Cladding resin composition

Abstract

The invention relates to a cladding resin composition curable by heat, ultraviolet radiation, an electron beam or the like. The composition comprises a polyoxyalkylene polyol phosphate ester (hydroxyl value: 10-2,000 mg KOH/g) and a polymerizable or reactive functional group-containing compound. This composition is highly conductive as it is and, without incorporation of the conventional conductive additives, can be used successfully in the field of coatings and protective films where electric conductivity is a requisite.

1 . A cladding resin composition comprising the reaction product of: 
 a polyoxyalkylene polyol phosphate ester, having a hydroxyl value of 10-2,000 mg KOH/g; and    at least one compound selected from the group consisting of: polyisocyanates, active hydrogen-containing (meth)acrylates, (meth)acrylic acid, and maleic anhydride.    
   
   
       2 . The cladding resin composition according to  claim 1 , wherein said at least one compound and said polyoxyalkylene polyol phosphate ester are in a molar ratio of the former to the latter of 1:1 to 10:1.  
   
   
       3 . The cladding resin composition according to  claim 1 , wherein said active hydrogen-containing (meth)acrylate is a dihydric alcohol mono(meth)acrylate.  
   
   
       4 . The cladding resin composition according to  claim 1 , wherein said active hydrogen-containing (meth)acrylate is at least one member selected from the group consisting of: ethylene glycol mono(meth)acrylate, propylene glycol mono(meth)acrylate, and diethylene glycol mono(meth)acrylate.  
   
   
       5 . A resin composition comprising a polyoxyalkylene polyol phosphate ester, having a hydroxyl value of 10-780 mg KOH/g, and one or more polymerizable or reactive functional group-containing compounds capable of reacting with the phosphate ester and/or with a metal salt derived from said phosphate ester, to produce a cured coating, wherein a molar ratio of said one or more polymerizable or reactive functional group-containing compounds to said polyoxyalkylene polyol phosphate ester is 1:1 to 10:1.  
   
   
       6 . The resin composition according to  claim 5 , wherein said one or more polymerizable or reactive functional group-containing compounds is at least one member selected from the group consisting of active hydrogen-containing (meth)acrylates, (meth)acrylic acid, and maleic anhydride.  
   
   
       7 . The resin composition according to  claim 5 , wherein said metal salt is an alkali metal salt.  
   
   
       8 . The resin composition according to  claim 7 , wherein said alkali metal salt is a sodium, potassium, or lithium salt.  
   
   
       9 . A film or coating comprising the reaction product of: 
 a polyoxyalkylene polyol phosphate ester, having a hydroxyl value of 10-2,000 mg KOH/g; and    at least one compound selected from the group consisting of: polyisocyanates, active hydrogen-containing (meth)acrylates, (meth)acrylic acid, and maleic anhydride, wherein said dry film or coating is substantially free of solid particles.    
   
   
       10 . The film or coating according to  claim 9 , wherein said at least one compound and said polyoxyalkylene polyol phosphate ester are in a molar ratio of the former to the latter of 1:1 to 10:1.  
   
   
       11 . The film or coating according to  claim 9 , wherein said active hydrogen-containing (meth)acrylate is a dihydric alcohol mono(meth)acrylate.  
   
   
       12 . The film or coating according to  claim 9 , wherein said active hydrogen-containing (meth)acrylate is at least one member selected from the group consisting of: ethylene glycol mono(meth)acrylate, propylene glycol mono(meth)acrylate, and diethylene glycol mono(meth)acrylate.  
   
   
       13 . A film or coating comprising a polyoxyalkylene polyol phosphate ester, having a hydroxyl value of 10-780 mg KOH/g, and one or more polymerizable or reactive functional group-containing compounds capable of reacting with the phosphate ester and/or with a metal salt derived from said phosphate ester, to produce a cured coating, wherein a molar ratio of said one or more polymerizable or reactive functional group-containing compounds to said polyoxyalkylene polyol phosphate ester is 1:1 to 10:1, wherein said film or coating is substantially free of solid particles.  
   
   
       14 . The film or coating according to  claim 13 , wherein said one or more polymerizable or reactive functional group-containing compounds is at least one member selected from the group consisting of active hydrogen-containing (meth)acrylates, (meth)acrylic acid, and maleic anhydride.  
   
   
       15 . The film or coating according to  claim 13 , wherein said metal salt is an alkali metal salt.  
   
   
       16 . The film or coating according to  claim 15 , wherein said alkali metal salt is a sodium, potassium, or lithium salt.