Photoimageable composition
Abstract
The use of photoacid generators including an alkoxyphenylphenyliodonium salt and/or bis(t-butylphenyl)iodonium salt in a photoimageable composition helps improve resolution. Suitable photoimageable compositions includes: (a) a multifunctional polymeric epoxy resin that is dissolved in an organic solvent wherein the epoxy resin comprises oligomers of bisphenyl A that is quantitatively protected by glycidyl ether and wherein the oligomers have an average functionality that ranges from about 3 to 12; and a photoacid generator comprising an alkoxyphenylphenyliodonium salt and/or bis(t-butylphenyl)iodonium salt. Preferred alkoxyphenylphenyliodonium salts include 4-octyloxyphenyl phenyliodonium hexafluoroantimonate and 4-methoxyphenyl phenyliodonium hexafluoroantimonate. The photoimageable composition is particularly suited for producing high aspect ration microstructure.
Claims
exact text as granted — not AI-modified1 . A photoimageable composition comprising:
(a) a multifunctional polymeric epoxy resin that is dissolved in an organic solvent wherein the epoxy resin comprises oligomers of bisphenyl A that are quantitatively protected by glycidyl ether and wherein the oligomers have an average functionality that ranges from about 3 to 12; and (b) a photoactive compound comprising an alkoxyphenylphenyliodonium salt, a bis(t-butylphenyl) iodonium salt, or both.
2 . The photoimageable composition of claim 1 wherein the photoactive compound is an alkoxyphenylphenyliodonium salt.
3 . The photoimageable composition of claim 1 wherein the photoactive compound is selected from the group consisting of 4-octyloxyphenyl phenyliodonium hexafluoroantimonate (OPI HFA), 4-methoxyphenyl phenyliodonium hexafluoroantimonate (MPI HFA), methide salts thereof, and mixtures thereof.
4 . The photoimageable composition of claim 1 wherein the photoactive compound is OPI HFA.
5 . The photoimageable composition of claim 1 wherein the photoactive compound is MPI HFA.
6 . The photoimageable composition of claim 1 wherein the photoactive compound is bis(t-butylphenyl)iodonium hexafluoroantimonate or methide salts thereof.
7 . The photoimageable composition of claim 1 wherein the multifunctional polymeric epoxy resin comprises a bisphenhol A novolac glycidyl ether.
8 . The photoimageable composition of claim 1 wherein the amount photoactive compound present is about 1 to 12 parts by weight based on 100 parts by weight of the resin.
9 . The photoimageable composition of claim 1 wherein the oligomers have an average functionality of about 8.
10 . The photoimageable composition of claim 2 wherein the multifunctional polymeric epoxy resin comprises a bisphenyl A novolac glycidyl ether.
11 . The photoimageable composition of claim 3 wherein the multifunctional polymeric epoxy resin comprises a bisphenyl A novolac glycidyl ether.
12 . The photoimageable composition of claim 4 wherein the multifunctional polymeric epoxy resin comprises a bisphenyl A novolac glycidyl ether.
13 . The photoimageable composition of claim 5 wherein the multifunctional polymeric epoxy resin comprises a bisphenyl A novolac glycidyl ether.
14 . The photoimageable composition of claim 6 wherein the multifunctional polymeric epoxy resin comprises a bisphenyl A novolac glycidyl ether.
15 . The photoimageable composition of claim 2 wherein the amount photoactive compound present is about 1 to 12 parts by weight based on 100 parts by weight of the resin.
16 . The photoimageable composition of claim 3 wherein the amount photoactive compound present is about 1 to 12 parts by weight based on 100 parts by weight of the resin.
17 . The photoimageable composition of claim 4 wherein the amount photoactive compound present is about 1 to 12 parts by weight based on 100 parts by weight of the resin.
18 . The photoimageable composition of claim 5 wherein the amount photoactive compound present is about 1 to 12 parts by weight based on 100 parts by weight of the resin.
19 . The photoimageable composition of claim 6 wherein the amount photoactive compound present is about 1 to 12 parts by weight based on 100 parts by weight of the resin.
20 . The photoimageable composition of claim 7 wherein the amount photoactive compound present is about 1 to 12 parts by weight based on 100 parts by weight of the resin.
21 . The photoimageable composition of claim 2 wherein the oligomers have an average functionality of about 8.
22 . The photoimageable composition of claim 3 wherein the oligomers have an average functionality of about 8.
23 . The photoimageable composition of claim 4 wherein the oligomers have an average functionality of about 8.
24 . The photoimageable composition of claim 5 wherein the oligomers have an average functionality of about 8.
25 . The photoimageable composition of claim 6 wherein the oligomers have an average functionality of about 8.
26 . The photoimageable composition of claim 7 wherein the oligomers have an average functionality of about 8.
27 . The photoimageable composition of claim 8 wherein the oligomers have an average functionality of about 8.Join the waitlist — get patent alerts
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