US2008121320A1PendingUtilityA1

Copper alloy and producing method therefor

Assignee: NIPPON MINING COPriority: Nov 29, 2002Filed: Jan 29, 2008Published: May 29, 2008
Est. expiryNov 29, 2022(expired)· nominal 20-yr term from priority
C22C 9/00C22F 1/08
60
PatentIndex Score
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Cited by
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Claims

Abstract

Superior bendability in a copper alloy and further strength improvement ensures characteristics which are sufficiently superior in view of essential qualities of strength of titanium-copper. 2.0 to 4.0 mass % of Ti, 0.01 to 0.50 mass % of one or more than one kind of element from among Fe, Co, Ni, Cr, V, Zr, B, and P as the third element group are contained, and not less than 50% of the total content of these elements is made to exist as second-phase particles.

Claims

exact text as granted — not AI-modified
1 . A copper alloy comprising:
 2.0 to 4.0 mass % of Ti; and   0.01 to 0.50 mass % of at least one element selected from Fe, Co, Ni, Cr, V, Zr, B, and P as an additional element; and   second-phase particles represented by Cu-Ti-X system particles, wherein X is selected from the group consisting of Fe, Co, Ni, Cr, V, Zr, B, and P;   wherein not less than 50% of the total content of the additional element exists as the second-phase particle.   
     
     
         2 . A copper alloy comprising:
 2.0 to 4.0 mass % of Ti;   0.01 to 0.50 mass % of at least one element selected from Fe, Co, Ni, Cr, V, Zr, B, and P as an additional element; and   second-phase particles represented by Cu-Ti-X system particles, wherein X is selected from the group consisting of Fe, Co, Ni, Cr, V, Zr, B, and P;   wherein the second-phase particles have not less than 0.01 μm 2  area observed by a cross section speculum, and the rate of the number of second-phase particles in which the content of the additional element within the second-phase particles is not less than 10 times the content of the additional element within the alloy is not less than 70% of the total number of the second-phase particles.   
     
     
         3 . A copper alloy comprising:
 2.0 to 4.0 mass % of Ti;   0.01 to 0.50 mass % of at least one element selected from Fe, Co, Ni, Cr, V, Zr, B, and P as an additional element; and   a second-phase particle represented by Cu-Ti-X system particles, wherein X is selected from the group consisting of Fe, Co, Ni, Cr, V, Zr, B, and P;   wherein the second-phase particle has not less than 0.01 μm 2  area observed by a cross section speculum, and the second-phase particle has an area percentage Af of not more than 1.0%.   
     
     
         4 . A copper alloy comprising:
 2.0 to 4.0 mass % of Ti;   0.01 to 0.50 mass % of at least one element selected from Fe, Co, Ni, Cr, V, Zr, B, and P as an additional element;   second-phase particles represented by Cu-Ti-X system particles, wherein X is selected from the group consisting of Fe, Co, Ni, Cr, V, Zr, B, and P, and wherein the second-phase particles have not less than 0.01 μm 2  area observed by a cross section speculum; and   an equable dispersion degree E defined by the following equation   
       
         
           
             
               E 
               = 
               
                 
                   
                     
                       1 
                       n 
                     
                      
                     
                       
                         ∑ 
                         i 
                         n 
                       
                        
                       
                         
                           ( 
                           
                             
                               d 
                               i 
                             
                             - 
                             
                               
                                 
                                   A 
                                   0 
                                 
                                 / 
                                 
                                   N 
                                   A 
                                 
                               
                             
                           
                           ) 
                         
                         2 
                       
                     
                   
                 
                 
                   
                     
                       A 
                       0 
                     
                     
                       N 
                       A 
                     
                   
                 
               
             
           
         
       
       wherein d i  is the distance from an i-th second-phase particle to a nearest second-phase particle, A 0  is the measured visual field area, and N A  is the number of the second-phase particles confirmed within the measured visual field area, wherein the equable dispersion degree E is not more than 0.8. 
     
     
         5 . A copper alloy comprising:
 2.0 to 4.0 mass % of Ti;   0.01 to 0.50 mass % of at least one element selected from Fe, Co, Ni, Cr, V, Zr, B, and P as an additional element;   an area percentage Af of second-phase particles represented by Cu-Ti-X system particles, wherein X is selected from the group consisting of Fe, Co, Ni, Cr, V, Zr, B, and P, and wherein the second-phase particles have not less than 0.01 μm 2  area observed by a cross section speculum, and the area percentage Af is not more than 1.0%;   the second-phase particles with not less than 0.01μm 2  area observed by the cross section speculum; and   an equable dispersion degree E defined by the following equation   
       
         
           
             
               E 
               = 
               
                 
                   
                     
                       1 
                       n 
                     
                      
                     
                       
                         ∑ 
                         i 
                         n 
                       
                        
                       
                         
                           ( 
                           
                             
                               d 
                               i 
                             
                             - 
                             
                               
                                 
                                   A 
                                   0 
                                 
                                 / 
                                 
                                   N 
                                   A 
                                 
                               
                             
                           
                           ) 
                         
                         2 
                       
                     
                   
                 
                 
                   
                     
                       A 
                       0 
                     
                     
                       N 
                       A 
                     
                   
                 
               
             
           
         
       
       wherein d i  is the distance from an i-th second-phase particle to a nearest second-phase particle, A 0  is the measured visual field area, and N A  is the number of the second-phase particles confirmed within the measured visual field area, wherein the equable dispersion degree E is not more than 0.8. 
     
     
         6 . The copper alloy according to  claim 1 , wherein the content of the Ti is 2.5 to 3.5 mass %. 
     
     
         7 . A producing method for the copper alloy of  claim 1  comprising the steps of:
 producing an ingot in which 0.01 to 0.50 mass % of at least one element selected from Fe, Co, Ni, Cr, V, Zr, B, and P is added to Cu, and 2.0 to 4.0 mass % of Ti is added;   solution treating for heating the ingot up to ultimate temperature T° C., the ingot heated to temperature exceeding 600° C. at a heating rate of not less than 20° C./sec, and the ingot is then held for not less than 10 sec within a temperature range of T−100° C. to T° C., resulting in a supersaturated solid solution;   cold rolling by applying cold rolling with 5 to 50% of degree of processing from conditions of the supersaturated solid solution; and   aging treating for applying a thermal treatment to the rolled material at 350 to 450° C.

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