US2008253919A1PendingUtilityA1

Powder-Metallurgically Produced, Wear-Resistant Material

Assignee: KOPPERN ENTWICKLUNGS GMBH & COPriority: Apr 29, 2005Filed: May 2, 2006Published: Oct 16, 2008
Est. expiryApr 29, 2025(expired)· nominal 20-yr term from priority
C22C 33/0285C22C 38/46C22C 38/56Y10T428/12C22C 38/001C22C 38/34C22C 38/50C22C 38/58C22C 38/02C22C 33/0257C22C 38/52B22F 2998/10B22F 2999/00C22C 30/00C22C 38/44C22C 38/48
45
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Claims

Abstract

A wear-resistant material comprising an alloy that contains: 1.5-5.5 wt. % carbon, 0.1-2.0 wt. % silicon, max. 2.0 wt. % manganese, 3.5-30.0 wt. % chromium, 0.3-10 wt. % molybdenum, 0-10 wt. % tungsten, 0.1-30 wt. % vanadium, 0-12 wt. % niobium, 0.1-12 wt. % titanium and 1.3-3.5 wt. % nickel, the remainder being comprised of iron and production-related impurities, whereby the carbon content fulfils the following condition: CAlloy [ w %]= S 1+ S 2+ S 3 where S1=(Nb+2(Ti+V−0.9))/a, S2=(Mo+W/2+Cr−b)/5, S3=c+(TH−900)·0.0025, where 7<a<9, 6<b<8, 0.3<c<0.5 and 900° C.<TH<1,220° C. Also. method for producing the wear-resistant material and to uses of the material.

Claims

exact text as granted — not AI-modified
1 - 32 . (canceled) 
     
     
         33 . Wear-resistant, powder-metallurgically produced material comprising an alloy that contains: 
       
         
           
                 
                 
                 
                 
               
                     
                     
                 
                     
                   1.5-5.5 
                   wt. % 
                   carbon 
                 
                     
                   0.1-2.0 
                   wt. % 
                   silicon 
                 
                     
                   max. 2.0 
                   wt. % 
                   manganese 
                 
                     
                   3.5-30.0 
                   wt. % 
                   chromium 
                 
                     
                   0.3-10 
                   wt. % 
                   molybdenum 
                 
                     
                   0-10 
                   wt. % 
                   tungsten 
                 
                     
                   0.1-30 
                   wt. % 
                   vanadium 
                 
                     
                   0-12 
                   wt. % 
                   niobium 
                 
                     
                   0.1-12 
                   wt. % 
                   titanium 
                 
                     
                   1.3-3.5 
                   wt. % 
                   nickel 
                 
                     
                   1-6 
                   wt. % 
                   cobalt 
                 
                     
                   0.3-3.5 
                   wt. % 
                   nitrogen 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
       
       with the remainder being comprised of iron and production-related impurities, wherein the carbon content fulfils the following condition:
   CAlloy [ w  %]= S 1 +S 2 +S 3 
   where: 
     S 1=(Nb+2(Ti+V−0.9))/ a    
     S 2=(Mo+W/2+Cr− b )/5 
     S 3 =c +( TH− 900)·0.0025 
   wherein 
   7<a<9 
   6<b<8 
   0.3<c<0.5 
   900° C.< TH< 1,220° C. 
 
     
     
         34 . Wear-resistant material according to claim  32 , wherein the content of vanadium is less than 11.5 wt. %. 
     
     
         35 . Wear-resistant material according to claim  32  wherein the alloy comprises: 
       
         
           
                 
                 
                 
               
                     
                 
                   2.0-2.5 
                   wt. % 
                   carbon 
                 
                   max. 1.0 
                   wt. % 
                   silicon 
                 
                   max. 0.6 
                   wt. % 
                   manganese 
                 
                   12.0-14.0 
                   wt. % 
                   chromium 
                 
                   1.0-2.0 
                   wt. % 
                   molybdenum 
                 
                   1.1-4.2 
                   wt. % 
                   vanadium 
                 
                   2.0-3.5 
                   wt. % 
                   nickel 
                 
                   1.0-6.0 
                   wt. % 
                   cobalt 
                 
                   0.3-3.5 
                   wt. % 
                   nitrogen. 
                 
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
               
            
           
         
       
     
     
         36 . Wear-resistant material according to claim  32 , wherein the nickel content is between 1.5 and 3.0 wt. %. 
     
     
         37 . Wear-resistant material according to claim  32 , wherein the nickel content is between 1.3 and 2.0 wt. %. 
     
     
         38 . Wear-resistant material according to claim  32 , wherein the nickel content is between 2.0 and 3.5 wt. %. 
     
     
         39 . Wear-resistant material according to claim  32 , wherein the alloy additionally has 1-6 wt. % Co.
   CAlloy [ w  %]= S 1 +S 2 K+S 3 is fulfilled, wherein       S 2 K =(Mo+W/2+Cr− b− 12)/5 with 6 <b <8 and Cr>12.   
     
     
         40 . Method for producing a wear-resistant material according to claim  32 , wherein a melt is produced, and then the melt is further processed by means of one of the following steps:
 Atomization of the melt into a powder;   Spray compaction of the melt; and   Casting the melt into a semi-finished product, and processing the semi-finished product for producing power chips.   
     
     
         41 . Method according to  claim 39 , wherein the powder is compacted into one of a semi-finished product or end product. 
     
     
         42 . Method according to  claim 40 , wherein the compacting is selected from the group comprising: cold isostatic pressing, uniaxial pressing, extrusion, powder forging, hot isostatic pressing, diffusion alloying, and sintering. 
     
     
         43 . Method according to  claim 39 , wherein the powder is further processed by means of thermal injection. 
     
     
         44 . Method according to  claim 40 , wherein one of a semi-finished product or an end product is heated to the hardening temperature and subsequently one of quenched or cooled. 
     
     
         45 . Method according to  claim 43 , wherein quenching is selected from the group comprising: quenching in an oil bath, salt bath or polymer bath, quenching in a fluidized bed or drizzle, and low and high pressure gas quenching. 
     
     
         46 . Method according to  claim 43 , wherein one of a semi-finished product or end product is cooled from the hardening temperature by one of the following steps: cooling in slightly moving air, cooling in static air, oven cooling with a standard atmosphere or inert gas, and cooling in an HIP system. 
     
     
         47 . Method according to  claim 43 , wherein the cooling is continuous and is interrupted by isothermal maintenance. 
     
     
         48 . Method according to  claim 43 , wherein after the cooling from the hardening temperature, performing the step of tempering in the temperature range from 150-750° C. one or more times. 
     
     
         49 . The method of production of one of solid or hollow rolls, solid or segmented rings which are arranged on solid or hollow roll bodies, and thick-walled or compact components, comprising forming the one of solid or hallow rolls, solid or segmented rings, and thick-walled or compact components from the wear-resistant materials of claim  32 . 
     
     
         50 . The method of  claim 48  wherein the solid or segmented rings are arranged on one of solid or hollow roll bodies by being shrunk on. 
     
     
         51 . Powder for the production of a wear-resistant material, comprising: 
       
         
           
                 
                 
                 
               
                     
                 
                   1.5-5.5 
                   wt. % 
                   carbon 
                 
                   0.1-2.0 
                   wt. % 
                   silicon 
                 
                   max. 2.0 
                   wt. % 
                   manganese 
                 
                   3.5-30.0 
                   wt. % 
                   chromium 
                 
                   0.3-10 
                   wt. % 
                   molybdenum 
                 
                   0-10 
                   wt. % 
                   tungsten 
                 
                   0.1-30 
                   wt. % 
                   vanadium 
                 
                   0-12 
                   wt. % 
                   niobium 
                 
                   0.1-12 
                   wt. % 
                   titanium 
                 
                   1.3-3.5 
                   wt. % 
                   nickel 
                 
                   1-6 
                   wt. % 
                   cobalt 
                 
                   0.3-3.5 
                   wt. % 
                   nitrogen 
                 
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
       
       with the remainder being comprised of iron and production-related impurities, wherein the carbon content fulfils the following condition:
   CAlloy [ w  %]= S 1 +S 2 +S 3 
   where: 
     S 1=(Nb+2(Ti+V−0.9))/ a    
     S 2=(Mo+W/2+Cr− b )/5 
     S 3= c +( TH− 900)·0.0025 
   wherein 
   7<a<9 
   6<b<8 
   0.3<c<0.5 
   900° C.< TH< 1,220° C. 
 
     
     
         52 . The method of production of a semi-finished product, comprising forming a semi-finished product from the powder according to  claim 50 . 
     
     
         53 . The method according to  claim 51 , where the semi-finished product is produced by spray compaction. 
     
     
         54 . The method of production of layer element of composite components, comprising forming the powder according to  claim 50 , in one of its powder form or as a semi-finished product, into a layer element of composite components. 
     
     
         55 . The method of production of hard material metal matrix composite elements, comprising forming the power according to  claim 50  into a matrix powder for hard material metal matrix composite elements. 
     
     
         56 . The wear-resistant material according to  claim 33 , wherein the content of the vanadium is less than 9.5 wt. %. 
     
     
         57 . The wear-resistant material according to  claim 33 , wherein the content of the vanadium is less than 6.0 wt. %.

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