US2008040970A1PendingUtilityA1

Systems for producing biodiesel and processes for using the same

Assignee: DAVANZO THOMAS ANTHONYPriority: Mar 30, 2006Filed: Mar 29, 2007Published: Feb 21, 2008
Est. expiryMar 30, 2026(expired)· nominal 20-yr term from priority
Y02E50/10C10L 1/026
29
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Claims

Abstract

The present invention relates to systems for producing biodiesel, including a batch-continuous flow system, and to processes using the system.

Claims

exact text as granted — not AI-modified
1 ) A system for producing a biodiesel from at least one batch load of feedstock, the system having at least one batch reactor, the batch reactor comprising at least one agitator substantially disposed inside the batch reactor, at least one baffle disposed inside the batch reactor, and at least one pump and at least one mixer disposed outside the batch reactor. 
   
   
       2 ) The system of  claim 1 , further comprising a post-reactor network, the post-reactor network comprising at least one co-product storage vessel and at least one biodiesel storage vessel, wherein the batch reactor is in fluid communication with the post-reactor network. 
   
   
       3 ) The system of  claim 1  further comprising at least one reagent storage vessel, which is in fluid communication with the batch reactor. 
   
   
       4 ) The system of  claim 1  further comprising at least one reagent mixing vessel, which is in fluid communication with the batch reactor. 
   
   
       5 ) The system of  claim 2 , wherein the post-reactor network further comprises at least one separator holding vessel, wherein the separator holding vessel is in fluid communication with the batch reactor, the at least one co-product storage vessel or a combination thereof. 
   
   
       6 ) The system as in  claim 2 , wherein the post-reactor network further comprises at least one separator, wherein the at least one separator is in fluid communication with the batch reactor, the at least one separator holding vessel, the at least one co-product storage vessel or a combination thereof. 
   
   
       7 ) The system of  claim 6 , wherein the at least one separator is a liquid phase separator or a centrifuge. 
   
   
       8 ) The system of  claim 2 , wherein the post-reactor network further comprises at least one polishing vessel, wherein the at least one polishing vessel is in fluid communication with the batch reactor, the at least one separator holding vessel, the at least one separator, the at least one co-product storage vessel, the at least one biodiesel storage vessel, or combination thereof. 
   
   
       9 ) The system of  claim 8 , wherein the at least one polishing vessel comprises a plurality of wash heads. 
   
   
       10 ) The system of  claim 9 , wherein the plurality of wash heads comprises from about 1 to about 20 wash heads. 
   
   
       11 ) The system of  claim 9 , wherein the plurality of wash heads is disposed in the roof of the polishing vessel, on an internal wall of the polishing vessel, on a pole inside the polishing vessel, on a rod inside the polishing vessel or a combination thereof. 
   
   
       12 ) The system of  claim 2 , wherein the post-reactor network further comprises at least one drying vessel, wherein the at least one drying vessel is in fluid communication with the at least one polishing vessel, the at least one biodiesel storage vessel, at least one reagent storage vessel or combination thereof. 
   
   
       13 ) The system of  claim 12 , wherein the at least one drying vessel comprises a heating element and a vacuum. 
   
   
       14 ) The system of  claim 1 , wherein the system further produces a co-product. 
   
   
       15 ) The system of  claim 1 , wherein the at least one baffle comprises a material selected from the group consisting of steel, carbon steel, stainless steel, chromium plated steel, copper, aluminum, metal alloy, thermally conductive polymer, polyvinyl chloride, expoxy, fluroroplastic, polypropylene, polyimide, polyacetal, polycarbonate, acrylonitrile-butadiene-styrene, polyetheretherketone, polybutylene, polyphenylene oxide, polyphenylene sulfide, liquid crystal polymer, and a combination thereof. 
   
   
       16 ) The system of  claim 1 , wherein the at least one baffle is affixed at an angle of about 90 degrees to an interior wall of the batch reactor. 
   
   
       17 ) The system of  claim 1 , wherein the at least one baffle is heated. 
   
   
       18 ) The system of  claim 17 , wherein the temperature of the heated baffle is from about 50° F. to about 200° F. 
   
   
       19 ) The system of  claim 17 , wherein the baffle comprises piping that is in fluid communication with a heat source. 
   
   
       20 ) The system of  claim 19 , wherein the piping is disposed substantially vertical to the height of the batch reactor. 
   
   
       21 ) The system of  claim 19 , wherein the heat source is steam. 
   
   
       22 ) The system of  claim 1 , wherein the batch reactor comprises from about 2 baffles to about 10 baffles. 
   
   
       23 ) The system of  claim 1 , wherein the at least one baffle comprises a cavity that allows the baffle to be substantially offset from an interior side of the batch reactor. 
   
   
       24 ) The system of  claim 23 , wherein the cavity is formed from two arms of the baffle disposed perpendicular to a main body of the baffle. 
   
   
       25 ) The system of  claim 24 , wherein the baffle further comprises a second cavity, which is disposed in the main body of the baffle. 
   
   
       26 ) The system of  claim 23 , wherein the cavity is formed from a concave nature of the baffle. 
   
   
       27 ) The system of  claim 1 , wherein the pump and the miser reintroduce a portion of reaction mixture into a remaining portion of reaction mixture, thereby providing a substantially homogeneous reaction mixture. 
   
   
       28 ) A process for producing a biodiesel from a feedstock using a batch reactor system having at least one baffle, the process involving the steps of:
 a) feeding the feedstock into the batch reactor system;   b) delivering at least one reagent to the feedstock in the batch reactor system to create a reaction mixture;   c) heating the reaction mixture;   d) mixing the reaction mixture; and   e) rotating the reaction mixture using the at least one baffle,   wherein steps a) to e) are performed for a predetermined time and under predetermined, conditions to produce a biodiesel-containing composition; and   f) separating the biodiesel of the biodiesel-containing composition from a non-biodiesel composition, thereby obtaining a crude biodiesel product; and   g) polishing the crude biodiesel product, thereby obtaining a polished biodiesel product.   
   
   
       29 ) The process of  claim 28 , further comprising the steps of:
 a) mixing the at least one reagent with a second reagent, thereby creating a reagent mixture; and   b) delivering the reagent mixture to the feedstock in the batch reactor, thereby, creating the reaction mixture.   
   
   
       30 ) The process of  claim 28 , further comprising the step of delivering a second reagent to the feedstock in the batch reactor. 
   
   
       31 ) The process of  claim 28 , further comprising the step of transferring the non-biodiesel composition to a co-product storage tank. 
   
   
       32 ) The process of  claim 31 , wherein the co-product comprises glycerin, fatty acids and alcohol. 
   
   
       33 ) The process of  claim 32 , wherein on a compositional basis the glycerin is from about 30% to about 40% v/v of the co-product, the fatty acids are from about 50% to about 60% v/v of the co-product and the alcohol is from about 5% to about 10% v/v of the co-product. 
   
   
       34 ) The process of  claim 32 , wherein on a compositional basis the glycerin is from about 34% to about 38% v/v of the co-product, the fatty acids are from about 55% to about 60% v/v of the co-product and the alcohol is from about 6% to about 7% v/v of the co-product. 
   
   
       35 ) The process of  claim 32 , wherein the co-product comprises a fuel source. 
   
   
       36 ) The process of  claim 35 , wherein the co-product fuel source fuels the batch reactor system. 
   
   
       37 ) The process of  claim 31 , wherein the co-product comprises a fuel extender. 
   
   
       38 ) The process of  claim 31 , further comprising the step of processing the co-product to provide a food grade product, pharmaceutical grad product, a livestock feed grade product or a generally recognized as safe product. 
   
   
       39 ) The process of  claim 37 , further comprising the step of drying the polished biodiesel product to obtain the biodiesel product. 
   
   
       40 ) The process of  claim 39 , wherein the drying step comprises heating the polished biodiesel under vacuum. 
   
   
       41 ) The process of  claim 40 , further comprising the steps of condensing vaporized residual reagent and polishing agent, and transferring condensed residual reagent and polishing agent to a reagent storage vessel. 
   
   
       42 ) The process of  claim 28 , wherein the feedstock comprises an organic oil. 
   
   
       43 ) The process of  claim 28 , wherein the feed stock comprises an animal fat. 
   
   
       44 ) The process of  claim 28 , wherein the feedstock comprises a plant source. 
   
   
       45 ) The process of  claim 28 , wherein the process further produces a co-product. 
   
   
       46 ) The process of  claim 28 , wherein the at least one reagent is an alcohol. 
   
   
       47 ) The process of  claim 28 , wherein the at least one reagent is a catalyst. 
   
   
       48 ) The process of  claim 28 , wherein the polishing step comprises a polishing agent. 
   
   
       49 ) The process of  claim 28 , wherein the predetermined time and the predetermined conditions for processing the feedstock; are selected from the group consisting of: 
     
       
         
               
               
               
               
               
             
                   
               
                   
                   
                   
                 Caustic 
                   
               
                 Temperate Range 
                 Processing Time 
                 Methanol 
                 Soda 
                 Oil 
               
                 (° F.) 
                 (Mins.) 
                 (% v/v) 
                 (lbs.) 
                 (Gals.) 
               
                   
               
                 about 60 to about 70 
                 about 475 to about 500 
                 about 20 
                 about 475 
                 about 8650; 
               
                 about 70 to about 80 
                 about 375 to about 400 
                 about 20 
                 about 475 
                 about 8650; 
               
                 about 80 to about 90 
                 about 275 to about 300 
                 about 20 
                 about 475 
                 about 8650; 
               
                 about 90 to about 100 
                 about 225 to about 250 
                 about 20 
                 about 475 
                 about 8650; 
               
                 about 100 to about 110 
                 about 175 to about 200 
                 about 21 
                 about 500 
                 about 8650; 
               
                 about 110 to about 120 
                 about 120 to about 130 
                 about 22 
                 about 500 
                 about 8650; 
               
                 about 120 to about 130 
                 about 100 to about 110 
                 about 24 
                 about 500 
                 about 8650; 
               
                 about 130 to about 140 
                 about 80 to about 90 
                 about 26 
                 about 525 
                 about 8650; 
               
                 about 140 to about 150 
                 about 60 to about 70 
                 about 27 
                 about 525 
                 about 8650; 
               
                 about 150 to about 160 
                 about 45 to about 50 
                 about 28 
                 about 525 
                 about 8650; and 
               
                 about 160 to about 170 
                 about 35 to about 40 
                 about 29 
                 about 525 
                 about 8650. 
               
                   
               
           
              
              
              
              
              
             
             
              
              
              
              
              
              
              
              
              
              
              
              
             
          
         
       
     
   
   
       50 ) The process of  claim 28 , wherein the predetermined time and the predetermined conditions for processing the feedstock are selected from the group consisting of: 
     
       
         
               
               
               
               
               
             
                   
               
                   
                   
                   
                 Caustic 
                   
               
                 Temperate Range 
                 Processing Time 
                 Methanol 
                 Soda 
                 Oil 
               
                 (° F.) 
                 (Mins.) 
                 (% v/v) 
                 (lbs.) 
                 (Gals.) 
               
                   
               
                 about 60 to about 70 
                 about 475 to about 500 
                 about 20 
                 about 450 
                 about 8650; 
               
                 about 70 to about 80 
                 about 375 to about 400 
                 about 20 
                 about 450 
                 about 8650; 
               
                 about 80 to about 90 
                 about 275 to about 300 
                 about 20 
                 about 450 
                 about 8650; 
               
                 about 90 to about 100 
                 about 225 to about 250 
                 about 20 
                 about 450 
                 about 8650; 
               
                 about 100 to about 110 
                 about 175 to about 200 
                 about 21 
                 about 475 
                 about 8650; 
               
                 about 110 to about 120 
                 about 120 to about 130 
                 about 22 
                 about 475 
                 about 8650; 
               
                 about 120 to about 130 
                 about 100 to about 110 
                 about 24 
                 about 475 
                 about 8650; 
               
                 about 130 to about 140 
                 about 80 to about 90 
                 about 26 
                 about 475 
                 about 8650; 
               
                 about 140 to about 150 
                 about 65 to about 70 
                 about 27 
                 about 500 
                 about 8650; 
               
                 about 150 to about 160 
                 about 45 to about 50 
                 about 28 
                 about 500 
                 about 8650; and 
               
                 about 160 to about 170 
                 about 35 to about 40 
                 about 29 
                 about 500 
                 about 8650. 
               
                   
               
           
              
              
              
              
              
             
             
              
              
              
              
              
              
              
              
              
              
              
              
             
          
         
       
     
   
   
       51 ) The process of  claim 28 , wherein the predetermined time and the predetermined conditions for processing the feedstock are selected from the group consisting of: 
     
       
         
               
               
               
               
               
             
                   
               
                   
                   
                   
                 Caustic 
                   
               
                 Temperate Range 
                 Processing Time 
                 Methanol 
                 Soda 
                 Oil 
               
                 (° F.) 
                 (Mins.) 
                 (% v/v) 
                 (lbs.) 
                 (Gals.) 
               
                   
               
                 about 60 to about 70 
                 about 440 to about 450 
                 about 20 
                 about 300 
                 about 8650; 
               
                 about 70 to about 80 
                 about 350 to about 375 
                 about 20 
                 about 300 
                 about 8650; 
               
                 about 80 to about 90 
                 about 250 to about 275 
                 about 20 
                 about 300 
                 about 8650; 
               
                 about 90 to about 100 
                 about 200 to about 225 
                 about 20 
                 about 300 
                 about 8650; 
               
                 about 100 to about 110 
                 about 150 to about 175 
                 about 21 
                 about 325 
                 about 8650; 
               
                 about 110 to about 120 
                 about 110 to about 120 
                 about 22 
                 about 325 
                 about 8650; 
               
                 about 120 to about 130 
                 about 90 to about 100 
                 about 24 
                 about 325 
                 about 8650; 
               
                 about 130 to about 140 
                 about 70 to about 80 
                 about 25 
                 about 325 
                 about 8650; 
               
                 about 140 to about 50 
                 about 55 to about 65 
                 about 26 
                 about 350 
                 about 8650; 
               
                 about 150 to about 160 
                 about 45 to about 50 
                 about 27 
                 about 350 
                 about 8650; and 
               
                 about 160 to about 170 
                 about 30 to about 35 
                 about 28 
                 about 350 
                 about 8650.

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