Formulation and method for depositing a material on a substrate

Abstract

A formulation for depositing a material on a substrate, the formulation comprising the material to be deposited on the substrate dissolved in a solvent system comprising a first solvent component having a relatively high boiling point and which exhibits a relatively low solubility with respect to the material to be deposited, and a second solvent component having a relatively low boiling point and which exhibits a relatively high solubility with respect to the material to be deposited.

1 . A formulation for depositing a material on a substrate according to an ink-jet technique, the formulation comprising the material to be deposited on the substrate dissolved in a solvent system comprising a first solvent component having a relatively high boiling point and which exhibits a relatively low solubility with respect to the material to be deposited, and a second solvent component having a relatively low boiling point and which exhibits a relatively high solubility with respect to the material to be deposited.  
     
     
         2 . A formulation according to  claim 1  wherein the second solvent component has a boiling point in the range of 100 to 200° C.  
     
     
         3 . A formulation according to  claim 1  or  claim 2  wherein the first solvent component has a boiling point in the range of 130 to 300° C.  
     
     
         4 . A formulation according to  claim 1  wherein the difference in boiling point between the first and second solvent components is in the range of 30 to 250° C.  
     
     
         5 . A formulation according to  claim 4  wherein the difference in boiling point between the first and second solvent components is in the range of 70 to 150° C.  
     
     
         6 . A formulation according to any preceding claim wherein the solubility of the material to be deposited in the first solvent component is up to 0.5% weight per volume.  
     
     
         7 . A formulation according to  claim 6  wherein the solubility of the material to be deposited in the first solvent component is in the range of 0.03 to 0.3% weight per volume.  
     
     
         8 . A formulation according to any preceding claim wherein the solubility of the material to be deposited in the second solvent component is greater than 0.5% weight per volume.  
     
     
         9 . A formulation according to  claim 8  wherein the wherein the solubility of the material to be deposited in the second solvent component is greater than 1.5% weight per volume.  
     
     
         10 . A formulation according to any preceding claim wherein the amount of material in the formulation and the proportion of the first solvent component are selected such that upon removal of the second solvent component the remaining solution of the material in the first solvent component would be at or above saturation.  
     
     
         11 . A formulation according to  claim 1  wherein the first solvent component comprises α-tetralone and the second solvent component comprises 1,2-dimethylbenzene.  
     
     
         12 . A formulation according to  claim 1  wherein the first solvent component comprises cyclohexylbenzene and the second solvent component comprises 1,2-dimethylbenzene.  
     
     
         13 . A formulation according to  claim 1  wherein the first solvent component comprises xylene and 1,2,4-trimethylbenzene and the second solvent component comprises isopropylbiphenyl.  
     
     
         14 . A method of depositing a material on a substrate comprising depositing one or more drops of a solution of the material onto the substrate through a nozzle according to an ink-jet technique and drying the drops, wherein the solution of the material comprises a formulation according to any preceding claim.  
     
     
         15 . A method according to  claim 14  wherein the variation in thickness of the dried drop is less than 30% of the maximum thickness.  
     
     
         16 . A method of producing a light-emitting device comprising a layer of an electroluminescent material sandwiched between two electrodes such that charge carriers can move between the electrodes and the layer of electroluminescent material, wherein the layer of electroluminescent material is produced by a method according to  claim 14  or  claim 15 .  
     
     
         17 . A use of a formulation according to any of  claims 1  to  13  for reducing or avoiding a ring deposition effect.  
     
     
         18 . A formulation according to  claim 1  excluding 1% w/v of a triblend containing approximately 14 wt. % of a ternary polymer containing fluorene (FB 8 ) units, benzothiadiazole (BT) units and triarylene units, 56 wt. % of F8BT and 30 wt. % TFB in a solvent mixture containing 20 vol. % 1,2,4-trimethylbenzene and 80 vol. % xylene or a solvent mixture containing 50 vol. % 1,2,4-trimethylbenzene and 50 vol. % xylene.