Fuel electrodes for solid oxide electrochemical cell, processes for producing the same, and solid oxide electrochemical cells

Abstract

A fuel electrode for a solid oxide electrochemical cell includes: an electrode layer 12 constituted of a mixed phase including an oxide having mixed conductivity and another oxide selected from the group including an aluminum-based oxide and a magnesium-based composite oxide, said another oxide having, supported on a surface part thereof, particles of at least one member selected from nickel, cobalt, and nickel-cobalt alloys; a meshy wiring 21 formed on a surface layer part of the electrode layer and made of a material having higher electronic conductivity than the electrode layer; and a current collector 14 which overlies the electrode layer and is in contact with at least the wiring.

1 . A fuel electrode for a solid oxide electrochemical cell comprising:
 an electrode layer comprising a mixed phase constituted of an oxide having mixed conductivity and another oxide selected from the group consisting of an aluminum-based oxide and a magnesium-based composite oxide, said another oxide having, supported on a surface part thereof, particles of at least one member selected from nickel, cobalt, and nickel-cobalt alloys;   a meshy wiring formed on a surface layer part of the electrode layer and comprising a material having higher electronic conductivity than the electrode layer; and   a current collector which overlies the electrode layer and is in contact with the wiring.   
   
   
       2 . The fuel electrode of  claim 1 , wherein the oxide having mixed conductivity is CeO 2  doped with Sm 2 O 3 , CeO 2  doped with Gd 2 O 3 , or CeO 2  doped with Y 2 O 3 . 
   
   
       3 . The fuel electrode of  claim 1 , wherein the material of the wiring comprises a composite material comprising at least one metal selected from Pt, Au, Ni, Co, and Fe and the oxide having mixed conductivity. 
   
   
       4 . The fuel electrode of  claim 1 , wherein the particles have an average particle diameter of from 5 nm to 200 nm. 
   
   
       5 . A solid oxide electrochemical cell including:
 a solid electrolyte plate having oxygen ion conductivity;   a fuel electrode formed on one side of the solid electrolyte plate, the fuel electrode comprising: an electrode layer comprising a mixed phase constituted of an oxide having mixed conductivity and another oxide selected from the group consisting of an aluminum-based oxide and a magnesium-based composite oxide, said another oxide having, supported on a surface part thereof, particles of at least one member selected from nickel, cobalt, and nickel-cobalt alloys; a meshy wiring formed on a surface layer part of the electrode layer and comprising a material having higher electronic conductivity than the electrode layer; and a current collector which overlies the electrode layer and is in contact with the wiring; and   an air electrode formed on the other side of the solid electrolyte plate, the air electrode comprising a composite oxide represented by Ln 1-x A x BO 3-δ  (wherein Ln is a rare-earth element; A is Sr, Ca, or Ba; and B is at least one of Cr, Mn, Fe, Co, and Ni) or comprising a composite phase constituted of the composite oxide represented by Ln 1-x A x BO 3-δ  and at least one of CeO 2  doped with Sm 2 O 3 , CeO 2  doped with Gd 2 O 3 , and CeO 2  doped with Y 2 O 3 .   
   
   
       6 . The solid oxide electrochemical cell of  claim 5 , wherein the oxide having mixed conductivity is CeO 2  doped with Sm 2 O 3 , CeO 2  doped with Gd 2 O 3 , or CeO 2  doped with Y 2 O 3 . 
   
   
       7 . The solid oxide electrochemical cell of  claim 5 , wherein the material of the wiring comprises a composite material comprising at least one metal selected from Pt, Au, Ni, Co, and Fe and the oxide having mixed conductivity. 
   
   
       8 . The solid oxide electrochemical cell of  claim 5 , wherein the particles have an average particle diameter of from 5 nm to 200 nm. 
   
   
       9 . A process for producing a fuel electrode for a solid oxide electrochemical cell comprising the steps of:
 producing a mixture of oxide particles having mixed conductivity and nickel-aluminum composite oxide particles, cobalt-aluminum composite oxide particles, or composite oxide particles composed of a nickel-aluminum composite oxide and a cobalt-aluminum composite oxide;   superposing a layer of the mixture on a surface of a solid electrolyte and sintering the mixture layer; and   reducing the resultant sinter at a temperature of from 800° C. to 1,000° C.   
   
   
       10 . The process of  claim 9 , wherein the oxide particles having mixed conductivity are mixed with the nickel-aluminum composite oxide particles, cobalt-aluminum composite oxide particles, or composite oxide particles composed of a nickel-aluminum composite oxide and a cobalt-aluminum composite oxide, in a ratio of from 50:50 to 95:5 by weight. 
   
   
       11 . A process for producing a fuel electrode for a solid oxide electrochemical cell comprising the steps of:
 producing a mixture of oxide particles having mixed conductivity and nickel-magnesium composite oxide particles, cobalt-magnesium composite oxide particles, or composite oxide particles composed of a nickel-magnesium composite oxide and a cobalt-magnesium composite oxide;   superposing a layer of the mixture on a surface of a solid electrolyte and sintering the mixture layer; and   reducing the resultant sinter at a temperature of from 800° C. to 1,000° C.   
   
   
       12 . The process of  claim 11 , wherein the oxide particles having mixed conductivity are mixed with the nickel-magnesium composite oxide particles, cobalt-magnesium composite oxide particles, or composite oxide particles composed of a nickel-magnesium composite oxide and a cobalt-magnesium composite oxide, in a ratio of from 50:50 to 95:5 by weight. 
   
   
       13 . The process of  claim 11 , wherein the nickel-magnesium composite oxide particles and the cobalt-magnesium composite oxide particles contain at least one of Sc, Al, and Cr, the content of these elements being from 0.01% by mole to 1.0% by mole based on the magnesium-based composite oxides.