Polymeric optical articles

Abstract

Polymeric optical articles, including gradient index optical preforms and fiber produced therefrom, are described. Methods for producing the optical articles using plasticizers and/or dopants in the sheathing of the articles are also described. Gradient index optical articles made according to the invention have excellent optical characteristics, enhanced mechanical properties and environmental stability, and enable more flexibility in the selection of materials.

1 - 30 . (Cancelled)  
     
     
         31 . A method for forming a gradient index plastic optical article comprising: 
 (a) forming a tube of polymeric sheathing material that is at least partially transparent to light at least one wavelength from at least one polymerizable sheathing monomer including a sheathing dopant; and    (b) forming a polymeric core that is at least partially transparent to light at at least one wavelength within the tube formed in step (a), with said core having a gradient in refractive index in a specific direction by: 
 (i) filling said tube with a composition including at least one polymerizable core monomer; and  
 (ii) polymerizing said core monomer.  
   
     
     
         32 . The method of  claim 31 , wherein said tube of sheathing material is formed by: 
 (a) supplying a cylindrical polymerization container;    (b) placing a quantity of a composition including said at least one polymerizable sheathing monomer and said sheathing dopant into said container; and    (c) polymerizing said sheathing monomer to form a hollow polymeric tube.    
     
     
         33 . The method of  claim 31 , wherein said sheathing dopant has a refractive index less than said polymerizable sheathing monomer when polymerized without the sheathing dopant.  
     
     
         34 . The method of  claim 31 , wherein the composition in step (b)(i) further includes a core dopant.  
     
     
         35 . The method of  claim 34 , wherein the core dopant has a refractive index greater than that of the polymerizable core monomer when polymerized without the core dopant.  
     
     
         36 . The method of  claim 31 , wherein energy is supplied during step (b)(ii).  
     
     
         37 . The method of  claim 32 , wherein energy is supplied during step (c).  
     
     
         38 . The method of  claim 36 , wherein said energy is in the form of heat.  
     
     
         39 . The method of  claim 37 , wherein said energy is in the form of heat.  
     
     
         40 . The method of  claim 32 , wherein said polymerization container is rotated during step (c).  
     
     
         41 . The method of  claim 31 , wherein said polymerizable sheathing monomer and said polymerizable core monomer are different.  
     
     
         42 . The method of  claim 31 , wherein said polymerizable sheathing monomer and said polymerizable core monomer are the same.  
     
     
         43 . The method of  claim 42 , wherein the polymerizable monomer is methyl methacrylate.  
     
     
         44 . The method of  claim 31  further comprising the step of hot-drawing the article formed after the completion of step (b) at a predetermined temperature and speed to form a gradient index optical fiber.  
     
     
         45 - 70 . (Cancelled)  
     
     
         71 . A method for making a gradient index plastic optical fiber comprising: 
 forming a polymeric preform rod comprising a polymeric sheathing and a polymeric core coaxially disposed within said sheathing, said polymeric core having a gradient in refractive index in a specific direction; and    hot-drawing said rod at a draw rate of at least 3 m/min into a fiber that conducts light of at least one wavelength with an attenuation less than 500 dB/km.    
     
     
         72 - 73 . (Cancelled)  
     
     
         74 . The method of  claim 31 , wherein in step (b)(ii), a concentration gradient of the sheathing dopant within at least a portion of the core is established by redistribution of at least a portion of the sheathing dopant during polymerization.