US2007158201A1PendingUtilityA1

Electrochemical processing with dynamic process control

Assignee: APPLIED MATERIALS INCPriority: Jan 6, 2006Filed: Jan 6, 2006Published: Jul 12, 2007
Est. expiryJan 6, 2026(expired)· nominal 20-yr term from priority
B23H 5/08C25D 5/18C25D 5/22C25D 21/12
41
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Claims

Abstract

Embodiments of the invention generally provide a method for electrochemically removing material from a substrate. In one embodiment, a method for electrochemically processing a substrate includes determining a process target for a substrate; electrochemically processing the substrate; determining a deviation between expected and actual process indicators while processing, and changing at least one process variable during processing in response to the variation.

Claims

exact text as granted — not AI-modified
1 . A method for processing a substrate comprising: 
 determining a process target for a substrate;    electrochemically processing a surface of the substrate;    determining a deviation between expected and actual process indicators while processing; and    changing at least one process variable during processing in response to the variation.    
   
   
       2 . The method of  claim 1 , wherein determining the process target further comprises: 
 determining a profile for the surface to be processed.    
   
   
       3 . The method of  claim 1 , wherein determining the process target further comprises: 
 determining the thickness of a film disposed on the substrate in a plurality of locations.    
   
   
       4 . The method of  claim 3 , wherein the thickness is determined through a non-destructive measuring technique.  
   
   
       5 . The method of  claim 4 , wherein the non-destructive measuring technique is at least one of eddy current, capacitance sensing or interferometry.  
   
   
       6 . The method of  claim 1 , wherein changing at least one process variable further comprises: 
 adjusting a current driving the electrochemical process.    
   
   
       7 . The method of  claim 1 , wherein electrochemically processing the surface further comprises: 
 pressing the surface of the substrate against a polishing material; and    establishing relative motion between the polishing material and the surface of the substrate.    
   
   
       8 . The method of  claim 1 , wherein electrochemically processing the surface of the substrate further comprises: 
 basing the surface of the substrate relative to an electrode spaced apart from the surface of the substrate; and    providing an electrolyte in contact with the electrode and the surface of the substrate.    
   
   
       9 . The method of  claim 1 , wherein electrochemically processing the surface of the substrate further comprises: 
 pressing the surface of the substrate against a conductive polymer surface in the presence of an electrolyte;    applying an electrical bias to the surface of the substrate through the conductive polymer surface; and    providing relative motion between the surface of the substrate and the conductive polymer surface.    
   
   
       10 . The method of  claim 1 , wherein electrochemically processing the surface of the substrate further comprises: 
 pressing the surface of the substrate against a dielectric polymer surface supported by a platen;    establishing a conductive path between the surface of the substrate and an electrode supported by the platen through an electrolyte;    applying an electrical bias to the surface of the substrate through an electrical contact extending from the platen; and    providing relative motion between the surface of the substrate and the dielectric polymer surface.    
   
   
       11 . The method of  claim 1 , wherein the step of determining further comprises: 
 comparing an expected current with a measured current.    
   
   
       12 . The method of  claim 1 , wherein the step of determining further comprises: 
 comparing an expected charge with a measured charge removed from the substrate.    
   
   
       13 . The method of  claim 1 , wherein the step of determining further comprises: 
 comparing an expected thickness with the actual thickness during the electrochemical process.    
   
   
       14 . The method of  claim 1 , wherein changing at least one process variable further comprises: 
 adjusting a voltage driving the electrochemical process.    
   
   
       15 . The method of  claim 1 , wherein the step of changing at least one process variable further comprises: 
 adjusting a process variable in a first process zone independently from a process variable for a second process zone so that an electrochemical removal rate is independently controlled in each process zone.    
   
   
       16 . The method of  claim 1 , wherein a voltage V I  driving the electrochemical process is changed in response to a deviation D i , wherein V i  is a bias voltage applied in a respective process zone of a processing system wherein the electrochemical process is performed, D i  is a deviation between expected and actual process indicators in a respective process zone of the processing system, and i is the number of laterally arranged process zones in the processing system.  
   
   
       17 . The method of  claim 16 , wherein V I  may be expressed as  
     
       
         
           
             
               
                 V 
                 i 
               
               ⁡ 
               
                 ( 
                 
                   t 
                   + 
                   
                     Δ 
                     ⁢ 
                     
                         
                     
                     ⁢ 
                     t 
                   
                 
                 ) 
               
             
             = 
             
               
                 
                   V 
                   i 
                 
                 ⁡ 
                 
                   ( 
                   t 
                   ) 
                 
               
               + 
               
                 P 
                 × 
                 
                   
                     Ie 
                     i 
                   
                   ⁡ 
                   
                     ( 
                     t 
                     ) 
                   
                 
               
               + 
               
                 I 
                 × 
                 
                   
                     Ce 
                     i 
                   
                   ⁡ 
                   
                     ( 
                     t 
                     ) 
                   
                 
                 ⁢ 
                 D 
                 × 
                 
                   
                     ⅆ 
                     
                       ( 
                       
                         
                           Ie 
                           
                             ( 
                             i 
                             ) 
                           
                         
                         ⁡ 
                         
                           ( 
                           t 
                           ) 
                         
                       
                       ) 
                     
                   
                   
                     ⅆ 
                     t 
                   
                 
               
             
           
         
       
     
     where, 
 Ie i  is an error in current for zone i;  
 Ce i  is error in charge for zone I; and  
 P, I and D are constants.  
 
   
   
       18 . The method of  claim 1  further comprising: 
 determining a change in a projected processing time during processing; and    adjusting the electrochemical process to compensate for the determined change.    
   
   
       19 . The method of  claim 18 , wherein adjusting the electrochemical process to compensate for the determined change further comprises: 
 maintaining an offset in arrival at an endpoint between a fastest and slowest processing zone within a predetermined period.    
   
   
       20 . The method of  claim 1  further comprising: 
 setting process parameters based an incoming thickness profile of a film to be processed on the substrate to yield the process target.    
   
   
       21 . A method for processing a substrate comprising: 
 determining a target profile and expected process indicators for achieving the target profile;    contacting a conductive surface of a substrate to a processing pad assembly, the pad assembly comprising an electrode having a plurality of zones;    establishing a conductive path between the conductive surface of the substrate and at least one zone of the electrode through an electrolyte;    independently controlling an electrical bias applied between the conductive surface of the substrate and each zone of the electrode;    determining a deviation between expected and actual process indicators while processing; and    changing at least one process variable during processing in response to the variation.    
   
   
       22 . The method of  claim 21  further comprising: 
 determining a change in a projected processing time during processing; and    adjusting the electrochemical process to compensate for the determined change.    
   
   
       23 . The method of  claim 22 , wherein adjusting the electrochemical process to compensate for the determined change further comprises: 
 maintaining an offset in arrival at an endpoint between a fastest and slowest processing zone within a predetermined period.    
   
   
       24 . A method for processing a substrate comprising: 
 determining a target profile and expected process indicators for achieving the target profile;    contacting a conductive surface of a substrate to a processing pad assembly, the pad assembly comprising an electrode having a plurality of zones;    establishing a conductive path between the conductive surface of the substrate and at least one zone of the electrode through an electrolyte;    independently controlling an electrical bias applied between the conductive surface of the substrate and each zone of the electrode;    determining a change in projected processing time required to arrive at the target profile in at least one zone; and    adjusting the electrochemical process to compensate for the determined change.    
   
   
       25 . The method of  claim 24 , wherein adjusting the electrochemical process to compensate for the determined change further comprises: 
 maintaining an offset in arrival at an endpoint between a fastest and slowest processing zone within a predetermined period.

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