Conductive tin oxide sol and process for producing same

Abstract

There is provided a conductive tin oxide sol having a high transparency, and a process for producing the sol, a coating composition by use of the sol and a material coated with the coating composition. The conductive tin oxide sol containing phosphorus-doped conductive tin oxide colloidal particles (A), wherein a sol prepared so as to have the colloidal particles (A) in a concentration of 10 mass % in the sol has a transmittance of 30% or more at a wavelength of 600 nm in an optical path length of 10 mm. The particle diameter of the conductive tin oxide sol by observation with transmission electron microscope is 2 to 25 nm. The molar ratio of the doped phosphorus (P) to the tin oxide (SnO 2 ) in the colloidal particles (A) is 0.005 to 0.2. The conductive tin oxide sol is produced by mixing a phosphorus compound in a tin oxide sol, and then subjecting to a hydrothermal treatment. The coating composition contains the conductive tin oxide sol and a binder. The material having a coating film formed from the coating composition is also provided.

1 . A conductive tin oxide sol containing phosphorus-doped conductive tin oxide colloidal particles (A), wherein a sol prepared so as to have the colloidal particles (A) in a concentration of 10 mass % in the sol has a transmittance of 30% or more at a wavelength of 600 nm in an optical path length of 10 mm. 
     
     
         2 . The conductive tin oxide sol according to  claim 1 , wherein the particle diameter of the conductive tin oxide sol by observation with transmission electron microscope is 2 to 25 nm. 
     
     
         3 . The conductive tin oxide sol according to  claim 1 , wherein the molar ratio of the doped phosphorus (P) to the tin oxide (SnO 2 ) in the colloidal particles (A) is 0.005 to 0.2. 
     
     
         4 . A process for producing the conductive tin oxide sol according to  claim 1 , comprising mixing a phosphorus compound in a tin oxide sol, and then subjecting to a hydrothermal treatment. 
     
     
         5 . The process for producing the conductive tin oxide sol according to  claim 4 , wherein a temperature for the hydrothermal treatment after mixing the phosphorus compound in the tin oxide sol is 100 to 350° C. 
     
     
         6 . The process for producing the conductive tin oxide sol according to  claim 4 , wherein the tin oxide sol is prepared by adding metal tin and hydrogen peroxide in an aqueous solution of an organic acid keeping H 2 O 2 /Sn molar ratio of 2 to 3, and reacting. 
     
     
         7 . The process for producing the conductive tin oxide sol according to  claim 6 , wherein the metal tin and hydrogen peroxide are added and reacted so that tin oxide concentration in the aqueous solution of an organic acid is 40 mass % or less. 
     
     
         8 . The process for producing the conductive tin oxide sol according to  claim 6 , wherein the organic acid is oxalic acid or an organic acid containing oxalic acid as a main component. 
     
     
         9 . The process for producing the conductive tin oxide sol according to  claim 4 , wherein the phosphorus compound is at least one phosphorus compound selected from the group consisting of orthophosphoric acid, sodium dihydrogen phosphate, disodium hydrogen phosphate, trisodium phosphate, ammonium dihydrogen phosphate, diammonium hydrogen phosphate, triammonium phosphate, phosphorous acid, sodium dihydrogen phosphite, disodium hydrogen phosphite, trisodium phosphite, phosphorus trichloride and phosphorus pentachloride. 
     
     
         10 . A coating composition comprising the conductive tin oxide sol according to  claim 1 , and a binder. 
     
     
         11 . The coating composition according to  claim 10 , wherein the binder is at least one selected from the group consisting of an acrylic resin, a polyester resin, an urethane resin, an epoxy resin, a polyvinyl alcohol resin, a melamine resin, gelatin and a gelatin derivative, cellulose and a cellulose derivative, a polyimide resin, a phenol resin, an organic silicon compound, a urea resin, a diallylphthalate resin and a butyral resin. 
     
     
         12 . A material having a coating film formed from the coating composition according to  claim 10 . 
     
     
         13 . The material according to  claim 12 , wherein the material is plastic, rubber, glass, metal, ceramics or paper. 
     
     
         14 . A material having an anti-reflective coating, further providing an anti-reflective coating on the material according to  claim 12 .