Method and System for Purifying Liquified Gases

Abstract

A method system for providing a purified liquified gas including a vessel containing adsorbent submerged within a liquified gas and an impurity contained inside a storage tank wherein the liquified gas is purified by the adsorbent.

1 . A method for providing a purified liquified gas, comprising the steps of:
 providing at least one vessel containing adsorbent submerged within a liquified gas and at least one impurity that are contained inside a storage tank;   allowing the liquified gas to flow into the at least one vessel containing adsorbent thereby purifying the liquified gas by preferentially adsorbing the at least one impurity on the adsorbent in comparison to the liquified gas; and   allowing the purified liquified gas to flow out of the at least one vessel and out of the storage tank and into a conduit for directing the purified liquified gas to another storage tank, a point of use or a vaporizer.   
   
   
       2 . The method of  claim 1 , wherein the liquified gas is liquid Nitrogen. 
   
   
       3 . The method of  claim 1 , wherein the liquified gas is liquid Oxygen. 
   
   
       4 . The method of  claim 1 , wherein the liquified gas is liquid Helium. 
   
   
       5 . The method of  claim 1 , wherein the liquified gas is liquid Argon. 
   
   
       6 . The method of  claim 1 , wherein the liquified gas is liquid Hydrogen. 
   
   
       7 . The method of  claim 1 , wherein the liquified gas is liquid Carbon Dioxide. 
   
   
       8 . The method of  claim 1 , wherein the at least one vessel containing adsorbent comprises first and second vessels containing adsorbent, said method comprising the further steps of:
 monitoring a concentration of the at least one impurity of purified liquified gas exiting the first vessel;   discontinuing the flow of liquified gas into the first vessel; and   regenerating the adsorbent contained in the first vessel.   
   
   
       9 . The method of  claim 1 , further comprising the step of regenerating the adsorbent contained in the at least one vessel by purging it with an inert gas and allowing the purge gas to be vented from the at least one vessel and storage tank. 
   
   
       10 . The method of  claim 1 , further comprising the step of regenerating the adsorbent contained in the at least one vessel by allowing a temperature of the at least one vessel to rise thereby desorbing the at least one impurity and allowing the at least one impurity to be vented from the at least one vessel and storage tank. 
   
   
       11 . The method of  claim 10 , wherein the temperature of the at least one vessel is allowed to rise by heating the at least one vessel with an electric heater associated with the vessel. 
   
   
       12 . The method of  claim 10 , wherein the temperature of the at least one vessel is allowed to rise by purging the at least one vessel with a heated purge gas. 
   
   
       13 . The method of  claim 1 , comprising the steps of:
 allowing the storage tank to empty itself of liquified gas and be vented thereby raising a temperature of the at least one vessel; and   venting the at least one vessel thereby desorbing the impurity.   
   
   
       14 . The method of  claim 9 , wherein the purge gas is the same as the purified liquified gas. 
   
   
       15 . The method of  claim 9 , wherein the liquified gas is liquid Helium and the purge gas is Nitrogen or Argon. 
   
   
       16 . The method of  claim 10 , wherein the temperature of the at least one vessel is allowed to rise by passing a heated heat exchange fluid through heat exchangers located inside the at least one vessel. 
   
   
       17 . The method of  claim 1 , further comprising the steps of:
 allowing the storage tank to empty itself of liquified gas and be vented thereby raising a temperature of the at least one vessel;   purging the at least one vessel with a purge gas; and   allowing the purge gas to be vented from the at least one vessel.   
   
   
       18 . The method of  claim 1 , further comprising the step of allowing the liquified gas to flow out of the storage tank and back into the storage tank before said step of allowing the liquified gas to flow into the at least one vessel containing adsorbent. 
   
   
       19 . A method for providing a purified liquified gas, comprising the steps of:
 providing first and second vessels each containing an adsorbent, each of the first and second vessels being submerged within a liquified gas and at least one impurity that are contained inside a storage tank;   allowing the liquified gas to flow out of the storage tank, back into the storage tank and into the first vessel thereby purifying the liquified gas by preferentially adsorbing the at least one impurity on the adsorbent in comparison to the liquified gas;   allowing the purified liquified gas to flow out of the first vessel and out of the storage tank and into a conduit for directing the purified liquified gas to another storage tank, a point of use or a vaporizer; and   regenerating the adsorbent contained in the second vessel thereby desorbing at least some of the at least one impurity, wherein said step of regenerating is performed concurrently with said step of allowing the liquified gas to flow out of the storage tank.   
   
   
       20 . A system for providing a purified liquified gas, comprising:
 a storage tank containing a liquified gas and at least one impurity;   at least one vessel containing adsorbent submerged within the liquified gas and the at least one impurity, the adsorbent having the property of preferentially adsorbing the at least one impurity in comparison to the liquified gas; and   a conduit in fluid communication with said at least one vessel configured and adapted to direct liquified gas purified by said at least one vessel to a point of use, a different storage tank, or a vaporizer.   
   
   
       21 . The system of  claim 20 , wherein the liquified gas is liquid Nitrogen. 
   
   
       22 . The system of  claim 20 , wherein the liquified gas is liquid Oxygen. 
   
   
       23 . The system of  claim 20 , wherein the liquified gas is liquid Helium. 
   
   
       24 . The system of  claim 20 , wherein the liquified gas is liquid Hydrogen. 
   
   
       25 . The system of  claim 20 , wherein the liquified gas is liquid Carbon Dioxide. 
   
   
       26 . The system of  claim 20 , further comprising:
 a source of purge gas; and   a conduit in fluid communication between the source of purge gas and the at least one vessel.   
   
   
       27 . The system of  claim 20 , wherein the at least one vessel containing adsorbent comprises first and second vessels each containing adsorbent. 
   
   
       28 . The system of  claim 20 , further comprising:
 a source of purge gas; and   a conduit in fluid communication between the source of purge gas and the at least one vessel.