Phosphonamide and phosphonamide blend compositions and method to treat water

Abstract

The invention is a water treatment composition comprising at least one phosphonamide and blends thereof and a method to treat water. As phosphonamides are generally odorless, and typically solids, phosphonamide and phosphonamide blend compositions are generally odorless, conveniently processed and manufactured, and safely used without risks of exposure to odors and vapors associated with the corresponding amines. Advantageously, phosphonamides blended with amino-phosphate esters provide useful treatment compositions. The inventive compositions are generally used to treat water contained in water flow systems such as boilers and cooling towers.

1 . A water treatment composition comprising at least one phosphonamide formed from an amine selected from the group consisting of cyclohexylamine, morpholine, octadecylamine, N,N-dimethyl-1,3-propandiamine, and ammonium hydroxide, and 
 a phosphonic acid selected from the group consisting of aminotri(methylene phosphonic acid), 1-hydroxyethylidene-1,1-diphosphonic acid, and 2-phosphono-butane-1,2,4-tricarboxylic acid, and blends thereof to treat water.    
     
     
         2 . The composition of  claim 1  wherein the blend comprising at least two phosphonamides formed from at least two amines and a phosphonic acid, said blend having a cumulative amine to phosphonic acid mole ratio in the range of from about 1:1 to about 10:1.  
     
     
         3 . The composition of  claim 1  further comprising an amino-phosphate ester formed from a hydroxyamine and a phosphonic acid.  
     
     
         4 . The composition of  claim 1  further comprising a hardness control agent.  
     
     
         5 . The composition of  claim 1  wherein the phosphonamide is present in at least about 10% by weight of the composition.  
     
     
         6 . The composition of  claim 1  wherein the composition is a solid.  
     
     
         7 . The composition of  claim 2  wherein the phosphonamide is present in at least about 10% by weight of the composition.  
     
     
         8 . The composition of  claim 3  wherein the amino-phosphate ester is present in at least about 10% by weight of the composition.  
     
     
         9 . The composition of  claim 3  wherein the hydroxyamine is selected from the group consisting of N,N-diethylethanolamine, 2-amino-2-methyl-1-propanol, 1,1-dimethylamine-propanol, and 2-dimethylamino-2-methyl-1-propanol.  
     
     
         10 . The composition of  claim 4  wherein the hardness control agent is a sulfonated water soluble polymeric compound.  
     
     
         11 . A water treatment composition comprising a blend of: 
 at least two phosphonamides formed from at least two amines independently selected from the group consisting of cyclohexylamine, morpholine, octadecylamine, N,N-dimethyl-1,3-propanediamine, and ammonium hydroxide, and a first phosphonic acid; and    an amino-phosphate ester formed from a hydroxyamine selected from the group consisting of N,N-diethylethanolamine, 2-amino-2-methyl-1-propanol, 1,1-dimethylamine-propanol, and 2-dimethylamino-2-methyl-1-propanol, and a second phosphonic acid,    said blend having a cumulative amine to cumulative phosphonic acid mole ratio in the range of from about 1:1 to about 10:1, and used to treat water.    
     
     
         12 . The composition of  claim 11  wherein the first phosphonic acid is the same as the second phosphonic acid.  
     
     
         13 . The composition of  claim 11  wherein the first and second phosphonic acids are independently selected from the group consisting of polyphosphoric acid, aminotri(methylene phosphonic acid), 1-hydroxyethylidene-1,1-diphosphonic acid, and 2-phosphono-butane-1,2,4-tricarboxylic acid.  
     
     
         14 . The composition of  claim 1  comprising a blend of: 
 a morpholine-1-hydroxy-ethylidene-phosphoryl-phosphonamide present in at least about 10% by weight;    a cyclohexylamine-1-hydroxy-ethylidene-phosphoryl-phosphonamide present in at least about 10% by weight; and    a diethylaminoethanol-1-hydroxy-ethylidene-phosphoryl-phosphonate ester present in at least about 10% by weight of the blend,    said blend being formed from a mixture of morpholine, cyclohexylamine, and N,N-diethylethanolamine reacted with 1-hydroxy-ethylidene-1,1-di-phosphonic acid and having a cumulative amine to 1-hydroxy-ethylidene-1,1-di-phosphonic acid mole ratio in the range of from about 1:1 to about 10:1.    
     
     
         15 . A method of treating water comprising the step of: 
 adding to water at least one phosphonamide formed from a reaction between an amine and a phosphonic acid, in an amount sufficient to treat the water.    
     
     
         16 . The method claimed in  claim 15  wherein the amine is of the general formula HN—R 1 R 2  wherein R 1  and R 2  independently are selected from the group consisting of H, alkyl, cycloalkyl, aryl, and heteroaryl organic structures having up to 10 atoms selected from the group consisting of C, N, and O, 
 and wherein R 1  and R 2  taken together with the nitrogen to which they are attached can form a 5 or 6 membered ring containing 0-2 additional heteroatoms selected from N or O, and    the phosphonic acid is of the general formula (OR) 2 —P(O)OH wherein each R independently is selected from the group consisting of H, alkyl, cycloalkyl, aryl, and heteroaryl organic structures having up to 10 atoms selected from the group consisting of C, N and O.    
     
     
         17 . The method claimed in  claim 15  wherein the amine is selected from the group consisting of cyclohexylamine, morpholine, octadecylamine, N,N-dimethyl-1,3-propanediamine, and ammonium hydroxide.  
     
     
         18 . The method claimed in  claim 15  wherein the phosphonic acid is selected from the group consisting of polyphosphoric acid, aminotri(methylene phosphonic acid), 1-hydroxyethylidene-1,1-diphosphonic acid, and 2-phosphono-butane-1,2,4-tricarboxylic acid.  
     
     
         19 . The method claimed in  claim 15  comprising adding to the water a blend of at least two phosphonamides formed from different amines and a phosphonic acid, wherein said blend has a cumulative amine to phosphonic acid mole ratio in the range of from about 1:1 to about 10:1.  
     
     
         20 . The method claimed in  claim 15  further comprising adding to the water an amino-phosphate ester formed from a hydroxyamine and a phosphonic acid.  
     
     
         21 . The method claimed in  claim 15  further comprising adding to the water a hardness control agent.  
     
     
         22 . The method claimed in  claim 15  wherein the phosphonamide is present in at least about 10% by weight of the composition.  
     
     
         23 . The method claimed in  claim 15  wherein the composition is a solid.  
     
     
         24 . The method claimed in  claim 19  wherein each phosphonamide is present in at least about 10% by weight of the composition.  
     
     
         25 . The method claimed in  claim 20  wherein the amino-phosphate ester is present in at least about 10% by weight of the composition.  
     
     
         26 . The method claimed in  claim 20  wherein the hydroxyamine is selected from the group consisting of N,N-diethylethanolamine, 2-amino-2-methyl-1-propanol, 1,1-dimethylamine-propanol, and 2-dimethylamino-2-methyl-1-propanol.  
     
     
         27 . The method claimed in  claim 15  wherein the composition is added to boiler water to treat water in a boiler and boiler feedlines.  
     
     
         28 . The method claimed in  claim 15  wherein the composition is added to water in a cooling tower.  
     
     
         29 . The method claimed in  claim 21  wherein the hardness control agent is a sulfonated water soluble polymeric compound.  
     
     
         30 . The method claimed in  claim 15  comprising adding to water an amount of a blend of: 
 at least two phosphonamides formed from at least two different amines selected from the group consisting of cyclohexylamine, morpholine, octadecylamine, N,N-dimethyl-1,3-propanediamine, and ammonium hydroxide, and a first phosphonic acid; and    an amino-phosphate ester formed from a hydroxyamine selected from the group consisting of N,N-diethylethanolamine, 2-amino-2-methyl-1-propanol, 1,1-dimethylamine-propanol, and 2-dimethylamino-2-methyl-1-propanol, and a second phosphonic acid,    wherein the blend has a cumulative amine to cumulative amine to phosphonic acid mole ratio in the range of from about 1:1 to about 10:1.    
     
     
         31 . The method claimed in  claim 30  wherein the first acid is the same as the second acid.  
     
     
         32 . The method claimed in  claim 30  wherein the first and second phosphonic acids are independently selected from the group consisting of polyphosphoric acid, aminotri(methylene phosphonic acid), 1-hydroxyethylidene-1,1-diphosphonic acid, and 2-phosphono-butane-1,2,4-tricarboxylic acid.  
     
     
         33 . The method claimed in  claim 15  comprising adding to water an amount of a blend of: 
 a morpholine-1-hydroxy-ethylidene-phosphoryl-phosphonamide formed from morpholine present in a range of from about 10% to about 50% by weight and 1-hydroxy-ethylidene-1,1-di-phosphonic acid;    a cyclohexylamine-1-hydroxy-ethylidene-phosphoryl-phosphonamide formed from cyclohexylamine present in a range of from about 10% to about 66% by weight and 1-hydroxy-ethylidene-1,1-di-phosphonic acid; and    a diethylaminoethanol-1-hydroxy-ethylidene-phosphoryl-phosphonate ester formed from diethylaminoethanol present in a range of from about 10% to about 70% by weight and 1-hydroxy-ethylidene-1,1-di-phosphonic acid,    wherein the cumulative amine to 1-hydroxy-ethylidene-1,1-di-phosphonic acid weight ratio is in the range of from about 1:1 to about 10:1.    
     
     
         34 . The method claimed in  claim 33  wherein the blend is added to boiler water to treat water in a boiler and boiler feedlines.  
     
     
         35 . The method claimed in  claim 15  comprising adding to water in a cooling tower: 
 a cyclohexylamine-1-hydroxy-ethylidene-phosphoryl-phosphonamide formed from cyclohexylamine and 1-hydroxy-ethylidene-diphosphonic acid and having a cyclohexylamine to 1-hydroxy-ethylidene-diphosphonic acid mole ratio in the range of from about 1:10 to about 2:1, and    a copolymer,    in an amount sufficient to treat the water.