US2007025873A1PendingUtilityA1

Corrosion-resistant, cold-formable, machinable, high strength, martensitic stainless steel

Assignee: MAGEE JOHN H JRPriority: Jul 29, 2005Filed: Jul 29, 2005Published: Feb 1, 2007
Est. expiryJul 29, 2025(expired)· nominal 20-yr term from priority
C22C 38/60C22C 38/001C22C 38/22C22C 38/04C22C 38/20C22C 38/002
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Claims

Abstract

A corrosion resistant, martensitic steel alloy having very good cold formability is described. The alloy has the following weight percent composition. Carbon 0.10-0.40 Manganese 0.01-2.0 Silicon 2.0 max. Phosphorus 0.2 max. Sulfur 0.030 max. Chromium 10-15 Nickel 0.5 max. Molybdenum 0.75-4.0 Nitrogen 0.02-0.15 Copper 1.5-4.0 Titanium 0.01 max. Aluminum 0.01 max. Niobium + Tantalum 0.10 max. Vanadium 0.20 max. Zirconium less than 0.001 Calcium less than 0.001 The balance of the alloy is essentially iron. Nickel and copper are balanced in the alloy such that the ratio Ni/Cu is less than 0.2. A second embodiment of the alloy contains at least about 0.005% sulfur, selenium, or a combination thereof to provide good machinability.

Claims

exact text as granted — not AI-modified
1 . A corrosion resistant, martensitic steel alloy consisting essentially, in weight percent, about  
     
       
         
               
               
               
             
                   
                   
               
                   
                   
               
                   
                 Carbon 
                 0.10-0.40 
               
                   
                 Manganese 
                 0.01-2.0 
               
                   
                 Silicon 
                 2.0 max 
               
                   
                 Phosphorus 
                 0.2 max 
               
                   
                 Sulfur 
                 0.030 max 
               
                   
                 Chromium 
                 10-15 
               
                   
                 Nickel 
                 0.5 max 
               
                   
                 Molybdenum 
                 0.75-4.0 
               
                   
                 Nitrogen 
                 0.02-0.15 
               
                   
                 Copper 
                 1.5-4.0 
               
                   
                 Titanium 
                 0.01 max 
               
                   
                 Aluminum 
                 0.01 max 
               
                   
                 Niobium + Tantalum 
                 0.10 max 
               
                   
                 Vanadium 
                 0.20 max 
               
                   
                 Zirconium 
                 less than 0.001 
               
                   
                 Calcium 
                 less than 0.001 
               
                   
                   
               
                   
                   
               
           
              
              
             
             
              
              
              
              
              
              
              
              
              
              
              
              
              
              
              
              
              
              
             
          
         
       
     
     and the balance is essentially iron, wherein Ni/Cu is less than 0.2.  
   
   
       2 . A corrosion resistant, martensitic steel alloy as set forth in  claim 1  containing not more than about 14.3% chromium.  
   
   
       3 . A corrosion resistant, martensitic steel alloy as set forth in  claim 1  containing at least about 1.75% copper.  
   
   
       4 . A corrosion resistant, martensitic steel alloy as set forth in  claim 1  containing not more than about 3.0% molybdenum.  
   
   
       5 . A corrosion resistant, martensitic steel alloy as set forth in  claim 1  containing at least about 0.04% nitrogen.  
   
   
       6 . A corrosion resistant, martensitic steel alloy as set forth in  claim 2  containing at least about 11.5% chromium.  
   
   
       7 . A corrosion resistant, martensitic steel alloy as set forth in  claim 1  containing not more than about 0.35% nickel.  
   
   
       8 . A corrosion resistant, martensitic steel alloy as set forth in  claim 7  containing at least about 2.0% copper.  
   
   
       9 . A corrosion resistant, martensitic steel alloy as set forth in  claim 8  containing not more than about 0.25% nickel.  
   
   
       10 . A corrosion resistant, martensitic steel alloy as set forth in  claim 1  containing at least about 0.005% of sulfur, selenium, or a combination thereof.  
   
   
       11 . A corrosion resistant, martensitic steel alloy consisting essentially, in weight percent, about  
     
       
         
               
               
               
             
                   
                   
               
                   
                   
               
                   
                 Carbon 
                 0.15-0.30 
               
                   
                 Manganese 
                 0.01-1.0 
               
                   
                 Silicon 
                 1.0 max 
               
                   
                 Phosphorus 
                 0.1 max 
               
                   
                 Sulfur 
                 0.020 max 
               
                   
                 Chromium 
                 11.5-14.3 
               
                   
                 Nickel 
                 0.35 max 
               
                   
                 Molybdenum 
                 1.25-3.0 
               
                   
                 Nitrogen 
                 0.04-0.10 
               
                   
                 Copper 
                 1.75-3.5 
               
                   
                 Titanium 
                 0.01 max 
               
                   
                 Aluminum 
                 0.01 max 
               
                   
                 Niobium + Tantalum 
                 0.10 max 
               
                   
                 Vanadium 
                 0.20 max 
               
                   
                 Zirconium 
                 less than 0.001 
               
                   
                 Calcium 
                 less than 0.001 
               
                   
                   
               
                   
                   
               
           
              
              
             
             
              
              
              
              
              
              
              
              
              
              
              
              
              
              
              
              
              
              
             
          
         
       
     
     and the balance is essentially iron, wherein Ni/Cu is not more than about 0.15.  
   
   
       12 . A corrosion resistant, martensitic steel alloy as set forth in  claim 11  containing not more than about 13.8% chromium.  
   
   
       13 . A corrosion resistant, martensitic steel alloy as set forth in  claim 11  containing at least about 2.0% copper.  
   
   
       14 . A corrosion resistant, martensitic steel alloy as set forth in  claim 11  containing not more than about 2.5% molybdenum.  
   
   
       15 . A corrosion resistant, martensitic steel alloy as set forth in  claim 11  containing at least about 0.05% nitrogen.  
   
   
       16 . A corrosion resistant, martensitic steel alloy as set forth in  claim 13  containing at least about 13.0% chromium.  
   
   
       17 . A corrosion resistant, martensitic steel alloy as set forth in  claim 11  containing not more than about 0.25% nickel.  
   
   
       18 . A corrosion resistant, martensitic steel alloy as set forth in  claim 11  containing at least about 0.005% sulfur, selenium, or a combination thereof.  
   
   
       19 . A corrosion resistant, martensitic steel alloy consisting essentially, in weight percent, about  
     
       
         
               
               
               
             
                   
                   
               
                   
                   
               
                   
                 Carbon 
                 0.20-0.25 
               
                   
                 Manganese 
                 0.01-0.3 
               
                   
                 Silicon 
                 0.75 max 
               
                   
                 Phosphorus 
                 0.05 max 
               
                   
                 Sulfur 
                 0.015 max 
               
                   
                 Chromium 
                 13.0-13.8 
               
                   
                 Nickel 
                 0.25 max 
               
                   
                 Molybdenum 
                 1.75-2.5 
               
                   
                 Nitrogen 
                 0.05-0.08 
               
                   
                 Copper 
                 2.0-3.0 
               
                   
                 Titanium 
                 0.01 max 
               
                   
                 Aluminum 
                 0.01 max 
               
                   
                 Niobium + Tantalum 
                 0.10 max 
               
                   
                 Vanadium 
                 0.20 max 
               
                   
                 Zirconium 
                 less than 0.001 
               
                   
                 Calcium 
                 less than 0.001 
               
                   
                   
               
                   
                   
               
           
              
              
             
             
              
              
              
              
              
              
              
              
              
              
              
              
              
              
              
              
              
              
             
          
         
       
     
     and the balance is essentially iron, wherein Ni/Cu is not more than about 0.10.  
   
   
       20 . A corrosion resistant, martensitic steel alloy as set forth in  claim 20  which contains at least about 0.007% sulfur, selenium, or a combination thereof.

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