Photoresist cleaning solutions and methods for pattern formation using the same

Abstract

Disclosed are photoresist cleaning solutions, which are used to clean semiconductor substrates before or after an exposing step when photoresist patterns are formed. Methods for forming patterns using the same are also disclosed. The cleaning solutions include H 2 O and a nonionic surfactant compound represented by Formula 1. By spraying the disclosed cleaning solutions on a surface of the semiconductor substrate before or after exposing step to form a photoresist pattern, the desired pattern only is obtained and unnecessary patterns generated in undesired regions by ghost images are avoided as excess acid generated by the photoacid generator is neutralized and removed and damage to unexposed portions of the photoresist polymer is avoided. wherein R 1 and R 2 are independently H, C 1 -C 20 alkyl, C 5 -C 25 alkyl aryl or C 1 -C 10 ester; m is 1 or 2; n is an integer ranging from 10 to 300; and o is 0 or 1.

1 . A photoresist cleaning solution comprising H 2 O and a nonionic surfactant compound represented by Formula 1:  
       
         
           
           
               
               
           
         
       
       wherein 
 R 1  and R 2  are independently H, C 1 -C 20  alkyl, C 5 -C 25  alkyl aryl or C 1 -C 10  ester;  
 m is 1 or2;  
 n is an integer ranging from 10 to 300; and  
 o is 0or 1.  
 
     
     
         2 . The photoresist cleaning solutions according to  claim 1 , wherein R 1  and R 2  are independently H, C 1 -C 12  alkyl, C 12 -C 20  alkyl aryl or C 1 -C 8  ester; and n is an integer ranging from 50 to 150.  
     
     
         3 . The photoresist cleaning solutions according to  claim 2 , wherein R 1  and R 2  are independently selected from the group consisting of H, octyl, octyl phenyl, nonyl, nonyl phenyl, decyl, decyl phenyl, undecyl, undecyl phenyl, dodecyl and dodecyl phenyl.  
     
     
         4 . The photoresist cleaning solutions according to  claim 1 , wherein the compound of Formula 1 is polyethylene glycol or polyethylene glycol monolaurate.  
     
     
         5 . The photoresist cleaning solutions according to  claim 1 , wherein the nonionic surfactant compound of Formula 1 is present in an amount ranging from 0.001 to 1 wt % based on total weight of the solution.  
     
     
         6 . The photoresist cleaning solutions according to  claim 5 , wherein the content of the nonionic surfactant compound of Formula 1 is from 0.005 to 0.05 wt % based on total weight of the solution.  
     
     
         7 . The photoresist cleaning solutions according to  claim 1 , further comprising an alcohol.  
     
     
         8 . The photoresist cleaning solutions according to  claim 7 , wherein the alcohol is present from 0.01 to 10 wt % based on total weight of the solution.  
     
     
         9 . The photoresist cleaning solutions according to  claim 8 , wherein the alcohol is present from 0.01 to 5 wt % based on total weight of the solution.  
     
     
         10 . The photoresist cleaning solutions according to  claim 8 , wherein the alcohol is selected from the group consisting of C 1 -C 10  alkyl alcohol and C 1 -C 10  alkoxyalkyl alcohol.  
     
     
         11 . The photoresist cleaning solutions according to  claim 10 , wherein the C 1 -C 10  alkyl alcohol is selected from the group consisting of methanol, ethanol, propanol, isopropanol, n-butanol, sec-butanol, t-butanol, 1-pentanol, 2-pentanol, 3-pentanol and 2,2-dimethyl-1-propanol.  
     
     
         12 . The photoresist cleaning solutions according to  claim 10 , wherein the C 1 -C 10  alkoxyalkyl alcohol is selected from the group consisting of 2-methoxyethanol, 2-(2-methoxyethoxy)ethanol, 1-methoxy-2-propanol and 3-methoxy-1,2-propanediol.  
     
     
         13 . A photoresist cleaning solutions comprising one or more of polyethylene glycol and polyethylene glycol monolaurate in an amount ranging from 0.001 to 1 wt %; an alcohol in an amount ranging from 0 to 10 wt %, respectively and H 2 O.  
     
     
         14 . The photoresist cleaning solutions according to  claim 13 , wherein the alcohol is ethanol.  
     
     
         15 . The photoresist cleaning solutions according to  claim 13 , wherein each of polyethylene glycol and polyethylene glycol monolaurate is present in an amount ranging from 0.005 to 0.05 wt %, and the alcohol is present in an amount ranging from 0 to 5 wt %.  
     
     
         16 . A method for forming a photoresist pattern, comprising: 
 (a) coating a photoresist on the surface of an underlying layer formed on a semiconductor substrate to form a photoresist film;    (b) soft-baking the photoresist film;    (c) exposing the photoresist film to light;    (d) post-baking the photoresist film; and    (e) developing the photoresist film to form a photoresist pattern, wherein the method further comprises cleaning the photoresist film using the photoresist cleaning solutions of  claim 1  after part (a) and before part (b) or after part (c) and before part (d).    
     
     
         17 . The method according to  claim 16 , wherein the exposure light source is selected from the group consisting of KrF (248 nm), ArF (193 nm), VUV (157 nm), EUV (13 nm), E-beam, X-ray and ion beam.  
     
     
         18 . A semiconductor device fabricated using the method of  claim 16.