US2006270544A1PendingUtilityA1

Optical colored glass, its use, and an optical long-pass cutoff filter

Assignee: SCHOTT AGPriority: Aug 22, 2001Filed: Aug 2, 2006Published: Nov 30, 2006
Est. expiryAug 22, 2021(expired)· nominal 20-yr term from priority
C03C 3/115C03C 4/02
52
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Claims

Abstract

The invention concerns an optical colored glass with a composition (in percent by weight based on oxide) of SiO 2 30-75; K 2 O 5-35; B 2 O 3 >4-17; ZnO 5-37; F 0.01-10; CdO 0.1-1, S+Se+Te 0.1-1.5 as well as the use of this glass as a long-pass cutoff filter.

Claims

exact text as granted — not AI-modified
1 . An optical colored glass composition comprising: (in percent by weight based on oxide)  
     
       
         
               
               
               
             
                   
                   
               
                   
                   
               
                   
                 SiO 2   
                 30-75 
               
                   
                 K 2 O 
                  5-35 
               
                   
                 B 2 O 3   
                 >4-17 
               
                   
                 ZnO 
                  5-37 
               
                   
                 F 
                 0.01-10   
               
                   
                 CdO 
                 0.1-1   
               
                   
                 S + Se + Te 
                  0.1-1.5; 
               
                   
                   
               
                   
                   
               
           
              
              
             
             
              
              
              
              
              
              
              
              
              
             
          
         
       
     
     and 
 said composition being substantially free of TiO 2  and Al 2 O 3 .  
 
   
   
       2 . The optical colored glass composition of  claim 1  comprising: (in percent by weight based on oxide)  
     
       
         
               
               
               
             
                   
                   
               
                   
                   
               
                   
                 SiO 2   
                 30-75 
               
                   
                 K 2 O 
                  5-35 
               
                   
                 B 2 O 3   
                 >4-17 
               
                   
                 ZnO 
                 5-30 
               
                   
                 F 
                 0.01-10   
               
                   
                 CdO 
                 0.1-1   
               
                   
                 S + Se + Te 
                  0.1-1.5; 
               
                   
                   
               
                   
                   
               
           
              
              
             
             
              
              
              
              
              
              
              
              
              
             
          
         
       
     
     and 
 said composition being substantially free of TiO 2  and Al 2 O 3 .  
 
   
   
       3 . The optical colored glass composition of  claim 1  comprising: (in percent by weight based on oxide)  
     
       
         
               
               
               
             
                   
                   
               
                   
                   
               
                   
                 SiO 2   
                 40-65 
               
                   
                 K 2 O 
                 15-29 
               
                   
                 B 2 O 3   
                  5-16 
               
                   
                 ZnO 
                  9-30 
               
                   
                 F 
                 0.01-10   
               
                   
                 CdO 
                 0.1-1   
               
                   
                 S + Se + Te 
                 0.1-1.1; 
               
                   
                   
               
                   
                   
               
           
              
              
             
             
              
              
              
              
              
              
              
              
              
             
          
         
       
     
     and 
 said composition being substantially free of TiO 2  and Al 2 O 3 .  
 
   
   
       4 . The optical colored glass composition of  claim 1 , further comprising common refining substances in common amounts.  
   
   
       5 . The optical colored glass composition of  claim 1  further comprising: (in percent by weight based on oxide)  
     
       
         
               
               
               
             
                   
                   
               
                   
                   
               
                   
                 Na2O 
                 0-20 
               
                   
                 MgO 
                 0-20 
               
                   
                 GaO 
                 0-20 
               
                   
                 with GaO + MgO 
                 0-20 
               
                   
                 Al 2 O 3   
                 0-10 
               
                   
                   
               
                   
                   
               
           
              
              
             
             
              
              
              
              
              
              
              
             
          
         
       
     
   
   
       6 . The optical colored glass composition of  claim 1  further comprising: (in percent by weight based on oxide)  
     
       
         
               
               
               
             
                   
                   
               
                   
                   
               
                   
                 SrO 
                  0-<10 
               
                   
                 BaO 
                  0-<10 
               
                   
                 La 2 O 3   
                 0-5 
               
                   
                 Nb 2 O 5   
                 0-5 
               
                   
                 Ta 2 O 5   
                 0-5 
               
                   
                 CeO 2   
                 0-5 
               
                   
                 ZrO 2   
                 0-5 
               
                   
                 P 2O   5   
                   0-10. 
               
                   
                   
               
                   
                   
               
           
              
              
             
             
              
              
              
              
              
              
              
              
              
              
             
          
         
       
     
   
   
       7 . The optical colored glass composition of  claim 1  further comprising:  
     
       
         
               
               
               
             
                   
                   
               
                   
                   
               
                   
                 F 
                 1-10 
               
                   
                 MgO + CaO + SrO + BaO 
                 0-<3 
               
                   
                   
               
                   
                   
               
           
              
              
             
             
              
              
              
              
             
          
         
       
     
     and  
   
   
       8 . The optical colored glass composition of  claim 5  further comprising:  
     
       
         
               
               
               
             
                   
                   
               
                   
                   
               
                   
                 MgO + CaO + SrO + BaO 
                 >3; and 
               
                   
                 and F 
                 0.01-<1. 
               
                   
                   
               
                   
                   
               
           
              
              
             
             
              
              
              
              
             
          
         
       
     
   
   
       9 . The optical colored glass composition of  claim 1 , comprising an absorption edge (=edge wavelength λ c ) between 390 nm and 850 nm.  
   
   
       10 . An optical long-pass cutoff filter comprising the optical colored glass of  claim 1 .  
   
   
       11 . An optical long-pass cutoff filter consisting of the optical colored glass of  claim 1 .  
   
   
       12 . The optical colored glass composition of  claim 2  comprising: (in percent by weight based on oxide)  
     
       
         
               
               
               
             
                   
                   
               
                   
                   
               
                   
                 SiO 2   
                 40-65 
               
                   
                 K 2 O 
                 15-29 
               
                   
                 B 2 O 3   
                  5-16 
               
                   
                 ZnO 
                  9-30 
               
                   
                 F 
                 0.01-10   
               
                   
                 CdO 
                 0.1-1   
               
                   
                 S + Se + Te 
                 0.1-1;  
               
                   
                   
               
                   
                   
               
           
              
              
             
             
              
              
              
              
              
              
              
              
              
             
          
         
       
     
     and 
 said composition being substantially free of TiO 2  and Al 2 O 3 .  
 
   
   
       13 . The optical colored glass composition of  claim 2  further comprising: (in percent by weight based on oxide)  
     
       
         
               
               
               
             
                   
                   
               
                   
                   
               
                   
                 Na2O 
                 0-20 
               
                   
                 MgO 
                 0-20 
               
                   
                 CaO 
                 0-20 
               
                   
                 with GaO + MgO 
                  0-20. 
               
                   
                 Al 2 O 3   
                 0-10 
               
                   
                   
               
                   
                   
               
           
              
              
             
             
              
              
              
              
              
              
              
             
          
         
       
     
   
   
       14 . The optical colored glass composition of  claim 3  further comprising: (in percent by weight based on oxide)  
     
       
         
               
               
               
             
                   
                   
               
                   
                   
               
                   
                 Na2O 
                 0-20 
               
                   
                 MgO 
                 0-20 
               
                   
                 GaO 
                 0-20 
               
                   
                 with GaO + MgO 
                  0-20. 
               
                   
                 Al 2 O 3   
                 0-10 
               
                   
                   
               
                   
                   
               
           
              
              
             
             
              
              
              
              
              
              
              
             
          
         
       
     
   
   
       15 . The optical colored glass composition of  claim 2  further comprising: (in percent by weight based on oxide)  
     
       
         
               
               
               
             
                   
                   
               
                   
                   
               
                   
                 SrO 
                 0-<10 
               
                   
                 BaO 
                 0-<10 
               
                   
                 La 2 O 3   
                 0-5 
               
                   
                 Nb 2 O 5   
                 0-5 
               
                   
                 Ta 2 O 5   
                 0-5 
               
                   
                 CeO 2   
                 0-5 
               
                   
                 ZrO 2   
                 0-5 
               
                   
                 P 2 O 5   
                 0-10. 
               
                   
                   
               
                   
                   
               
           
              
              
             
             
              
              
              
              
              
              
              
              
              
              
             
          
         
       
     
   
   
       16 . The optical colored glass composition of  claim 3  further comprising: (in percent by weight based on oxide)  
     
       
         
               
               
               
             
                   
                   
               
                   
                   
               
                   
                 SrO 
                 0-<10 
               
                   
                 BaO 
                 0-<10 
               
                   
                 La 2 O 3   
                 0-5 
               
                   
                 Nb 2 O 5   
                 0-5 
               
                   
                 Ta 2 O 5   
                 0-5 
               
                   
                 CeO 2   
                 0-5 
               
                   
                 ZrO 2   
                 0-5 
               
                   
                 P 2 O 5   
                 0-10. 
               
                   
                   
               
                   
                   
               
           
              
              
             
             
              
              
              
              
              
              
              
              
              
              
             
          
         
       
     
   
   
       17 . The optical colored glass in accordance with composition of  claim 5  further comprising: (in percent by weight based on oxide)  
     
       
         
               
               
               
             
                   
                   
               
                   
                   
               
                   
                 SrO 
                 0-<10 
               
                   
                 BaO 
                 0-<10 
               
                   
                 La 2 O 3   
                 0-5 
               
                   
                 Nb 2 O 5   
                 0-5 
               
                   
                 Ta 2 O 5   
                 0-5 
               
                   
                 CeO 2   
                 0-5 
               
                   
                 ZrO 2   
                 0-5 
               
                   
                 P 2 O 5   
                 0-10. 
               
                   
                   
               
                   
                   
               
           
              
              
             
             
              
              
              
              
              
              
              
              
              
              
             
          
         
       
     
   
   
       18 . The optical colored glass composition of  claim 6  further comprising:  
     
       
         
               
               
               
             
                   
                   
               
                   
                   
               
                   
                 MgO + CaO + SrO + BaO 
                 >3 and 
               
                   
                 and F 
                 0.01-<1. 
               
                   
                   
               
                   
                   
               
           
              
              
             
             
              
              
              
              
             
          
         
       
     
   
   
       19 . The optical colored glass composition of  claim 2 , further comprising an absorption edge (=edge wavelength λ c ) between 390 nm and 850 nm.  
   
   
       20 . The optical colored glass composition of  claim 3 , further comprising an absorption edge (=edge wavelength λ c ) between 390 nm and 850 nm.  
   
   
       21 . An optical colored glass composition comprising: (in percent by weight based on oxide)  
     
       
         
               
               
               
             
                   
                   
               
                   
                   
               
                   
                 SiO 2   
                 30-75 
               
                   
                 K 2 O 
                  5-35 
               
                   
                 B 2 O 3   
                 >4-17 
               
                   
                 ZnO 
                  5-37 
               
                   
                 F 
                 >2    
               
                   
                 CdO 
                 0.1-1   
               
                   
                 S + Se + Te 
                  0.1-1.5. 
               
                   
                   
               
                   
                   
               
           
              
              
             
             
              
              
              
              
              
              
              
              
              
             
          
         
       
     
   
   
       22 . The optical colored glass composition of  claim 21 , comprising: (in percent by weight based on oxide)  
     
       
         
               
               
               
             
                   
                   
               
                   
                   
               
                   
                 SiO2 
                 30-75 
               
                   
                 K20 
                  5-35 
               
                   
                 B203 
                 >4-17 
               
                   
                 ZnO 
                  5-37 
               
                   
                 F 
                 >6.73     
               
                   
                 CdO 
                 0.1-1   
               
                   
                 S+ Se + Te 
                  0.1-1.5.

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