US2007098646A1PendingUtilityA1

Aerosol propellants comprising unsaturated fluorocarbons

64
Individually held — no corporate assignee on recordPriority: Nov 1, 2005Filed: Oct 30, 2006Published: May 3, 2007
Est. expiryNov 1, 2025(expired)· nominal 20-yr term from priority
Inventors:Mario Joseph NappaJoseph Anthony CreazzoAllen Capron SievertEkaterina N. Swearingen
A61K 9/124C09K 3/30
64
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Claims

Abstract

Disclosed herein are propellants comprising fluorocarbons and/or hydrofluorocarbons. Also disclosed are sprayable compositions comprising the propellants.

Claims

exact text as granted — not AI-modified
1 . A propellant comprising at least one fluorocarbon or hydrofluorocarbon selected from the group consisting of: 
 (i) a hydrofluorocarbon having the formula E- or Z-R° CH═CHR 2 , wherein R 1  and R 2  are, independently, C 1  to C 6  perfluoroalkyl groups; and    (iii) a fluorocarbon or hydrofluorocarbon selected from the group consisting of CF 3 CF═CHF, CF 3 CH═CF 2 , CHF 2 CF═CF 2 , CHF 2 CH═CHF, CF 3 CF═CH 2 , CF 3 CH═CHF, CH 2 FCF═CF 2 , CHF 2 CH═CF 2 , CHF 2 CF═CHF, CHF 2 CF═CH 2 , CF 3 CH═CH 2 , CH 3 CF═CF 2 , CH 2 FCHCF 2 , CH 2 FCF═CHF, CHF 2 CH═CHF, CF 3 CF═CFCF 3 , CF3CF 2 CF═CF 2 , CF 3 CF═CHCF 3 , CF 3 CF 2 CF═CH 2 , CF 3 CH═CHCF 3 , CF 3 CF 2 CH═CH 2 , CF 2 ═CHCF 2 CF 3 , CF 2 ═CFCHFCF 3 , CF 2 ═CFCF 2 CHF 2 , CHF 2 CH═CHCF 3 , (CF 3 ) 2 C═CHCF 3 , CF 3 CF═CHCF 2 CF 3 , CF 3 CH═CFCF 2 CF 3 , (CF 3 ) 2 CFCH═CH 2 , CF 3 CF 2 CF 2 CH═CH 2 , CF 3 (CF 2 ) 3 CF═CF 2 , CF 3 CF 2 CF═CFCF 2 CF 3 , (C F 3 ) 2 C═C(CF 3 ) 2 , (CF 3 ) 2 CFCF═CHCF 3 , CF 2 ═CFCF 2 CH 2 F, CF 2 ═CFCHFCHF 2 , CH 2 ═C(CF 3 ) 2 , CH 2 CF 2 CF═CF 2 , CH 2 FCF═CFCHF 2 , CH 2 FCF 2 CF═CF 2 , CF 2 ═C(CF 3 )(CH 3 ), CH 2 ═C(CHF 2 )(CF 3 ), CH 2 ═CHCF 2 CHF 2 , CF 2 ═C(CHF 2 )(CH 3 ), CHF═C(CF 3 )(CH 3 ), CH 2 ═C(CHF 2 ) 2 , CF 3 CF═CFCH 3 , CH 3 CF═CHCF 3 , CF 2 ═CFCF 2 CF 2 CF 3 , CHF═CFCF 2 CF 2 CF 3 , CF 2 ═CHCF 2 CF 2 CF 3 , CF 2 ═CFCF 2 CF 2 CHF 2 , CHF 2 CF═CFCF 2 CF 3 , CF 3 CF═CFCF 2 CHF 2 , CF 3 CF═CFCHFCF 3 , CHF═CFCF(CF 3 ) 2 , CF 2 ═CFCH(CF 3 ) 2 , CF 3 CH═C(CF 3 ) 2 , CF 2 ═CHCF(CF 3 ) 2 , CH 2 ═CFCF 2 CF 2 CF 3 , CHF═CFCF 2 CF 2 CHF 2 , CH 2 ═C(CF 3 )CF 2 CF 3 , CF 2 ═CHCH(CF 3 ) 2 , CHF═CHCF(CF 3 ) 2 , CF 2 ═C(CF 3 )CH 2 CF 3 , CH 2 ═CFCF 2 CF 2 CHF 2 , CF 2 ═CHCF 2 CH 2 CF 3 , CF 3 CF═C(CF 3 )(CH 3 ), CH 2 ═CFCH(CF 3 ) 2 , CHF═CHCH(CF 3 ) 2 , CH 2 FCH═C(CF 3 ) 2 , CH 3 CF═C(CF 3 ) 2 , CH 2 ═CHCF 2 CHFCF 3 , CH 2 C(CF 3 )CH 2 CF 3 , (CF 3 ) 2 C═CHC 2 F 5 , (CF3) 2 CFCF═CHCF 3 , CH 2 ═CHC(CF 3 ) 3 , (CF 3 ) 2 C═C(CH 3 )(CF 3 ), CH 2 ═CFCF 2 CH(CF 3 ) 2 , CF 3 CF═C(CH 3 )CF 2 CF 3 , CF 3 CH═CHCH(CF 3 ) 2 , CH 2 ═CHCF 2 CF 2 CF 2 CHF 2 , (CF 3 ) 2 C═CHCF 2 CH 3 , CH 2 ═C(CF 3 )CH 2 C 2 F 5 , CH 2 ═CHCH 2 CF 2 C 2 F 5 , CH 2 ═CHCH 2 CF 2 C 2 F 5 , CF 3 CF 2 CF═CFC 2 H 5 , CH 2 ═CHCH 2 CF(CF 3 ) 2 , CF 3 CF═CHCH(CF 3 )(CH 3 ), (CF 3 ) 2 C═CFC 2 H5, cyclo-CF 2 CF 2 CF 2 CH═CH—, cyclo-CF 2 CF 2 CH═CH—, CF 3 CF 2 CF 2 C(CH 3 )=CH 2 , CF 3 CF 2 CF 2 CH═CHCH 3 , cyclo-CF 2 CF 2 CF═CF—, cyclo-CF 2 CF═CFCF 2 CF 2 —, cyclo-CF 2 CF═CFCF 2 CF 2 CF 2 , CF 3 CF 2 CF 2 CF 2 CH═CH 2 , CF 3 CH═CHCF 2 CF 3 , CF 2 CF 2 CH═CHCF 2 CF 3 , CF 3 CH═CHCF 2 CF 2 CF 3 , CF 3 CF═CFC 2 F 5 , CF 3 CF═CFCF 2 CF 2 C 2 F 5 , CF 3 CF 2 CF═CFCF 2 C 2 F 5 , CF 3 CH═CFCF 2 CF 2 C 2 F 5 , CF 3 CF═CHCF 2 CF 2 C 2 F 5 , CF 3 CF 2 CH═CFCF 2 C 2 F 5 , CF 3 CF 2 CF═CHCF 2 C 2 F 5 , C 2 F 5 CF 2 CF═CHCH 3 , C 2 F 5 CF═CHCH 3 , (CF 3 ) 2 C═CHCH 3 , CF 3 C(CH 3 )=CHCF 3 , CHF═CFC 2 F 5 , CHF 2 CF═CFCF 3 , (CF 3 ) 2 C═CHF, CH 2 FCF═CFCF 3 , CHF═CHCF 2 CF 3 , CHF 2 CH═CFCF 3 , CHF═CFCHFCF 3 , CF 3 CH═CFCHF 2 , CHF═CFCF 2 CHF 2 , CHF 2 CF═CFCHF 2 , CH 2 CF═CFCF 3 , CH 2 FCH═CFCF 3 , CH 2 ═CFCHFCF 3 , CH 2 ═CFCF 2 CHF 2 , CF 3 CH═CFCH 2 F, CHF═CFCH 2 CF 3 , CHF═CHCHFCF 3 , CHF═CHCF 2 CHF 2 , CHF 2 CF═CHCHF 2 , CHF═CFCHFCHF 2 , CF 3 CF═CHCH 3 , CF 2 ═CHCF 2 Br, CHF═CBrCHF 2 , CHBr═CHCF 3 , CF 3 CBr═CFCF 3 , CH 2 ═CBrCF 2 CF 3 , CHBr═CHCF 2 CF 3 , CH 2 ═CHCF 2 CF 2 Br, CH 2 ═CHCBrFCF 3 , CH 3 CBr═CHCF 3 , CF 3 CBr═CHCH 3 , (CF 3 ) 2 C═CHBr, CF 3 CF═CBrCF 2 CF 3 , E-CHF 2 CBr═CFC 2 F 5 , Z-CHF 2 CBr═CFC 2 F 5 , CF 2 ═CBrCHFC 2 F 5 , (CF 3 ) 2 CFCBr═CH 2 , CHBr═CF(CF 2 ) 2 CHF 2 , CH 2 ═CBrCF 2 C 2 F 5 , CF 2 ═C(CH 2 Br)CF 3 , CH 2 ═C(CBrF 2 )CF 3 , (CF 3 ) 2 CHCH═CHBr, (CF 3 ) 2 C═CHCH 2 Br, CH 2 ═CHCF(CF 3 )CBrF 2 , CF 2 ═CHCF 2 CH 2 CBrF 2 , CFBr═CHCF 3 , CFBr═CFCF 3 , CF 3 CF 2 CF 2 CBr═CH 2 , and CF 3 (CF 2 ) 3 CBr═CH 2 .    
   
   
       2 . The propellant of  claim 1 , wherein R 1  and R 2  are, independently, CF 3 , C 2 F 5 , CF 2 CF 2 CF 3 , CF(CF 3 ) 2 , CF 2 CF 2 CF 2 CF 3 , CF(CF 3 )CF 2 CF 3 , CF 2 CF(CF 3 ) 2 , C(CF 3 ) 3 , CF 2 CF 2 CF 2 CF 2 CF 3 , CF 2 CF 2 CF(CF 3 ) 2 , C(CF 3 ) 2 C 2 F 5 , CF 2 CF 2 CF 2 CF 2 CF 2 CF 3 , CF(CF 3 ) CF 2 CF 2 C 2 F 5 , or C(CF 3 ) 2 CF 2 C 2 F 5 .  
   
   
       3 . The propellant of  claim 1 , wherein the hydrofluorocarbon is CF 3 CH═CHCF 3 , CF 3 CH═CHC 2 F 5 , CF 3 CH═CHCF 2 C 2 F 5 , CF 3 CH═CHCF(CF 3 ) 2 , C 2 F 5 CH═CHC 2 F 5 , CF 3 CH═CH(CF 2 ) 3 CF 3 , CF 3 CH═CHCF 2 CF(CF 3 ) 2 , CF 3 CH═CHCF(CF 3 )C 2 F 5 , CF 3 CH═CHC(CF 3 ) 3 , C 2 F 5 CH═CHCF 2 C 2 F 5 , C 2 F 5 CH═CHCF(CF 3 ) 2 , CF 3 CH═CH(CF 2 ) 4 CF 3 , CF 3 CH═CHCF 2 CF 2 CF(CF 3 )  2 , CF 3 CH═CHC(CF 3 ) 2 C 2 F 5 , C 2 F 5 CH═CH(CF 2 ) 3 CF 3 , C 2 F 5 CH═CHCF 2 CF(CF 3 ) 2 , C 2 F 5 CH═CHCF(CF 3 )C 2 F 5 , C 2 F 5 CH═CHC(CF 3 ) 3 , C 2 F 5 CF 2 CH═CHCF 2 C 2 F 5 , (CF 3 ) 2 CFCH═CHCF(CF 3 ) 2 , C 2 F 5 CH═CHCF(CF 3 ) 2 , CF 3 CH═CH(CF 2 ) 5 CF 3 , CF 3 CH═CHCF(CF 3 )(CF 2 ) 2 C 2 F 5 , CF 3 CH═CHC(CF 3 ) 2 CF 2 C 2 F 5 , C 2 F 5 CH═CH(CF 2 ) 4 CF 3 , C 2 F 5 CH═CHCF 2 CF 2 CF(CF 3 ) 2 , C 2 F 5 CH═CHC(CF 3 ) 2 C 2 F 5 , C 2 F 5 CF 2 CH═CH(CF 2 ) 3 CF 3 , C 2 F 5 CF 2 CH═CHCF 2 CF(CF 3 ) 2 , C 2 F 5 CF 2 CH═CHCF(CF 3 )C 2 F 5 , C 2 F 5 CF 2 CH═CHC(CF 3 ) 3 , (CF 3 ) 2 CFCH═CH(CF 2 ) 3 CF 3 , (CF 3 ) 2 CFCH═CHCF 2 CF(CF 3 ) 2 , (CF 3 ) 2 CFCH═CHCF(CF 3 )C 2 F 5 , (CF 3 ) 2 CFCH═CHC(CF 3 ) 3 , C 2 F 5 CH═CH(CF 2 ) 5 CF 3 , C 2 F 5 CH═CHCF(CF 3 )(CF 2 ) 2 C 2 F 5 , C 2 F 5 CH═CHC(CF 3 ) 2 CF 2 C 2 F 5 , C 2 F 5 CF 2 CH═CH(CF 2 )  4 CF 3 , C 2 F 5 CF 2 CH═CHCF 2 CF 2 CF(CF 3 ) 2 , C 2 F 5 CF 2 CH═CHC(CF 3 ) 2 C 2 F 5 , (CF 3 ) 2 CFCH═CH(CF 2 ) 44 CF 3 , (CF 3 ) 2 CFCH═CHCF 2 CF 2 CF(CF 3 ) 2 , (CF 3 ) 2 CFCH═CHC(CF 3 ) 2 C 2 F 5 , CF 3 (CF 2 ) 3 CH═CH(CF 2 ) 3 CF 3 , CF 3 (CF 2 ) 3 CH═CHCF 2 CF(CF 3 ) 2 , CF 3 (CF 2 ) 3 CH═CHCF(CF 3 )C 2 F 5 , CF 3  (CF 2 ) 3 CH═CHC(CF 3 ) 3 , (CF 3 ) 2 CFCF 2 CH═CHCF 2 CF(CF 3 ) 2 , (CF 3 ) 2 CFCF 2 CH═CHCF(CF 3 )C 2 F 5 , (CF 3 ) 2 CFCF 2 CH═CHC(CF 3 ) 3 , C 2 F 5 CF(CF 3 )CH═CHCF(CF 3 )C 2 F 5 , C 2 F 5 CF(CF 3 )CH═CHC(CF 3 ) 3 , or (CF 3 ) 3 CCH═CHC(CF 3 ) 3 .  
   
   
       4 . The propellant of  claim 1 , wherein the propellant consists essentially of the fluorocarbon or hydrofluorocarbon.  
   
   
       5 . The propellant of  claim 4 , wherein the propellant consists of the fluorocarbon or hydrofluorocarbon.  
   
   
       6 . A sprayable composition comprising the propellant of  claim 1 .  
   
   
       7 . The sprayable composition of  claim 6 , wherein the sprayable composition is an aerosol.  
   
   
       8 . The sprayable composition of  claim 7 , wherein the aerosol has a vapor pressure in a range of from about 138 to 621 kPa at 21° C.  
   
   
       9 . The sprayable composition of  claim 6 , wherein the sprayable composition is a cleaner, duster, personal care product, household product, automotive product, or medicament.  
   
   
       10 . The sprayable composition of  claim 9 , wherein the personal care product is a deodorant, perfume, or hair spray.  
   
   
       11 . The sprayable composition of  claim 9 , wherein the household product is a wax, polish, pan spray, room freshener, or household insecticide.  
   
   
       12 . The sprayable composition of  claim 9 , wherein medicament is a metered dose inhaler.  
   
   
       13 . The sprayable composition of  claim 9 , wherein the medicament further comprises a beta-agonist or a corticosteroid.  
   
   
       14 . The sprayable composition of  claim 9 , wherein the automotive product is a cleaner or polisher.  
   
   
       15 . An aerosol dispensing system comprising the propellant of  claim 1 .  
   
   
       16 . A sealed container comprising the aerosol dispensing system of  claim 15 .  
   
   
       17 . The sealed container of  claim 16 , further comprising an aerosol dispensing valve.  
   
   
       18 . A pro cess for producing aerosol products comprising the step of adding a composition of  claim 1  to active ingredients in an aerosol container, wherein said composition functions as a propellant.  
   
   
       19 . A pro cess for producing aerosol products comprising the step of adding a composition of  claim 3  to active ingredients in an aerosol container, wherein said composition functions as a propellant.

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