Post-formable multilayer optical films and methods of forming

Abstract

Articles including post-formed multilayer optical films with layers of at least one strain-induced birefringent material, methods of manufacturing such articles by post-forming multilayer optical films, and multilayer optical films that are particularly well-suited to post-forming operations are disclosed. The articles, methods and multilayer optical films of the present invention allow for post-forming of multilayer optical films including strain-induced index of refraction differentials while retaining the desired optical properties of the multilayer optical films.

1 . An article comprising multilayer optical film comprising an optical stack comprising a plurality of layers, the layers comprising at least one birefringent polymer and at least one second polymer, wherein the optical stack comprises a strain-induced index of refraction differential between layers in the optical stack along a first in-plane axis, and further wherein the optical stack defines first and second major surfaces, the first major surface including at least one depressed area formed therein.  
   
   
       2 . The article of  claim 1 , wherein the depth of the depressed area relative to the first surface is at least about 0.1 millimeter or more, and further wherein the second major surface includes at least one raised area formed thereon.  
   
   
       3 . The article of  claim 2 , wherein each of the depressed areas formed in the first surface is located opposite one of the raised areas on the second surface.  
   
   
       4 . The article of  claim 2 , wherein the optical stack further comprises a strain-induced index of refraction differential along a second in-plane axis that is perpendicular to the first in-plane axis.  
   
   
       5 . The article of  claim 1 , wherein the depth of the depressed area relative to the first surface is at least about 1 millimeter or more.  
   
   
       6 . The article of  claim 5 , wherein the second major surface comprises at least one raised area formed thereon.  
   
   
       7 . The article of  claim 6 , wherein each of the depressed areas formed in the first surface is located opposite one of the raised areas on the second surface.  
   
   
       8 . The article of  claim 6 , wherein the optical stack further comprises a strain-induced index of refraction differential along a second in-plane axis that is perpendicular to the first in-plane axis.  
   
   
       9 . The article of  claim 1 , wherein the optical stack has a corrugated configuration.  
   
   
       10 . The article of  claim 1 , wherein the optical stack includes one or more deformed portions whose thickness differs from remaining portions of the optical stack by at least about 10%.  
   
   
       11 . The article of  claim 10 , wherein the one or more deformed portions are selected from the group consisting of embossed portions and thermoformed portions.  
   
   
       12 . The article of  claim 10 , wherein the deformed portions define indicia.  
   
   
       13 . The article of  claim 10 , wherein a thickness ratio of the optical stack between the deformed portions and the remaining portions is up to a factor of 3.  
   
   
       14 . The article of  claim 1 , further comprising a rigid substrate attached to the multilayer optical film.  
   
   
       15 . The article of  claim 1 , wherein the optical film has been underdrawn to achieve a crystallinity of the birefringent polymer of from about 3% to about 18%.  
   
   
       16 . The article of  claim 1 , wherein the birefringent polymer has associated therewith a draw ratio Regime II over which the crystallinity of the birefringent polymer is at least about 3% and over which a refractive index difference of the birefringent polymer increases at a faster rate than over larger draw ratios, and wherein the optical film has been underdrawn such that the birefringent polymer has been stretched to a draw ratio in Regime II.  
   
   
       17 . An article comprising a multilayer optical film comprising an optical stack comprising a plurality of layers, the layers comprising at least one birefringent polymer and at least one second polymer, the multilayer optical film comprising at least a first and second reflective portion wherein the second reflective portion is thinned relative to the first reflective portion, wherein the first and second reflective portions reflect normally incident light in a first and second wavelength range respectively that differ from each other but that overlap at least in a wavelength range of interest.  
   
   
       18 . The article of  claim 17 , wherein the wavelength range of interest comprises 400 to 700 nanometers.  
   
   
       19 . The article of  claim 17 , wherein the second reflective portion is thinned by a factor of at least 2 relative to the first reflective portion.  
   
   
       20 . The article of  claim 17 , wherein the first wavelength range comprises at least 400 to 1800 nanometers.  
   
   
       21 . The article of  claim 17 , wherein the second wavelength range comprises at least 400 to 900 nanometers.  
   
   
       22 . The article of  claim 17 , wherein the second reflective portion is selected from the group consisting of an embossed portion and a thermoformed portion of the multilayer optical film.  
   
   
       23 . The article of  claim 17 , wherein the optical stack comprises a strain-induced index of refraction differential between layers in the optical stack along a first in-plane axis, and further wherein the optical stack defines first and second major surfaces, the first major surface including a depressed area formed therein at the second reflective portion.  
   
   
       24 . The article of  claim 23 , wherein the depth of the depressed area relative to the first surface is at least about 1 millimeter or more.  
   
   
       25 . The article of  claim 23 , wherein the depth of the depressed area relative to the first surface is at least about 0.1 millimeter or more, and further wherein the second major surface includes at least one raised area formed thereon.