Fabric care composition

Abstract

The present invention is directed to polysaccharide-grafted polymer particles wherein the polysaccharide is preferably a β-1,4 linked polysaccharide and the particle comprises monomer units and a preformed polymer, and/or an inorganic solid or organic material.

1 . A polysaccharide-grafted polymer particle wherein the polysaccharide has β-1,4 linkages and wherein the polymer particle comprises 
 a) monomer units and a preformed polymer, or    b) monomer units and an inorganic solid or organic material or mixture thereof, or    c) a mixture of a) and b).    
   
   
       2 . A particle as claimed in  claim 1  wherein the monomer units comprise more than one type of monomer unit.  
   
   
       3 . A particle as claimed in  claim 1  wherein the monomer units comprise i) hydrophobic water insoluble monomer units or ii) hydrophilic monomer units, said hydrophobic monomer units being derived from monomers having a solubility of greater than 30 g/litre in water (distilled or equivalent) at 25° C. and which are capable of undergoing free radical addition polymerisation.  
   
   
       4 . A polysaccharide-grafted polymer particle as claimed in  claim 3  wherein the hydrophobic, water insoluble monomers are insoluble in water (distilled or equivalent) at a concentration of 0.1 g/litre or above, at 25° C.  
   
   
       5 . A polysaccharide-grafted polymer particle as claimed in  claim 4  wherein the hydrophobic, water insoluble monomer units are selected from monoacrylates, methacrylates and mixtures thereof, having a carbon chain length of at least 10 carbon atoms.  
   
   
       6 . A polysaccharide-grafted polymer particle as claimed in  claim 3  wherein the hydrophilic monomers have a solubility of greater than 40 g/litre in water (distilled or equivalent) at 25° C.  
   
   
       7 . A polysaccharide-grafted polymer particle as claimed in  claim 3  wherein the hydrophilic monomer units are present at levels of at least 10% by weight of the polysaccharide-grafted particle.  
   
   
       8 . A polysaccharide-grafted polymer particle as claimed in  claim 3 , wherein the hydrophilic monomer units are selected from methacrylic and acrylic acid, 2-hydroxyethyl acrylates and methacrylates, glycerol acrylates and methacrylates, poly(ethylene glycol) methacrylates and acrylates, n-vinyl pyrrolidone, acryloyl morpholine, n-vinyl acetamide and vinyl caprolactone.  
   
   
       9 . A polysaccharide-grafted polymer particle as claimed in  claim 1  wherein the preformed polymer is selected from 1) the group consisting of a polysiloxane, a polyester, a polyamide, a polyurethane, a polyether, an epoxy resin, an alkyd resin and a phenolic resin, and 2) a block copolymer.  
   
   
       10 . A polysaccharide-grafted polymer particle as claimed in  claim 9  wherein the block copolymer, preferably an ABA triblock thermoplastic elastomer.  
   
   
       11 . A polysaccharide-grafted polymer particle as claimed in  claim 1  wherein the inorganic solid or organic material is selected from the group consisting of titanium dioxide, zinc oxide, benzophenones, pigments and organic dyes or mixtures thereof.  
   
   
       12 . A polysaccharide-grafted polymer particle as claimed in  claim 1  wherein the polysaccharide-grafted particle contains an additional fabric benefit agent.  
   
   
       13 . A polysaccharide-grafted polymer particle as claimed in  claim 12  wherein the fabric benefit agent is selected from the following: a fabric softener, lubricant, ease of ironing aid, stiffening agent, moisturising agent, shape retention agent, crease reduction agent, anti-pilling agent, colour preservative, perfume, drape modifier, fluorescent, sunscreen, photofading inhibitor, fungicide or insect repellent.  
   
   
       14 . A polysaccharide-grafted polymer particle as claimed in  claim 1  wherein the polysaccharide is selected from the group consisting of a polymannan, polyglucan, polyglucomannan, polyxyloglucan and polygalactomannan or a mixture thereof.  
   
   
       15 . A polysaccharide-grafted polymer particle as claimed in  claim 14  wherein the polysaccharide is locust bean gum.  
   
   
       16 . A polysaccharide-grafted polymer particle as claimed in  claim 1  wherein the polysaccharide is present at levels of from 0.1% to 10% w/w of the monomer, preferably 2% w/w of the monomer.  
   
   
       17 . Use of a polysaccharide-grafted polymer particle as claimed in  claim 1 , in the treatment of fabric, preferably cotton.  
   
   
       18 . A laundry treatment composition comprising the polysaccharide-grafted particle as claimed in  claim 1 .  
   
   
       19 . Use of a laundry treatment composition as claimed in  claim 18  in the treatment of fabric, preferably cotton.  
   
   
       20 . Use as claimed in  claim 19  wherein the use provides a fabric softener, lubricant, ease of ironing, stiffening, moisturising, shape retention, crease reduction, anti-pilling, colour preservative, perfume increase, drape modifier, fluorescent, sunscreen, photofading inhibition, fungicidal or insect repellent effect to the fabric.  
   
   
       21 . A method of treating fabric, preferably cotton, comprising contacting the fabric with the polysaccharide-grafted polymer particle as claimed in  claim 1 .  
   
   
       22 . Use of a particle as claimed in  claim 1  in the treatment of fabric to deliver one or more benefit agents to the fabric.  
   
   
       23 . Use of a particle as claimed in  claim 1  in the treatment of a fabric, preferably cotton, to provide a fabric softening, lubricant, ease of ironing, stiffening, moisturising, shape retention, crease reduction, anti-pilling, colour preserving, perfume enhancing, drape modifying, fluorescent, sunscreen, photofading inhibition, fungicidal or insect repellent effect to the fabric.