Methods of enhancing fine particle dewatering

Abstract

A new method of improving the process of dewatering fine particulate materials is disclosed. In this method, an aqueous slurry of fine particles is treated with appropriate hydrophobizing reagents so that the particulate material becomes moderately hydrophobic with its water contact angle considerably below 90°. A low hydrophile-lipophile balance (HLB) number surfactant is then added to the slurry, so that the surfactant molecules adsorb on the moderately hydrophobic surface primarily by hydrophobic attraction and, thereby, increase its contact angle close to or above 90°. By virtue of the greatly enhanced hydrophobicity, the water molecules adhering to the surface are destabilized and removed more readily by a mechanical dewatering process. Any nonionic surfactant with its HLB number below about 15 may be used for the hydrophobicity enhancement. The surfactants may be used in conjunction with appropriate solvents such as light hydrocarbon oils and short-chain alcohols. The moisture reduction can be further improved by using appropriate electrolytes in conjunction with the low HLB surfactants, spraying surface tension lowering reagents onto the filter cake, subjecting the cake to a suitable vibratory means, and by using combinations thereof.

1 . A process for dewatering a slurry of hydrophobic particulate material comprising: 
 i) initially increasing the hydrophobicity of said hydrophobic particulate material by adding hydrocarbon oil to said slurry;    ii) adding a nonionic surfactant of hydrophile-lipophile balance (HLB) number less than 15 dissolved in at least one organic solvent; and    iii) allowing said nonionic surfactant to adsorb on the surface of said material to further increase the hydrophobicity of said material.    
     
     
         2 . The process of  claim 1 , further comprising agitating said slurry.  
     
     
         3 . The process of  claim 1 , further comprising subjecting said slurry to a mechanical method of dewatering.  
     
     
         4 . The process of  claim 1 , wherein said particulate material comprises particles of less than 2 mm in size.  
     
     
         5 . The process of  claim 1 , wherein said nonionic surfactant is selected from the group consisting of: fatty acids, fatty esters, phosphate esters, hydrophobic polymers, ethers, glycol derivatives, sarcosine derivatives, silicon-based surfactants and polymers, sorbitan derivatives, sucrose and glucose esters and derivatives, lanolin-based derivatives, glycerol esters, ethoylated fatty esters, ethoxylated amines and amides, ethoxylated linear alcohols, ethoxylated tryglycerides, ethoylated vegetable oils, and ethoxylated fatty acids.  
     
     
         6 . The process of  claim 1 , wherein said nonionic surfactant is blended with an oil of vegetable or animal origin.  
     
     
         7 . The process of  claim 1 , wherein said organic solvent includes a solvent selected from the group consisting of: light hydrocarbon oils and short-chain alcohols.  
     
     
         8 . The process of  claim 7 , wherein said light hydrocarbon oils are selected from diesel oil, kerosene, gasoline, petroleum distillate, turpentine, naphtanic oils, and oils of vegetable or animal origins.  
     
     
         9 . The process of  claim 7 , wherein said short-chain alcohols have carbon atom numbers less than eight.  
     
     
         10 . The process of  claim 3 , wherein said mechanical method of dewatering is selected from the group consisting of: vacuum filtration, pressure filtration, centrifugal filtration, and centrifugation.  
     
     
         11 . A process for dewatering a slurry of hydrophobic particulate material comprising: 
 initially increasing the hydrophobicity of said hydrophobic particulate material by adding hydrocarbon oil to said slurry;    dissolving a water insoluble nonionic surfactant of hydrophile-lipophile balance (HLB) number less than 15 in at least one organic solvent;    adding said dissolved water insoluble nonionic surfactant and said at least one organic solvent to said slurry; and    allowing said nonionic surfactant to adsorb on the surface of said material to further increase the hydrophobicity of said material.    
     
     
         12 . The process according to  claim 11 , further comprising agitating said slurry.  
     
     
         13 . The process of  claim 11 , further comprising subjecting the agitated slurry containing said material to a mechanical method of dewatering.  
     
     
         14 . The process of  claim 11 , wherein said organic solvent includes a solvent selected from the group consisting of: light hydrocarbon oils and short-chain alcohols.  
     
     
         15 . The process of  claim 14 , wherein said light hydrocarbon oils are selected from diesel oil, kerosene, gasoline, petroleum distillate, turpentine, naphtanic oils, and oils of vegetable or animal origins.  
     
     
         16 . The process of  claim 14 , wherein said short-chain alcohols have carbon atom numbers less than eight.  
     
     
         17 . The process of  claim 11 , wherein said particulate material comprises particles of less than 2 mm in size.