to form the freestanding membrane, the form of the vertically aligned carbon nanotubes on the substrate is substantially the same as the form of the vertically aligned carbon nanotubes in the freestanding membrane. 
     
     
         9 . The freestanding membrane according to  claim 1 , wherein the carbon nanotubes are multi-walled carbon nanotubes and/or single-walled carbon nanotubes. 
     
     
         10 . The freestanding membrane according to  claim 1 , wherein the carbon nanotubes are single-walled carbon nanotubes. 
     
     
         11 . A process for producing a freestanding membrane consisting of vertically aligned carbon nanotubes, comprising the steps of:
 (a) preparing a composite comprising a substrate and vertically aligned carbon nanotubes formed on the substrate; and   (b) immersing the composite in water wherein a temperature (T w ) of the water is higher than a temperature (T c ) of the composite with a temperature difference ΔT (=T w −T c ) between the temperature (T w ) and the temperature (T c ) being 25° C. or more to peel off the vertically aligned carbon nanotubes from the composite to obtain the freestanding membrane.   
     
     
         12 . The process according to  claim 11 , wherein the step (b) comprises the step of forming the freestanding membrane so that the freestanding membrane is partially supported by a support member. 
     
     
         13 . The process according to  claim 11 , wherein the freestanding membrane has a thickness of 200 nm to 500 μm. 
     
     
         14 . The process according to  claim 11 , wherein a ratio r/d of a diameter r of a circle to a thickness d of the freestanding membrane is 10 or more, the circle being calculated for the freestanding membrane and having an area equivalent to that of the freestanding membrane. 
     
     
         15 . The process according to  claim 11 , wherein the form of the vertically aligned carbon nanotubes in the freestanding membrane substantially maintains that of the vertically aligned carbon nanotubes in the composite. 
     
     
         16 . The process according to  claim 11 , wherein the freestanding membrane is free from silicon (Si). 
     
     
         17 . The process according to  claim 11 , wherein the freestanding membrane is free from halogen. 
     
     
         18 . The process according to  claim 17 , wherein the halogen is fluoride, and the freestanding membrane has fluoride of 100 ppm or less. 
     
     
         19 . The process according to  claim 17 , wherein the halogen is chlorine, and the freestanding membrane has chlorine of 100 ppm or less. 
     
     
         20 . The process according to  claim 11 , wherein the carbon nanotubes are multi-walled carbon nanotubes and/or single-walled carbon nanotubes. 
     
     
         21 . The process according to  claim 11 , wherein the carbon nanotubes are single-walled carbon nanotubes. 
     
     
         22 . A process for peeling off vertically aligned carbon nanotubes from a substrate, comprising the steps of:
 (a) preparing a composite comprising the substrate and the vertically aligned carbon nanotubes formed on the substrate; and   (b) immersing the composite in water wherein a temperature (T w ) of the water is higher than a temperature (T c ) of the composite with a temperature difference ΔT (=T w −T c ) between the temperature (T w ) and the temperature (T c ) being 25° C. or more to peel off the carbon nanotubes from the composite.   
     
     
         23 . The process according to  claim 22 , wherein the vertically aligned carbon nanotubes peeled have a thickness of 200 nm to 500 μm. 
     
     
         24 . The process according to  claim 22 , wherein the form of the vertically aligned carbon nanotubes peeled substantially maintains the form of the vertically aligned carbon nanotubes in the composite. 
     
     
         25 . The process according to  claim 22 , wherein the vertically aligned carbon nanotubes peeled are free from silicon (Si). 
     
     
         26 . The process according to  claim 22 , wherein the vertically aligned carbon nanotubes peeled are free from halogen. 
     
     
         27 . The process according to  claim 26 , wherein the halogen is fluoride, and the vertically aligned carbon nanotubes peeled have fluoride of 100 ppm or less. 
     
     
         28 . The process according to  claim 26 , wherein the halogen is chlorine, and the vertically aligned carbon nanotubes peeled have chlorine of 100 ppm or less. 
     
     
         29 . The process according to  claim 22 , wherein the carbon nanotubes are multi-walled carbon nanotubes and/or single-walled carbon nanotubes. 
     
     
         30 . The process according to  claim 22 , wherein the carbon nanotubes are single-walled carbon nanotubes. 
     
     
         31 . A composite comprising a first substrate (excluding quartz or silicon) and vertically aligned carbon nanotubes formed on the first substrate. 
     
     
         32 . The composite according to  claim 31 , wherein the vertically aligned carbon nanotubes has a thickness of 200 nm to 500 μm. 
     
     
         33 . The composite according to  claim 31 , wherein the vertically aligned carbon nanotubes are free from silicon (Si). 
     
     
         34 . The composite according to  claim 31 , wherein the vertically aligned carbon nanotubes are free from halogen. 
     
     
         35 . The composite according to  claim 34 , wherein the halogen is fluoride, and the vertically aligned carbon nanotubes have fluoride of 100 ppm or less. 
     
     
         36 . The composite according to  claim 34 , wherein the halogen is chlorine, and the vertically aligned carbon nanotubes have chlorine of 100 ppm or less. 
     
     
         37 . The composite according to  claim 31 , wherein when the vertically aligned carbon nanotubes in the composite are formed on a second substrate, are peeled off from the second substrate, and are formed on the composite, the form of the vertically aligned carbon nanotubes on the second substrate is substantially the same as the form of the vertically aligned carbon nanotubes in the composite. 
     
     
         38 . The composite according to  claim 31 , wherein the carbon nanotubes are multi-walled carbon nanotubes and/or single-walled carbon nanotubes. 
     
     
         39 . The composite according to  claim 31 , wherein the carbon nanotubes are single-walled carbon nanotubes. 
     
     
         40 . A process for producing a first composite comprising a first substrate and vertically aligned carbon nanotubes formed on the first substrate, comprising the steps of:
 (a) preparing a second composite comprising a second substrate made of quartz or silicon and vertically aligned carbon nanotubes formed on the second substrate;   (b) immersing the second composite in water wherein a temperature (T w ) of the water is higher than a temperature (T c ) of the second composite with a temperature difference ΔT (=T w −T c ) between the temperature (T w ) and the temperature (T c ) being 25° C. or more to peel off the vertically aligned carbon nanotubes from the second substrate, and arranging the vertically aligned carbon nanotubes in the water or on the surface of the water; and   (c) placing the vertically aligned carbon nanotubes peeled on the first substrate to form the vertically aligned carbon nanotubes on the first substrate.   
     
     
         41 . The process according to  claim 40 , wherein the first substrate is made of a material excluding a material consisting of quartz or a material consisting of silicon. 
     
     
         42 . The process according to  claim 40 , wherein the form of the vertically aligned carbon nanotubes in the first composite substantially maintains the form of the vertically aligned carbon nanotubes in the second composite. 
     
     
         43 . The process according to  claim 40 , wherein the vertically aligned carbon nanotubes have a thickness of 200 nm to 500 μm. 
     
     
         44 . The process according to  claim 40 , wherein the first composite is free from silicon (Si). 
     
     
         45 . The process according to  claim 40 , wherein the first composite is free from halogen. 
     
     
         46 . The process according to  claim 45 , wherein the halogen is fluoride, and the first composite has fluoride of 100 ppm or less. 
     
     
         47 . The process according to  claim 45 , wherein the halogen is chlorine, and the first composite has chlorine of 100 ppm or less. 
     
     
         48 . The process according to  claim 40 , wherein the carbon nanotubes are multi-walled carbon nanotubes and/or single-walled carbon nanotubes. 
     
     
         49 . The process according to  claim 40 , wherein the carbon nanotubes are single-walled carbon nanotubes.