Anionic polymers composed of dicarboxylic acids and uses thereof

Abstract

Biodegradable anionic polymers are disclosed which include recurring polymeric subunits preferably made up of dicarboxylic monomers such as maleic anhydride, itaconic anhydride or citraconic anhydride. Free radical polymerization is used in the synthesis of the polymers. The polymers may be complexed with ions and/or mixed with fertilizers or seeds to yield agriculturally useful compositions. The preferred products of the invention may be applied foliarly or to the earth adjacent growing plants in order to enhance nutrient uptake by the plants.

1 . A method of decreasing fertilizer dust comprising the step of coating fertilizer with a polymer, said polymer being in intimate contact with said fertilizer, and comprising recurring polymeric subunits each made up of at least two different moieties individually and respectively taken from the group consisting of B, and C moieties, where moiety B is of the general formula  
       
         
           
           
               
               
           
         
         and moiety C is of the general formula  
         
           
             
             
                 
                 
             
           
         
         wherein each R 7  is individually and respectively selected from the group consisting of H, OH, C 1 -C 30  straight, branched chain and cyclic alkyl or aryl groups, C 1 -C 30  straight, branched chain and cyclic alkyl or aryl based ester groups, R′CO 2  groups, OR′ groups and COOX groups, wherein R′ is selected from the group consisting of C 1 -C 30  straight, branched chain and cyclic alkyl or aryl groups and X is selected from the group consisting of H, the alkali metals, NH 4  and the C 1 -C 4  alkyl ammonium groups, R 3  and R 4  are individually and respectively selected from the group consisting of H, C 1 -C 30  straight, branched chain and cyclic alkyl or aryl groups, R 5 , R 6 , R 10  and R 11  are individually and respectively selected from the group consisting of H, the alkali metals, NH 4  and the C 1 -C 4  alkyl ammonium groups, Y is selected from the group consisting of Fe, Mn, Mg, Zn, Cu, Ni, Co, Mo, V and Ca, and R 8  and R 9  are individually and respectively selected from the group consisting of nothing (i.e., the groups are non-existent), CH 2 , C 2 H 4 , and C 3 H 6 , each of said moieties having or being modified to have a total of two COO groups therein, and;  
         wherein a majority of the subunits forming the resultant polymer are dicarboxylic subunits.  
       
     
     
         2 . The method of  claim 1 , said polymer coating being at a level of at least about 0.005% w/w.  
     
     
         3 . A method of decreasing fertilizer dust comprising the step of coating fertilizer with a composition comprising a dicarboxylic acid polymer, said polymer being in intimate contact with said fertilizer, and having recurring polymeric subunits each made up of at least two different moieties individually and respectively taken from the group consisting of B and C moieties,-wherein moiety B is of the general formula  
       
         
           
           
               
               
           
         
       
       and moiety C is of the general formula  
       
         
           
           
               
               
           
         
         wherein each R 7  is individually and respectively selected from the group consisting of H, OH, C 1 -C 30  straight, branched chain and cyclic alkyl or aryl groups, C 1 -C 30  straight, branched chain and cyclic alkyl or aryl based ester groups, R′CO 2  groups, OR′ groups and COOX groups, wherein R′ is selected from the group consisting of C 1 -C 30  straight, branched chain and cyclic alkyl or aryl groups and X is selected from the group consisting of H, the alkali metals, NH 4  and the C 1 -C 4  alkyl ammonium groups, R 3  and R 4  are individually and respectively selected from the group consisting of H, C 1 -C 30  straight, branched chain and cyclic alkyl or aryl groups, R 5 , R 6 , R 10  and R 11  are individually and respectively selected from the group consisting of H, the alkali metals, NH 4  and the C 1 -C 4  alkyl ammonium groups, Y is selected from the group consisting of Fe, Mn, Mg, Zn, Cu, Ni, Co, Mo, V and Ca, and R 8  and R 9  are individually and respectively selected from the group consisting of nothing (i.e., the groups are non-existent), CH 2 , C 2 H 4 , and C 3 H 6 , each of said moieties having or being modified to have a total of two COO groups therein, and;  
         wherein a majority of the subunits forming the resultant polymer are dicarboxylic subunits.  
       
     
     
         4 . The method of  claim 3 , said polymer comprising at least about 0.005% by weight of said coated fertilizer.  
     
     
         5 . The method of  claim 3 , said polymer comprising at least about 0.01% by weight of said coated fertilizer.  
     
     
         6 . A method of decreasing fertilizer dust comprising the step of coating fertilizer with a polymer, comprising recurring polymeric subunits each made up of at least two different moieties individually and respectively taken from the group consisting of B, and C moieties, where moiety B is of the general formula  
       
         
           
           
               
               
           
         
         and moiety C is of the general formula  
         
           
             
             
                 
                 
             
           
         
         wherein each R 7  is individually and respectively selected from the group consisting of H, OH, C 1 -C 30  straight, branched chain and cyclic alkyl or aryl groups, C 1 -C 30  straight, branched chain and cyclic alkyl or aryl based ester groups, R′CO 2  groups, OR′ groups and COOX groups, wherein R′ is selected from the group consisting of C 1 -C 30  straight, branched chain and cyclic alkyl or aryl groups and X is selected from the group consisting of H, the alkali metals, NH 4  and the C 1 -C 4  alkyl ammonium groups, R 3  and R 4  are individually and respectively selected from the group consisting of H, C 1 -C 30  straight, branched chain and cyclic alkyl or aryl groups, R 5 , R 6 , R 10  and R 11  are individually and respectively selected from the group consisting of H, the alkali metals, NH 4  and the C 1 -C 4  alkyl ammonium groups, Y is selected from the group consisting of Fe, Mn, Mg, Zn, Cu, Ni, Co, Mo, V and Ca, and R 8  and R 9  are individually and respectively selected from the group consisting of nothing (i.e., the groups are non-existent), CH 2 , C 2 H 4 , and C 3 H 6 , each of said moieties having or being modified to have a total of two COO groups therein, and;  
         wherein a majority of the subunits forming the resultant polymer are dicarboxylic subunits.  
       
     
     
         7 . The method of  claim 6 , said polymer comprising at least about 0.005% by weight of said coated fertilizer.  
     
     
         8 . The method of  claim 6 , said polymer comprising at least about 0.01% by weight of said coated fertilizer.