Process for the manufacture of solid regenerated viscose fibres

Abstract

The present invention concerns a process for the manufacture of solid regenerated viscose fibres, comprising the steps of:—spinning a viscose spinning dope through a spinneret comprising spinning holes into a regenerating bath thereby forming filaments,—said viscose spinning dope having an alkali ratio immediately before spinning of from 0.7 to 1.0, preferably from 0.8 to 0.9,—at least part of said spinning holes having a circular orifice,—said regenerating bath containing—from 70 to 120 g/l, preferably 90 to 110 g/l sulfuric acid,—from 240 to 380 g/l, preferably 330 to 370 g/l sodium sulphate,—form 20 to 50 g/l, preferably 25 to 35 g/l zinc sulphate and said regenerating bath having a temperature of from 45 to 55° C., preferably 48 to 50° C.,—stretching said filaments after leaving said regenerating bath in a secondary bath and/or in air at a stretching ratio of from 70% to 90%, preferably 80% to 90% of the maximum stretching ratio as hereinbefore defined and—treating said filaments with a fatty acid ester.

1 - 13 . (canceled)  
   
   
       14 . A process for manufacturing solid regenerated viscose fibers comprising 
 (1) spinning a viscose spinning dope through a spinneret comprising spinning holes into a regenerating bath thereby forming filaments, 
 wherein said viscose spinning dope has an alkali ratio immediately before spinning of from 0.7 to 1.0, preferably from 0.8 to 0.9,  
 wherein at least part of said spinning holes have a circular orifice,  
 wherein said regenerating bath contains from 70 to 120 g/l of sulfuric acid, from 240 to 380 g/l of sodium sulphate, from 20 to 50 g/l of zinc sulphate and  
 wherein said regenerating bath has a temperature of from 45 to 55° C.,  
   (2) stretching said filaments after leaving said regenerating bath in a secondary bath and/or in air at a stretching ratio of from 70% to 90% of a maximum stretching ratio and    (3) treating said filaments with a fatty acid ester thereby forming said fibers.    
   
   
       15 . The method of  claim 14 , wherein the regenerating bath contains from 90 to 110 g/l of sulfuric acid.  
   
   
       16 . The method of  claim 14 , wherein the regenerating bath contains from 330 to 370 g/l, of sodium sulphate.  
   
   
       17 . The method of  claim 14 , wherein the regenerating bath contains from 25 to 35 g/l of zinc sulphate.  
   
   
       18 . The method of  claim 14 , wherein the regenerating bath has a temperature of from 48 to 50° C.  
   
   
       19 . The method of  claim 14 , wherein the stretching ratio is from 80% to 90%, of the maximum stretching ratio.  
   
   
       20 . The process of  claim 14 , wherein a suitable amount of alkali is admixed into the viscose spinning dope immediately before spinning to achieve the desired alkali ratio.  
   
   
       21 . The process of  claim 14 , wherein the fatty acid ester is polyoxethylene sorbitan fatty acid ester.  
   
   
       22 . The process of  claim 14 , wherein the fatty acid ester is present in an amount of from 0.03 to 0.7% (w/w calculated on basis of cellulose), preferably 0.3 to 0.4%.  
   
   
       23 . The process of  claim 14 , wherein the secondary bath has an elevated temperature in comparison to the temperature of the regenerating bath.  
   
   
       24 . The process of  claim 14 , further comprising cutting the filaments to form staple fiber.  
   
   
       25 . The process of  claim 14 , wherein all of said spinning holes have a circular orifice.  
   
   
       26 . Regenerated solid viscose fibers obtained by 
 (1) spinning a viscose spinning dope through a spinneret comprising spinning holes into a regenerating bath thereby forming filaments, 
 wherein said viscose spinning dope has an alkali ratio immediately before spinning of from 0.7 to 1.0,  
 wherein at least part of said spinning holes have a circular orifice,  
 wherein said regenerating bath contains from 70 to 120 g/l of sulfuric acid, from 240 to 380 g/l of sodium sulphate, from 20 to 50 g/l of zinc sulphate and  
 wherein said regenerating bath has a temperature of from 45 to 55° C.,  
   (2) stretching said filaments after leaving said regenerating bath in a secondary bath and/or in air at a stretching ratio of from 70% to 90% of a maximum stretching ratio and    (3) treating said filaments with a fatty acid ester thereby forming said fibers.    
   
   
       27 . The fibers of  claim 26 , wherein the viscose spinning dope has an alkali ratio immediately before spinning of from 0.8 to 0.9.  
   
   
       28 . The fibers of  claim 26 , wherein the regenerating bath contains from 90 to 110 g/l of sulfuric acid.  
   
   
       29 . The fibers of  claim 26 , wherein the regenerating bath contains from 330 to 370 g/l of sodium sulphate.  
   
   
       30 . The fibers of  claim 26 , wherein the regenerating bath contains from 25 to 35 g/l of zinc sulphate.  
   
   
       31 . The fibers of  claim 26 , wherein the regenerating bath has a temperature of from 48 to 50° C.  
   
   
       32 . The fibers of  claim 26 , wherein the stretching ratio is from 80% to 90% of the maximum stretching ratio.  
   
   
       33 . The fibers of  claim 26 , wherein the fibers are in the form of a staple fiber.  
   
   
       34 . The fibers of  claim 26 , wherein the fibers have a Syngina absorbancy of more than 6.0 g/g.  
   
   
       35 . The fibers of  claim 26 , wherein the fibers have a water retention value measured according to DIN 53814 of from 70-110%.  
   
   
       36 . The fibers of  claim 26 , wherein the fibers have a water retention value measured according to DIN 53814 of from 80-90%.  
   
   
       37 . The fibers of  claim 26 , wherein the fibers have a water holding capacity measured according to test method for viscose waddings, described in European Pharmacopoeia 4 01/2002:0034, of more than 23 g/g.  
   
   
       38 . The fibers of  claim 26 , wherein the fibers have a water holding capacity measured according to test method for viscose waddings, described in European Pharmacopoeia 4 01/2002:0034, of more than 25 g/g.  
   
   
       39 . The fibers of  claim 26 , wherein a suitable amount of alkali is admixed into the viscose spinning dope immediately before spinning to achieve the desired alkali ratio.