Glass fiber forming compositions

Abstract

Mathematical relationship for ingredients for fiber glass compositions are used to identify properties of the glass. In particular the forming temperature and delta T. In one embodiment, the mathematical relationship of the ingredients is of a generic quaternary SiO 2 , CaO, AI 2 O 3 and MgO glass system. The relationship of SiO 2 , CaO, AI 2 O 3 and MgO of interest include RO=CaO+MgO, SiO 2 /CaO, SiO 2 /RO, SiO 2 /AI 2 O 3 ; AI 2 O 3 /CaO; SiO 2 +AI 2 O 3 ; SiO 2 -RO and AI 2 O 3 /RO or RO/AI 2 O 3 when other ingredients or components are added to the glass batch materials to alter the forming and/or liquidus temperatures of the glass, for example Na 2 O, Li 2 O, K 2 O and B 2 O 3 the following mathematical relationships are of interest, (SiO 2 +AI 2 O 3 )/(R20+RO+B 2 O 3 ) where RO is as previously defined and R2O=Na 2 O+Li 2 O+K 2 O. Each of the compositional features of the glass identified above reflects the relative balance between the fluidity (i.e. viscosity) of the glass melt and its crystallization potential. Low boron or boron free fiber glass compositions having a low forming temperature ,e.g. 1178 to 1240° C. and a delta T greater than 50° C. in order that the composition can be processed at a low temperature while reducing the possibility of devitrification of the molten glass in the bushing area during a glass fiber forming operation. Fiber glass compositions having low. boron, e.g. less than 5.10 percent by weight has a low forming temperature, e.g. 1193 to 1240° C. and a delta T greater than 50° C.

1 . A glass composition comprising:  
       
         
           
                 
                 
                 
                 
               
                     
                     
                 
                     
                     
                 
                     
                   SiO 2   
                   56 to 59 
                   percent by weight; 
                 
                     
                   Al 2 O 3   
                   10 to 14 
                   percent by weight; 
                 
                     
                   CaO 
                   21 to 25 
                   percent by weight; 
                 
                     
                   MgO 
                   2 to 4 
                   percent by weight; 
                 
                     
                   TiO 2   
                   0 to 1.5 
                   percent by weight; 
                 
                     
                   Na 2 O 
                   0 to 1.25 
                   percent by weight; 
                 
                     
                   Na 2 O + K 2 O 
                   0 to 2 
                   percent by weight; 
                 
                     
                   Fe 2 O 3   
                   0 to 0.5 
                   percent by weight; 
                 
                     
                   B 2 O 3   
                   less than 1.10 
                   percent by weight; 
                 
                 
                 
                 
               
                     
                   Li 2 O 
                   essentially none; 
                 
                     
                     
                 
                     
                     
                 
             
                
                
               
               
                
                
                
                
                
                
                
                
                
               
            
             
                
                
                
               
            
           
         
         MnO or MnO 2  2 to 4 percent by weight;  
         wherein the glass composition has a log 3 forming temperature no greater than 1230° C., and the difference between the log3 forming temperature and the liquidus temperature is at least 50° C.  
       
     
     
         2 . The glass composition according to  claim 1 , wherein the glass composition is essentially free of B 2 O 3 .  
     
     
         3 . The glass composition according to  claim 1 , wherein the glass includes no deliberate addition of fluorine-containing constituents.  
     
     
         4 . The glass composition according to  claim 1 , wherein the ratio of SiO 2  to (CaO+MgO) is no greater than 2.30.  
     
     
         5 . The glass composition according to  claim 1 , wherein the ratio of SiO 2  to (CaO+MgO) is from 2.00 to 2.30.  
     
     
         6 . The glass composition according to  claim 1 , wherein (Na 2 O+K 2 O) is no greater than about 1.03 percent by weight.  
     
     
         7 . The glass composition according to  claim 1 , wherein (Na 2 O+K 2 O) is no greater than 1 percent by weight.  
     
     
         8 . The glass composition according to  claim 1 , wherein the composition includes MnO in an amount no greater than 4 percent by weight.  
     
     
         9 . The glass composition according to  claim 1 , wherein the composition includes MnO 2  in an amount no greater than 4 percent by weight.  
     
     
         10 . A glass composition comprising:  
       
         
           
                 
                 
                 
                 
               
                     
                     
                 
                     
                     
                 
                     
                   SiO 2   
                   57 to 59 
                   percent by weight; 
                 
                     
                   Al 2 O 3   
                   11 to 14 
                   percent by weight; 
                 
                     
                   CaO 
                   22 to 24 
                   percent by weight; 
                 
                     
                   MgO 
                   2 to 3 
                   percent by weight; 
                 
                     
                   TiO 2   
                   0 to 2 
                   percent by weight; 
                 
                     
                   Na 2 O 
                   0 to 1 
                   percent by weight; 
                 
                     
                   Na 2 O + K 2 O 
                   0 to 2 
                   percent by weight; 
                 
                     
                   Fe 2 O 3   
                   0.1 to 0.5 
                   percent by weight; 
                 
                     
                   B 2 O 3   
                   less than 1.0 
                   percent by weight; 
                 
                 
                 
                 
               
                     
                   Li 2 O 
                   essentially none; 
                 
                     
                     
                 
                     
                     
                 
             
                
                
               
               
                
                
                
                
                
                
                
                
                
               
            
             
                
                
                
               
            
           
         
         MnO or MnO 2  2 to 4 percent by weight;  
         wherein the glass composition has a log 3 forming temperature no greater than 1230° C., and the difference between the log3 forming temperature and the liquidus temperature is at least 50° C.  
       
     
     
         11 . The glass composition according to  claim 10 , wherein the SiO 2  is less than 58 percent by weight.