Tooth for whitening products and methods of making the same

Abstract

A dissolving strip for tooth whitening the strip having at least a first tooth contacting layer and a second outer layer. The first tooth contacting layer has a solid tooth whitening active in an amount which reacts within a predetermined time when placed on a tooth. The second outer layer has a blend of polymers having different molecular weights; the blend of polymers being selected to dissolve after the predetermined time has elapsed. The outer layer contains the tooth whitening active on said tooth until the active is substantially used up. A method of forming a dissolving tooth whitening strip is also provided, in which the outer layer is formed on a backing layer followed by the inner layer being formed on the outer layer.

1 . A dissolving strip for tooth whitening, said strip comprising: 
 at least a first tooth contacting layer and a second outer layer,    said first tooth contacting layer comprising a solid tooth whitening active in an amount which reacts within a predetermined time when placed on a tooth; and    said second outer layer comprising a blend of polymers having different molecular weights, the blend of polymers being selected to dissolve after said predetermined time has elapsed, wherein said outer layer contains said tooth whitening active on said tooth until said active is substantially used up.    
   
   
       2 . A dissolving strip for tooth whitening as claimed in  claim 1  wherein said dissolving strip is between 0.05 mm and 0.15 mm thick.  
   
   
       3 . A dissolving strip for tooth whitening as claimed in  claim 2  wherein said dissolving strip is about 0.15 mm thick.  
   
   
       4 . A dissolving strip for tooth whitening as claimed in  claim 2  wherein said outer layer dissolves in less than ten minutes.  
   
   
       5 . A dissolving strip for tooth whitening as claimed in  claim 4  wherein said outer layer dissolves in between three and seven minutes.  
   
   
       6 . A dissolving strip for tooth whitening strip as claimed in  claim 1  wherein said outer layer dissolves in about five minutes.  
   
   
       7 . A dissolving strip for tooth whitening as claimed in  claim 1  wherein said dissolving strip is mounted on a removable backing strip.  
   
   
       8 . A dissolving strip for tooth whitening as claimed in  claim 7  wherein said dissolving strip is mounted on said removable backing strip with said outer layer adjacent to said backing strip and said tooth contacting layer remote from said backing strip.  
   
   
       9 . A dissolving strip as claimed in  claim 1  wherein said outer layer contains one or more of a sweetener, a colorant and a flavouring agent.  
   
   
       10 . A dissolving strip as claimed in  claim 1  wherein said outer layer includes an anti-tartar active to be deposited on said tooth after said second outer layer dissolves.  
   
   
       11 . A dissolving strip as claimed in  claim 1  wherein said outer layer includes a tooth whitening accelerator, said tooth whitening accelerator combining with said tooth whitening active as said outer layer dissolves, said accelerator causing said tooth whitening active to react more quickly.  
   
   
       12 . A dissolving strip as claimed in  claim 1  wherein said first tooth contacting layer includes one or more plasticizers in an amount sufficient to render the first layer pliable enough to be placed on said tooth.  
   
   
       13 . A dissolving strip as claimed in  claim 12  wherein said plasticizers are selected from the group of polyols, glycerin, propylene glycol, butylene glycol and sorbitol.  
   
   
       14 . A dissolving strip as claimed in  claim 1  wherein said outer layer includes HPMC having at least three different molecular weights.  
   
   
       15 . A dissolving strip as claimed in  claim 14  wherein said HPMC includes a first HPMC type having a molecular weight of between 5,000 to 10,000 Daltons, a second HPMC type having a molecular weight of about 26,000 Daltons and a third HPMC type having a molecular weight of about 86,000 Daltons.  
   
   
       16 . A dissolving strip as claimed in  claim 15  wherein said first HPMC type has a dry weight to weight range of between 7.4 to 22%, said second HPMC type has a dry weight to weight range of between 18.5 to 33.3% and said third HPMV type has a dry weight to weight range of 3.7 to 11.1%.  
   
   
       17 . A dissolving strip as claimed in  claim 1  wherein said solid tooth whitening active in said tooth contacting layer is PVP-hydrogen peroxide.  
   
   
       18 . A dissolving strip as claimed in  claim 17  wherein said PVP-hydrogen peroxide tooth whitening active is at least 80% weight to weight dry of said tooth whitening layer.  
   
   
       19 . A dissolving strip as claimed in  claim 17  wherein said PVP-hydrogen peroxide tooth whitening active is at least 90% weight to weight dry of said tooth whitening layer.  
   
   
       20 . A dissolving strip as claimed in  claim 17  wherein said PVP-hydrogen peroxide tooth whitening active is about 93% weight to weight dry of said tooth whitening layer.  
   
   
       21 . A dissolving strip as claimed in  claim 17  wherein said PVP-hydrogen peroxide includes a first type of PVP-hydrogen peroxide having a low molecular weight of at least 8,000 Daltons and at least a second type of PVP-hydrogen peroxide having a higher molecular weight of no more than 3,000,000 Daltons.  
   
   
       22 . A dissolving strip as claimed in  claim 21  wherein said first type of PVP-hydrogen peroxide has a molecular weight of about 60,000 Daltons and at least a second type of PVP-hydrogen peroxide having a higher molecular weight of about 1,300,000 Daltons.  
   
   
       23 . A dissolving strip as claimed in  claim 21  wherein tooth contacting layer includes more of said first type of PVP-hydrogen peroxide than said second type of PVP-hydrogen peroxide.  
   
   
       24 . A dissolving strip as claimed in  claim 1  wherein said solid tooth whitening active in said tooth contacting layer is one or more of, a water insoluble cross linked PVP, carbamide peroxide, PVP/MA (poly alkyl vinyl ether-maleic acid), PVP/MA copolymer, PVP/VA (polyvinyl pyrrolidone-vinyl acetate), and PVP/VA copolymer  
   
   
       25 . A method of forming a dissolving tooth whitening strip having at least two layers, including a tooth contacting layer having a whitening active and an outer layer, said method comprising the steps of: 
 Providing a releasable backing strip;    Forming said outer layer on said backing strip and then,    Forming said tooth contacting layer with said active on said outer layer,    wherein exposure of said tooth contacting layer to manufacturing steps is minimized.    
   
   
       26 . A method of forming a dissolving tooth whitening strip as claimed in  claim 25  wherein said outer layer is formed by casting a water based cellulose solution onto said backing layer and drying said solution to form a solid film.  
   
   
       27 . A method of forming a dissolving tooth whitening strip as claimed in  claim 26  wherein said tooth contacting layer is formed by casting a volatile solvent based tooth whitening active solution onto said solid film and drying said solution to form at least a second layer on said film.  
   
   
       28 . A method of forming a dissolving tooth whitening strip as claimed in  claim 25  wherein said tooth contacting layer is formed by spraying a powder onto said solid film.  
   
   
       29 . A method of forming a dissolving tooth whitening strip as claimed in  claim 25  wherein said solid film is sufficiently dry to permit said solid film to be rolled into a roll without sticking.  
   
   
       30 . A method of forming a dissolving tooth whitening strip as claimed in  claim 25  wherein said drying step occurs in a drying tunnel.  
   
   
       31 . A method of forming a dissolving tooth whitening strip as claimed in  claim 26  wherein said solvent is ethanol.  
   
   
       32 . A method of forming a dissolving tooth whitening strip as claimed in  claim 31  wherein said ethanol is anhydrous 200 proof ethanol.