US2005086856A1PendingUtilityA1

Composition

Priority: Aug 6, 2002Filed: Aug 5, 2003Published: Apr 28, 2005
Est. expiryAug 6, 2022(expired)· nominal 20-yr term from priority
C10L 1/198C10L 1/1835C10L 1/1981C10L 1/1832C10L 1/2283C10L 1/2225C10L 1/2608C10L 1/14
31
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Claims

Abstract

The present invention provides a jet fuel composition comprising (i) a jet fuel; (ii) a compound of Formula I wherein m is at least 1; wherein n is 0 or 1; wherein when m is 1, n is 0; wherein the or each R 1 is a hydrocarbyl group with the proviso that the or each R 1 is free of carboxylic acid and carboxylic ester groups; and wherein when m is 1, R 1 is a polymeric group comprising at least 12 carbon atoms.

Claims

exact text as granted — not AI-modified
1 . A jet fuel composition comprising 
 (i) a jet fuel; and    (ii) a compound of Formula I                          wherein m is at least 1;    wherein n is 0 or 1;    wherein when m is 1, n is 0;    wherein the or each R 1  is a hydrocarbyl group with the proviso that the or each R 1  is free of carboxylic acid and carboxylic ester groups; and    wherein when m is 1, R 1  is a polymeric group comprising at least 12 carbon atoms.    
     
     
         2 . A jet fuel composition according to  claim 1  further comprising (iii) an antioxidant.  
     
     
         3 . A jet fuel composition according to  claim 1  further comprising (iv) a metal deactivator.  
     
     
         4 . A jet fuel composition according to wherein m is 1.  
     
     
         5 . A jet fuel composition according to  claim 1  wherein R 1  is a hydrocarbon group.  
     
     
         6 . A jet fuel composition according to  claim 1  wherein R 1  is a linear or branched alkyl group.  
     
     
         7 . A jet fuel composition according to  claim 1  wherein R 1  is a C 1 -C 200  group.  
     
     
         8 . A jet fuel composition according to  claim 1  wherein R 1  is a C 10 -C 200  group.  
     
     
         9 . A jet fuel composition according to  claim 1  wherein R 1  is a C 40 -C 180  group.  
     
     
         10 . A jet fuel composition according to  claim 1  wherein R 1  is a branched alkyl group.  
     
     
         11 . A jet fuel composition according to  claim 1  wherein R 1  is a polyalkenyl group.  
     
     
         12 . A jet fuel composition according to  claim 1  wherein R 1  is polyisobutene (PIB).  
     
     
         13 . A jet fuel composition according to  claim 1  wherein R 1  has a molecular weight of from 200 to 2500.  
     
     
         14 . A jet fuel composition according to  claim 1  wherein R 1  has a molecular weight of 500 to 2500.  
     
     
         15 . A jet fuel composition according to  claim 1  wherein R 1  has a molecular weight of approximately 750.  
     
     
         16 . A jet fuel composition according to  claim 1  wherein R 1  has a molecular weight of approximately 1000.  
     
     
         17 . A jet fuel composition according to  claim 1  wherein R 1  has a molecular weight of approximately 2300.  
     
     
         18 . A jet fuel composition according to  claim 1  comprising 
 (i) a jet fuel    (ii) a compound of Formula I                          wherein m is 1 and n is 0;    wherein R 1  is a polyisobutene with a molecular weight of from 200 to 2500;    (iii) an antioxidant; and    (iv) a metal deactivator.    
     
     
         19 . A jet fuel composition according to  claim 1  wherein m is greater than 1.  
     
     
         20 . A jet fuel composition according to  claim 19  wherein R 1  is a hydrocarbon group.  
     
     
         21 . A jet fuel composition according to  claim 19  wherein R 1  is a linear or branched alkyl group.  
     
     
         22 . A jet fuel composition according to  claim 19  wherein R 1  is a C 1 -C 50  group.  
     
     
         23 . A jet fuel composition according to  claim 19  wherein R 1  is a C 1 -C 25  group.  
     
     
         24 . A jet fuel composition according to  claim 19  wherein R 1  is a C 5 -C 15  group.  
     
     
         25 . A jet fuel composition according to  claim 19  wherein m is at least 4.  
     
     
         26 . A jet fuel composition according to  claim 19  comprising 
 (i) a jet fuel    (ii) a compound of Formula I                          wherein m is greater than 1 and n is 1;    wherein each R 1  is a C 1 -C 50  hydrocarbyl group free of carboxylic acid and carboxylic ester groups.    (iii) an antioxidant; and    (iv) a metal deactivator.    
     
     
         27 . A jet fuel composition according to  claim 18  wherein R 1  is para substituted relative to the OH group.  
     
     
         28 . A jet fuel composition according to  claim 18  wherein the (CH 2 ) n  group is ortho substituted relative to the OH group.  
     
     
         29 . A jet fuel composition according to  claim 2  wherein the antioxidant is a hindered phenol antioxidant.  
     
     
         30 . A jet fuel composition according to  claim 29  wherein the antioxidant is 2,6-di-t-butyl-4-methyl phenol (BHT).  
     
     
         31 . A jet fuel composition according to  claim 2  wherein the antioxidant is a phosphonate.  
     
     
         32 . A jet fuel composition according to  claim 31  wherein the antioxidant is dilauryl phosphonate.  
     
     
         33 . A jet fuel composition according to  claim 3  wherein the metal deactivator is N,N′-disalicylidene 1,2-propanediamine.  
     
     
         34 . A jet fuel composition according to  claim 1  wherein the compound of Formula I is present in an amount of 50-200 mg/L.  
     
     
         35 . A jet fuel composition according to  claim 1  wherein the compound of Formula I is present in an amount of 80-120 mg/L.  
     
     
         36 . A jet fuel composition according to  claim 2  wherein the antioxidant is present in an amount of 1-50 mg/L.  
     
     
         37 . A jet fuel composition according to  claim 36  wherein the antioxidant is present in an amount of 1-30 mg/L.  
     
     
         38 . A jet fuel composition according to  claim 3  wherein the metal deactivator is present in an amount of 0.05-10 mg/L.  
     
     
         39 . A jet fuel composition according to  claim 38  wherein the metal deactivator is present in an amount of 0.5-5 mg/L.  
     
     
         40 . A jet fuel composition according to  claim 1  wherein the compound of Formula I is a compound of Formula II  
       
         
           
           
               
               
           
         
       
       wherein the or each R 2  is an optional hydrocarbyl group with the proviso that the or each R 2  is free of carboxylic acid and carboxylic ester groups; and wherein m, n and R 1  are as defined in any one of the preceding claims.  
     
     
         41 . Use of a compound of Formula I as defined in  claim 1  for the inhibition of oxidation of a jet fuel composition as defined in any one of the preceding claims.  
     
     
         42 . Use of a compound of Formula I as defined in  claim 1  for the inhibition of deposit formation in a jet fuel composition as defined in any one of the preceding claims.  
     
     
         43 . Use of a compound of Formula I as defined in  claim 1  for the inhibition of particulate formation from the oxidation product(s) of a jet fuel composition as defined in any one of the preceding claims.  
     
     
         44 . Use of a compound of Formula I as defined in  claim 1  for the solubilisation of deposits and/or deposit precursors in a jet fuel composition as defined in any one of the preceding claims.  
     
     
         45 . A method for inhibiting deposit formation in a jet fuel at a temperature of from 100 to 335° C., the method comprising combining with the jet fuel a compound of Formula I  
       
         
           
           
               
               
           
         
         wherein m is at least 1;  
         wherein n is 0 or 1;  
         wherein when m is 1, n is 0;  
         wherein the or each R 1  is a hydrocarbyl group with the proviso that the or each R 1  is free of carboxylic acid and carboxylic ester groups; and  
         wherein when m is 1, R 1  is a polymeric group comprising at least 12 carbon atoms.  
       
     
     
         46 . (canceled)  
     
     
         47 . (canceled)  
     
     
         48 . (canceled)  
     
     
         49 . (canceled)

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