Composition and method for fracturing subterranean reservoirs

Abstract

A composition and method for fracturing subterranean reservoirs by including a partially esterified, polyalkoxylated polyols as an oxidizing breaker retarder in the aqueous fracturing fluid to delay its gel breaking properties with the oxidizing breaker. The delayed gel breaking properties will lead to the controlled breaking of the fracturing fluid that reduces or eliminates damage to the formation and facilitates well clean up.

1 . A delayed breaking fracturing fluid composition for fracturing subterranean reservoirs comprising a hydratable gelling agent, an aqueous liquid, an oxidizing breaker, a partially esterified polyalkoxylated polyol as oxidizing breaker retarder and optionally a pH control agent, proppant, and crosslinking agent.  
   
   
       2 . The delayed breaking fracturing fluid composition of  claim 1  where the hydratable gelling agent is a polysaccharide and derivatives thereof that contain one or more of the following monosaccharide units: galactose, mannose, glucoside, glucose, xylose, arabinose, fructose, glucuronic acid, pyranosyl sulfate.  
   
   
       3 . The delayed breaking fracturing fluid composition of  claim 1  where the hydratable gelling agent is a synthetic polymer or copolymer of one or more of the following: polyacrylate, polymethacrylate, polyacrylamide, maleic anhydride methylvinyl ether copolymers, polyvinyl alcohol, polyvinylpyrrolldone.  
   
   
       4 . The delayed breaking fracturing fluid composition of  claim 1  where the hydratable gelling agent is chosen from the group guar gum and derivatives thereof, locust bean gum, tara, konjak, tamarind, starch, cellulose and derivatives thereof, karaya, xanthan, tragacanth, carrageenan.  
   
   
       5 . The delayed breaking fracturing fluid composition of  claim 1  where the aqueous liquid is water, a sodium chloride brine solution, a potassium chloride solution, or water-alcohol mixtures.  
   
   
       6 . The delayed breaking fracturing fluid composition of  claim 1  where the oxidizing breaker is ammonium persulfate, sodium persulfate, potassium persulfate, sodium peroxide, sodium chlorite, sodium, lithium or calcium hypochlorite, potassium perphosphate, or sodium perborate.  
   
   
       7 . The delayed breaking fracturing fluid composition of  claim 1  where the partially esterified polyalkoxylated polyol oxidizing breaker retarder is a mono and higher ester of one or more of chosen from the group alkoxylated sorbitol, alkoxylated monosaccharides, alkoxylated disaccharides, alkoxylated glycerine, alkoxylated polyglycerine, alkoxylated pentaerythritol, alkoxylated trimethylolpropane.  
   
   
       8 . The delayed breaking fracturing fluid composition of  claim 1  where the partially esterified polyalkoxylated polyol is an alkoxylate containing ethylene oxide groups, propylene oxide groups, butylene oxide groups or combinations of one or more ethylene oxide groups, propylene oxide groups, butylene oxide groups that has then been partially esterified with one or more fatty acids.  
   
   
       9 . The delayed breaking fracturing fluid composition of  claim 1  where the partially esterified polyalkoxylated polyol is used in amounts from about 0.1 to about 20 gallons per 1000 gallons, preferably from about 1.0 to about 10 gallons per 1000 gallons of the delayed breaking fracturing fluid,  
   
   
       10 . The delayed breaking fracturing fluid composition of  claim 1  where the hydratable polymer is used in an amount from about 5 to about 80 pounds per 1000 gallons of delayed breaking fracturing fluid composition.  
   
   
       11 . The delayed breaking fracturing fluid composition of  claim 1  where the oxidizing breaker is used in amount of about 0.1 to about 10 pounds per 1000 gallons, preferably from about 0.1 to about 0.5 pounds per 1000 gallons of delayed breaking fracturing fluid composition.  
   
   
       12 . A process for fracturing a subterranean reservoir by: 
 a) injecting into said reservoir a composition having delayed gel breaking properties and consisting of a hydratable gelling agent, an aqueous liquid, an oxidizing breaker, a partially esterified polyalkoxylated polyol as oxidizing breaker retarder, a proppant and optionally a pH control agent and crosslinking agent,    b) allowing enough time for the gel to break, and    c) allowing the broken gel to flow back out of the reservoir while leaving the proppant behind to keep the fracture open.    
   
   
       13 . The process for fracturing a subterranean reservoir as described in  claim 12  where the hydratable gelling agent is a polysaccharide and derivatives thereof which contain one or more of the following monosaccharide units: galactose, mannose, glucoside, glucose, xylose, arabinose, fructose, glucuronic acid, pyranosyl sulfate.  
   
   
       14 . The process for fracturing a subterranean reservoir as described in  claim 12  where the hydratable gelling agent is a synthetic polymer or copolymer of one or more of the following: polyacrylate, polymethacrylate, polyacrylamide, maleic anhydride methylvinyl ether copolymers, polyvinyl alcohol, polyvinylpyrrolidone.  
   
   
       15 . The process for fracturing a subterranean reservoir as described in  claim 12  where the hydratable gelling agent is chosen from the group guar gum and derivatives thereof, locust bean gum, tara, konjak, tamarind, starch, cellulose and derivatives thereof, karaya, xanthan, tragacanth, carrageenan.  
   
   
       16 . The process for fracturing a subterranean reservoir as described in  claim 12  where the aqueous liquid is water, a sodium chloride brine solution, a potassium chloride solution, or water-alcohol mixtures.  
   
   
       17 . The process for fracturing a subterranean reservoir as described in  claim 12  where the oxidizing gel breaker is ammonium persulfate, sodium persulfate, potassium persulfate, sodium peroxide, sodium chlorite, sodium, lithium or calcium hypochlorite, potassium perphosphate, or sodium perborate.  
   
   
       18 . The process for fracturing a subterranean reservoir as described in  claim 12  where the partially esterified polyalkoxylated polyol oxidizing breaker retarder where the partially esterified polyalkoxylated polyol oxidizing breaker retarder is a mono and higher ester of one or more chosen from the group alkoxylated Sorbitol, alkoxylated monosaccharides, alkoxylated disaccharides, alkoxylated glycerin, alkoxylated polyglycerine, alkoxylated pentaerythritol, alkoxylated trimethylolpropane.  
   
   
       19 . The process for fracturing a subterranean reservoir as described in  claim 12  where the partially esterified polyalkoxylated polyol is an alkoxylate containing ethylene oxide groups, propylene oxide groups, butylene oxide groups or combinations of one or more ethylene oxide groups, propylene oxide groups, butylene oxide groups that has then been partially esterified with one or more fatty acids.  
   
   
       20 . The process for fracturing a subterranean reservoir as described in  claim 12  where the proppant is chosen from sand, resin coated sand, synthetic ceramics, or spherical pellets of glass.  
   
   
       21 . The process for fracturing a subterranean reservoir as described in  claim 12  where the concentration and degree of esterification and alkoxylation of the partially esterified polyalkoxylated polyol is chosen to give the desired amount of delayed breaking of the gelled fracturing fluid.